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    • 1. 发明授权
    • Paintable olefinic interpolymer compositions
    • 可涂漆烯烃互聚物组合物
    • US5883188A
    • 1999-03-16
    • US926760
    • 1997-09-10
    • Yuh-Chin HwangStephen R. BetsoThomas J. McKeand, Jr.H. Craig SilvisDeepak R. ParikhDon J. GermanoSeema V. Karande
    • Yuh-Chin HwangStephen R. BetsoThomas J. McKeand, Jr.H. Craig SilvisDeepak R. ParikhDon J. GermanoSeema V. Karande
    • C08L51/06C08L51/00
    • C08L51/06Y10T428/31938
    • Paintable thermoplastic polyolefin compositions are disclosed which comprise (i) about 20 to about 70 wt % of at least one graft-modified polypropylene, (ii) about 10 to about 40 wt % of at least one nongrafted or graft-modified homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, styrene block copolymer, or a combination thereof and (iii) about 5 to about 50 wt % of an interpolymer of ethylene and an .alpha.,.beta.-unsaturated carbonyl copolymer, e.g. a copolymer of ethylene and acrylic acid. The polypropylene and, optionally the homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, and styrene block copolymer are grafted with an unsaturated organic compound containing at least one site of ethylenic unsaturation and at least one carbonyl group, e.g. maleic anhydride. The compositions exhibit excellent paintability with conventional paints without prior application of a primer or surface treatment, good heat resistance, good low temperature impact resistance, and they can be recycled by melt blending the compositions with thermoplastic materials, e.g., in an extruder.
    • 公开了可涂覆的热塑性聚烯烃组合物,其包含(i)约20至约70重量%的至少一种接枝改性聚丙烯,(ii)约10至约40重量%的至少一种未接枝或接枝改性的均匀支化的线型乙烯 聚合物,乙烯 - 丙烯单体橡胶,乙烯 - 丙烯 - 二烯单体橡胶,非均匀支化的线性乙烯聚合物,苯乙烯嵌段共聚物或其组合,和(iii)约5-约50wt%的乙烯和α的互聚物, β-不饱和羰基共聚物,例如 乙烯和丙烯酸的共聚物。 聚丙烯和任选的均匀支化的线性乙烯聚合物,乙烯 - 丙烯单体橡胶,乙烯 - 丙烯 - 二烯单体橡胶,非均匀支化的线性乙烯聚合物和苯乙烯嵌段共聚物用含有至少一个烯属的位点的不饱和有机化合物 不饱和键和至少一个羰基,例如 马来酸酐。 组合物在常规涂料中表现出优异的可涂色性,而无需预先施用底漆或表面处理,良好的耐热性,良好的低温耐冲击性,并且它们可以通过将组合物与热塑性材料(例如在挤出机中)熔融共混来再循环。
    • 3. 发明授权
    • Polyolefin elastomer blends exhibiting improved properties
    • 表现出改进性能的聚烯烃弹性体共混物
    • US6005053A
    • 1999-12-21
    • US784681
    • 1997-01-22
    • Deepak R. ParikhPak-Wing S. ChumRajen M. PatelKlye G. KummerPradeep JainThomas J. McKeand, Jr.Ronald P. MarkovichTimothy E. ClayfieldWasif Ahmed Khan
    • Deepak R. ParikhPak-Wing S. ChumRajen M. PatelKlye G. KummerPradeep JainThomas J. McKeand, Jr.Ronald P. MarkovichTimothy E. ClayfieldWasif Ahmed Khan
    • C08L23/04C08L23/08C08L91/00C08L33/02
    • C08L23/0815C08L2205/02C08L91/00
    • Polymer mixtures are disclosed which comprise at least one homogeneously branched ethylene polymer (A) and at least one ethylene polymer (B) having a crystallinity which is at least 7% greater than the crystallinity of polymer (A) with certain provisos. A process for making a molded article using the disclosed polymer mixtures is disclosed as well as films, film layers, coatings and molded articles formed from those mixtures. These mixtures have several advantages over polymer compositions of the prior art, including improved properties at elevated temperatures such as improved softening point under load, improved hardness, improved toughness, improved 100% modulus of elasticity, improved compression set, improved ability to prevent oil bleed out at lower temperatures when the mixture contains oil and reduced injection molding cycle time. The mixtures retain their performance advantages even when substantial amounts of additives such as oil and filler are incorporated into the mixture. The mixtures may also be crosslinked after they are formed into the shape of an article to form vulcanized elastomeric products. The polymer mixtures have utility in a variety of applications.
    • 公开了包含至少一种均匀支化的乙烯聚合物(A)和至少一种乙烯聚合物(B)的聚合物混合物,其结晶度比聚合物(A)的结晶度大至少7%,具有某些条件。 公开了使用所公开的聚合物混合物制备模塑制品的方法以及由这些混合物形成的薄膜,薄膜层,涂层和模塑制品。 这些混合物具有优于现有技术的聚合物组合物的几个优点,包括在升高的温度下改进的性能,例如负载下改进的软化点,改进的硬度,改进的韧性,改进的100%弹性模量,改进的压缩永久变形,改进的防止油渗出的能力 当混合物含有油和降低注塑周期时,在较低的温度下出来。 即使将大量的添加剂如油和填料加入到混合物中,混合物也保持其性能优势。 在混合物形成制品的形状以形成硫化的弹性体产品之后,它们也可以交联。 聚合物混合物可用于各种应用。