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1. 发明授权

US5849963A Method for producing difluoromethane and 1,1,1,2-tetrafluoroethane 失效
标题翻译：生产二氟甲烷和1,1,1,2-四氟乙烷的方法
公开(公告)号：US5849963A
公开(公告)日：1998-12-15
申请号：US656229
申请日：1996-06-07
申请人： Yukio Homoto , Kunitada Tanaka , Takashi Shibanuma , Satoshi Komatsu , Satoshi Koyama
发明人： Yukio Homoto , Kunitada Tanaka , Takashi Shibanuma , Satoshi Komatsu , Satoshi Koyama
IPC分类号： C07C17/20 , C07C17/21 , C07C19/08 , C07C17/158 , C07C17/06
CPC分类号： C07C19/08 , C07C17/206 , C07C17/21
摘要： According to the method for producing difluoromethane and 1,1,1,2-tetrafluoroethane, having the steps of: (1) reacting methylene chloride and 1,1,2-trichloroethylene with hydrogen fluoride in a vapor phase In the presence of a fluorinating catalyst and 1,1,1,2-tetrafluoroethane in a first reactor; and (2) reacting 1,1,1-trifluorochloroethane with hydrogen fluoride in a vapor phase in the presence of a fluorinating catalyst in a second reactor, and supplying the reaction mixture from the second reactor to the first reactor, HFC-32 can be obtained in high conversion and high selectivity by fluorinating HCC-30 using commonly a large (excess) amount of HF which is required for producing HFC-134a.
摘要翻译： PCT No.PCT / JP94 / 02070 Sec。 371日期1996年6月7日第 102（e）日期1996年6月7日PCT 1994年12月9日PCT PCT。公开号WO95 / 15937 日期：1995年6月15日根据生产二氟甲烷和1,1,1,2-四氟乙烷的方法，具有以下步骤：（1）使二氯甲烷和1,1,2-三氯乙烯与氟化氢在气相In 在第一反应器中存在氟化催化剂和1,1,1,2-四氟乙烷; 和（2）在第二反应器中，在氟化催化剂存在下，在气相中使1,1,1-三氟氯乙烷与氟化氢反应，并将反应混合物从第二反应器供应到第一反应器，HFC-32可以通过使用通常产生HFC-134a所需的大量（过量）的HF来氟化HCC-30而以高转化率和高选择性获得。

2. 发明授权

US5847244A Method of producing 1,1,1,2,2-pentafluoroethane, a method of producing 2,2-dichloro-1,1,1-trifluoroethane, and a method of purifying 1,1,1,2,2-pentafluoroethane 失效
标题翻译：制造1,1,1,2,2-五氟乙烷的方法，2,2-二氯-1,1,1-三氟乙烷的制造方法以及1,1,1,2,2-五氟乙烷
公开(公告)号：US5847244A
公开(公告)日：1998-12-08
申请号：US23881
申请日：1998-02-13
申请人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
发明人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
IPC分类号： C07C17/20 , C07C17/21 , C07C17/395 , C07C19/08 , C07C17/08 , C07C17/38
CPC分类号： C07C17/206 , C07C17/21 , C07C17/395
摘要： A production method in which reaction processes are divided into two regions comprising one reaction region where mainly perohloroethylene is made to react with HF in a vapor phase in the presence of a catalyst and the other reaction region where HCFC-123 (CF.sub.3 CHCl.sub.2) and/or HCFC-124 (CF.sub.3 CFHCl) is made to react with HF in a vapor phase in the presence of a catalyst, the former region being kept at a higher pressure and the latter region at a lower pressure during the reaction procedure. By this method it is possible to keep the conversion of perchloroethylene at a high level while securing the life of a catalyst, and it is also possible to raise the selectivity of HFC-125. This is a method of producing HFC-125 in which the content of CFC-115 is lowered to not more than 15 vol % of the total amount of HFC-125 and CFC-115, and then CFC-115 is made to react with hydrogen in the presence of a catalyst. By this method, reaction conditions can be lightened and the absolute amount of by-products also decreased, and the effective purification of HFC-125 can be realized.
摘要翻译：一种制备方法，其中将反应过程分为两个区域，其中一个反应区域主要使四氯乙烯与HF在气相中在催化剂存在下反应，另一个反应区域是HCFC-123（CF3CHCl2）和/或在催化剂存在下使HCFC-124（CF 3 CFHCl）在气相中与HF反应，在反应过程中将前一个区域保持在较高的压力，而后一个区域处于较低的压力。通过该方法，可以保持全氯乙烯的转化率高，同时确保催化剂的寿命，并且还可以提高HFC-125的选择性。这是生产HFC-125的方法，其中CFC-115的含量降低到不超过HFC-125和CFC-115总量的15vol％，然后使CFC-115与氢反应在催化剂存在下。通过该方法，可以减轻反应条件，副产物的绝对量也降低，能够实现HFC-125的有效净化。

3. 发明授权

US5750809A Methods of producing 1,1,1,2,2-pentafluoroethane 失效
标题翻译：生产1,1,1,2,2-五氟乙烷的方法
公开(公告)号：US5750809A
公开(公告)日：1998-05-12
申请号：US513755
申请日：1995-09-05
申请人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
发明人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
IPC分类号： C07C17/20 , C07C17/21 , C07C17/395 , C07C19/08 , C07C17/08
CPC分类号： C07C17/206 , C07C17/21 , C07C17/395
摘要： A production method in which reaction processes are divided into two regions comprising one reaction region where mainly perchloroethylene is made to react with HF in a vapor phase in the presence of a catalyst and the other reaction region where HCFC-123 (CF.sub.3 CHCl.sub.2) and/or HCFC-124 (CF.sub.3 CFHCl) is made to react with HF in a vapor phase in the presence of a catalyst, the former region being kept at a higher pressure and the latter region at a lower pressure during the reaction procedure. By this method it is possible to keep the conversion of perchloroethylene at a high level while securing the life of a catalyst, and it is also possible to raise the selectivity of HFC-125. This is a method of producing HFC-125 in which the content of CFC-115 is lowered to not more than 15 vol % of the total amount of HFC-125 and CFC-115, and then CFC-115 is made to react with hydrogen in the presence of a catalyst. By this method, reaction conditions can be lightened and the absolute amount of by-products also decreased, and the effective purification of HFC-125 can be realized.
摘要翻译： PCT No.PCT / JP94 / 00348 Sec。 371 1995年9月5日第 102（e）日期1995年9月5日PCT 1994年3月3日PCT公布。 WO94 / 20441 PCT出版物日期1994年9月15日一种制备方法，其中反应过程分为两个区域，其中一个反应区域主要使全氯乙烯与HF在气相中在催化剂存在下反应，另一个反应区域是HCFC-123（ CF 3 CHCl 2）和/或HCFC-124（CF 3 CFHCl）在气相中在催化剂存在下与HF反应，前一区域保持在较高压力，后一区域在反应过程中处于较低压力。通过该方法，可以保持全氯乙烯的转化率高，同时确保催化剂的寿命，并且还可以提高HFC-125的选择性。这是生产HFC-125的方法，其中CFC-115的含量降低到不超过HFC-125和CFC-115总量的15vol％，然后使CFC-115与氢反应在催化剂存在下。通过该方法，可以减轻反应条件，副产物的绝对量也降低，能够实现HFC-125的有效净化。

4. 发明授权

US06180840B2 Method of producing 1,1,1,2,2-pentafluoroethane a method of producing 2,-2,-diohloro-1,1,1-trifluorethane and a method of purifying 1,1,1,2 pentafluoroethane 失效
标题翻译：制备1,1,1,2,2-五氟乙烷的方法制备2，-2， - 二氯-1,1,1-三氟乙烷的方法和1,1,1,2五氟乙烷
公开(公告)号：US06180840B2
公开(公告)日：2001-01-30
申请号：US09107490
申请日：1998-06-30
申请人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
发明人： Takashi Shibanuma , Yukio Homoto , Satoshi Komatsu , Toshikazu Yoshimura
IPC分类号： C07C1710
CPC分类号： C07C17/395 , C07C19/08
摘要： A production method in which reaction processes are divided into two regions comprising one reaction region where mainly perchloroethylene is made to react with HF in a vapor phase in the presence of a catalyst and the other reaction region where HCFC-123 (CF3CHCl2) and/or HCFC-124 (CF3CFHCl) is made to react with HF in a vapor phase in the presence of a catalyst, the former region being kept at a higher pressure and the latter region at a lower pressure during the reaction procedure. By this method it is possible to keep the conversion of perchloroethylene at a high level while securing the life of a catalyst, and it is also possible to raise the selectivity of HFC-125. This is a method of producing HFC-125 in which the content of CFC-115 is lowered to not more than 15 vol % of the total amount of HFC-125 and CFC-115, and then CFC-115 is made to react with hydrogen in the presence of a catalyst. By this method, reaction conditions can be lightened and the absolute amount of by-products also decreased, and the effective purification of HFC-125 can be realized.
摘要翻译：一种制备方法，其中将反应过程分为两个区域，其中一个反应区域主要使全氯乙烯与HF在气相中在催化剂存在下反应，另一个反应区域中，HCFC-123（CF 3 CHCl 2）和/或在催化剂存在下使HCFC-124（CF 3 CFHCl）在气相中与HF反应，在反应过程中将前一个区域保持在较高的压力，而后一个区域处于较低的压力。通过该方法，可以保持全氯乙烯的转化率高，同时确保催化剂的寿命，并且还可以提高HFC-125的选择性。这是生产HFC-125的方法，其中CFC-115的含量降低到不超过HFC-125和CFC-115总量的15vol％，然后使CFC-115与氢反应在催化剂存在下。通过该方法，可以减轻反应条件，副产物的绝对量也降低，能够实现HFC-125的有效净化。

5. 发明申请

US20050148790A1 Method for producing mixture of fluoroalkyl iodide telomers and method for producing mixture of fluorine-containing (meth)acrylate esters 有权
标题翻译：氟烷基碘调节剂混合物的制备方法和含氟（甲基）丙烯酸酯的混合物的制造方法
公开(公告)号：US20050148790A1
公开(公告)日：2005-07-07
申请号：US11074707
申请日：2005-03-09
申请人： Yukio Homoto , Kunitada Tanaka
发明人： Yukio Homoto , Kunitada Tanaka
IPC分类号： C07C17/275 , C07C17/278 , C07C19/16 , C07C67/10 , C07C69/653 , C07C69/52
CPC分类号： C07C19/16 , C07C17/275 , C07C17/278 , C07C67/10 , C07C69/653
摘要： A mixture of fluoroalkyl iodide telomers represented by the formula: Rf(CF2CF2)nI wherein Rf represents a fluoroalkyl group whose number of carbon atoms is in the range of 1 to 10, with the polymerization degree n equal to or more than k that is an integer of 3 or more, is obtained by reacting a fluoroalkyl iodide with tetrafluoroethylene in a first reactor followed by fractionating a first reaction mixture which contains fluoroalkyl iodide telomers of low polymerization degree, as well as by reacting the telomer with n of (k−1) separated from the first reaction mixture with tetrafluoroethylene in the second reactor.
摘要翻译：由下式表示的氟代烷基碘调节剂的混合物：其中（R 1，R 2，R 2，R 2） R f表示碳原子数为1〜10的氟代烷基，聚合度n为3以上的k以上的聚合度n通过使氟烷基碘与四氟乙烯在第一反应器中反应，然后分馏含有低聚合度的氟烷基碘调节剂的第一反应混合物，以及通过使调聚物与从第一反应混合物分离的（k-1）n与四氟乙烯在第二反应器中。

6. 发明授权

US07038095B2 Method for producing fluoroalkyl iodide telomer mixture and method for producing mixture fluorine-containing (meth) acrylate esters 失效
标题翻译：氟代烷基碘调聚物混合物的制备方法和含氟（甲基）丙烯酸酯混合物的制备方法
公开(公告)号：US07038095B2
公开(公告)日：2006-05-02
申请号：US10466869
申请日：2002-02-05
申请人： Yukio Homoto , Kunitada Tanaka
发明人： Yukio Homoto , Kunitada Tanaka
IPC分类号： C07C17/00
CPC分类号： C07C19/16 , C07C17/275 , C07C17/278 , C07C67/10 , C07C69/653
摘要： A mixture of fluoroalkyl iodide telomers represented by the formula: Rf(CF2CF2)nI wherein Rf represents a fluoroalkyl group whose number of carbon atoms is in the range of 1 to 10, with the polymerization degree n equal to or more than k that is an integer of 3 or more, is obtained by reacting a fluoroalkyl iodide with tetrafluoroethylene in a first reactor followed by fractionating a first reaction mixture which contains fluoroalkyl iodide telomers of low polymerization degree, as well as by reacting the telomer with n of (k−1) separated from the first reaction mixture with tetrafluoroethylene in the second reactor.
摘要翻译：由下式表示的氟代烷基碘调节剂的混合物：其中（R 1，R 2，R 2，R 2） R f表示碳原子数为1〜10的氟代烷基，聚合度n为3以上的k以上的聚合度n通过使氟烷基碘与四氟乙烯在第一反应器中反应，然后分馏含有低聚合度的氟烷基碘调节剂的第一反应混合物，以及通过使调聚物与从第一反应混合物分离的（k-1）n与四氟乙烯在第二反应器中。

7. 发明授权

US07390917B2 Method for producing mixture of fluoroalkyl iodide telomers and method for producing mixture of fluorine-containing (meth)acrylate esters 有权
标题翻译：氟烷基碘调节剂混合物的制备方法和含氟（甲基）丙烯酸酯的混合物的制造方法
公开(公告)号：US07390917B2
公开(公告)日：2008-06-24
申请号：US11074707
申请日：2005-03-09
申请人： Yukio Homoto , Kunitada Tanaka
发明人： Yukio Homoto , Kunitada Tanaka
IPC分类号： C07C69/52
CPC分类号： C07C19/16 , C07C17/275 , C07C17/278 , C07C67/10 , C07C69/653
摘要： A method of producing a mixture of fluorine-containing (meth)acrylate esters, the method including: (A) a telomerization step of obtaining the mixture of the fluoroalkyl iodide telomers; (B) an ethylene addition step of adding ethylene to the mixture of the fluoroalkyl iodide telomers obtained in the step (A) to give a mixture of ethylene adducts; and (C) an esterification step of reacting the mixture of the ethylene adducts obtained in the step (B) with a (meth)acrylate compound to obtain fluorine-containing (meth)acrylate esters.
摘要翻译：一种制备含氟（甲基）丙烯酸酯混合物的方法，该方法包括：（A）得到氟代烷基碘调节剂的混合物的调聚步骤; （B）乙烯加成步骤，在步骤（A）得到的氟烷基碘调节剂的混合物中加入乙烯，得到乙烯加成物的混合物; 和（C）使步骤（B）中获得的乙烯加成物的混合物与（甲基）丙烯酸酯化合物反应得到含氟（甲基）丙烯酸酯的酯化步骤。

8. 发明授权

US5264637A Process for preparing fluoroalcohol 失效
标题翻译：制备氟代醇的方法
公开(公告)号：US5264637A
公开(公告)日：1993-11-23
申请号：US770751
申请日：1991-10-04
申请人： Tutomu Yoshida , Kunitada Tanaka , Yasumichi Chiba , Yasuhisa Furutaka , Yukio Homoto
发明人： Tutomu Yoshida , Kunitada Tanaka , Yasumichi Chiba , Yasuhisa Furutaka , Yukio Homoto
IPC分类号： C07C29/124 , C07C31/40 , C07C31/38
CPC分类号： C07C31/40 , C07C29/124
摘要： A fluoroalcohol of the formulaRf(CH.sub.2 CH.sub.2 OH)n (1)is prepared by the following three kinds of processes:(a) by contacting a betaine compound with a halide compound of the formulaRf(CH.sub.2 CH.sub.2 X)n (2) to obtain an intermediate compound and subjecting the intermediate compound to hydrolysis,(b) by contacting a betaine compound and water in the presence of an organic solvent with a halide compound of the formulaRf(CH.sub.2 CH.sub.2 X)n (2), or(c) by contacting a betaine type surfactant and water with a halide compound of the formulaRf(CH.sub.2 CH.sub.2 X)n (2), wherein Rf is C.sub.2.about.13 fluoroalkyl or C.sub.2.about.13 fluoroalkylene group, X is iodine or bromine, n is 1 when Rf is fluoroalkyl group and n is 2 when Rf is fluoroalkylene group.
摘要翻译：通过以下三种方法制备式Rf（CH 2 CH 2 OH）n（1）的氟代醇：（a）通过使甜菜碱化合物与式Rf（CH 2 CH 2 X）n（2）的卤化合物接触，得到中间体（b）通过使有机溶剂存在下的甜菜碱化合物和水与式Rf（CH2CH2X）n（2）的卤化物化合物接触，或（c）通过使甜菜碱式（2）中卤素化合物，其中R f是C 2-6烷基或C 2-6不同的氟代亚烷基，X是碘或溴，当Rf是氟烷基时n是1，n是1 当Rf为氟代亚烷基时为2。

9. 发明授权

US6049016A Process for producing pentafluoroethane and tetrafluorochloroethane 失效
标题翻译：生产五氟乙烷和四氟氯乙烷的方法
公开(公告)号：US6049016A
公开(公告)日：2000-04-11
申请号：US359644
申请日：1999-07-26
申请人： Toshikazu Yoshimura , Yukio Homoto , Yasufu Yamada , Takehide Tsuda , Takashi Shibanuma
发明人： Toshikazu Yoshimura , Yukio Homoto , Yasufu Yamada , Takehide Tsuda , Takashi Shibanuma
IPC分类号： C07C17/20 , C07C17/21 , C07C19/08 , C07C19/12 , C07C17/08
CPC分类号： C07C19/12 , C07C17/206 , C07C17/21 , C07C19/08
摘要： There is provided a process for producing HFC-125 and/or HCFC-124 from PCE, characterized by the first reaction step of fluorinating PCE in the presence of catalyst in a liquid phase to form HCFC-123 and/or HCFC-122 and the second reaction step of fluorinating HCFC-123 and/or HCFC-122 in the presence of catalyst in a vapor phase to form HFC-125 and/or HCFC-124.This process is improved in the yield of objective products, and life of catalyst, and the controllability of reaction temperature.
摘要翻译：提供了从PCE生产HFC-125和/或HCFC-124的方法，其特征在于在催化剂存在下在液相中氟化PCE以形成HCFC-123和/或HCFC-122的第一反应步骤，在催化剂存在下在气相中氟化HCFC-123和/或HCFC-122以形成HFC-125和/或HCFC-124的第二反应步骤。该方法提高了目标产物的产率，催化剂的使用寿命和反应温度的可控性。

10. 发明授权

US6011185A Process for producing pentafluoroethane and tetrafluorochloroethane 失效
标题翻译：生产五氟乙烷和四氟氯乙烷的方法
公开(公告)号：US6011185A
公开(公告)日：2000-01-04
申请号：US894472
申请日：1997-08-20
申请人： Toshikazu Yoshimura , Yukio Homoto , Yasufu Yamada , Takehide Tsuda , Takashi Shibanuma
发明人： Toshikazu Yoshimura , Yukio Homoto , Yasufu Yamada , Takehide Tsuda , Takashi Shibanuma
IPC分类号： C07C17/20 , C07C17/21 , C07C19/08 , C07C19/12 , C07C17/08
CPC分类号： C07C19/12 , C07C17/206 , C07C17/21 , C07C19/08
摘要： There is provided a process for producing HFC-125 and/or HCFC-124 from PCE, characterized by the first reaction step of fluorinating PCE in the presence of catalyst in a liquid phase to form HCFC-123 and/or HCFC-122 and the second reaction step of fluorinating HCFC-123 and/or HCFC-122 in the presence of catalyst in a vapor phase to form HFC-125 and/or HCFC-124.This process is improved in the yield of objective products, and life of catalyst, and the controllability of reaction temperature.
摘要翻译： PCT No.PCT / JP96 / 00401 Sec。 371日期1997年8月20日 102（e）日期1997年8月20日PCT 1996年2月22日PCT公布。出版物WO96 / 26172 日本1996年8月29日提供了从PCE生产HFC-125和/或HCFC-124的方法，其特征在于在催化剂存在下在液相中氟化PCE的第一反应步骤，形成HCFC-123和/或 HCFC-122和在催化剂存在下在气相中氟化HCFC-123和/或HCFC-122以形成HFC-125和/或HCFC-124的第二反应步骤。该方法提高了目标产物的产率，催化剂的使用寿命和反应温度的可控性。

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