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    • 6. 发明授权
    • Digital duty cycle correction circuit and method for multi-phase clock
    • 数字占空比校正电路及多相时钟方法
    • US06958639B2
    • 2005-10-25
    • US10774398
    • 2004-02-10
    • Hong June ParkYoung Chan JangSeung Jun Bae
    • Hong June ParkYoung Chan JangSeung Jun Bae
    • H03K5/00H03K3/017H03K5/156
    • H03K5/1565
    • Provided is a digital duty cycle correction circuit and method for a multi-phase clock, in which duty cycle correction information of an input clock signal is stored in a power save state of a system by adopting a digital correction method in a duty cycle correction method for a multi-phase clock and phase information of the input clock signal is held constant during duty cycle correction of the input clock signal by correcting duty cycles of the input clock signal by changing the falling edge of the clock without changing the rising edge of the input clock signal during duty cycle correction of the input clock signal, thereby correcting the multi-phase clock. To this end, the digital duty cycle correction circuit includes a clock delay means that takes the form of a shunt capacitor-inverter, a clock generation means including a clock rising edge generation circuit and a clock falling edge generation circuit, and a digital duty cycle detection means including integrators, a comparator, and a counter/register.
    • 提供了一种用于多相时钟的数字占空比校正电路和方法,其中输入时钟信号的占空比校正信息在占空比校正方法中采用数字校正方法存储在系统的省电状态 对于多相时钟,输入时钟信号的相位信息在输入时钟信号的占空比校正期间通过在不改变时钟信号的上升沿的情况下改变时钟信号的下降沿来校正输入时钟信号的占空比来保持恒定 在输入时钟信号的占空比校正期间输入时钟信号,从而校正多相时钟。 为此,数字占空比校正电路包括采用并联电容器 - 反相器形式的时钟延迟装置,包括时钟上升沿产生电路和时钟下降沿产生电路的时钟产生装置和数字占空比 检测装置包括积分器,比较器和计数器/寄存器。
    • 9. 发明授权
    • High 1,4-cis polybutadiene-polyurethane copolymer and preparation method thereof
    • 高1,4-顺式聚丁二烯 - 聚氨酯共聚物及其制备方法
    • US07247695B2
    • 2007-07-24
    • US10827001
    • 2004-04-19
    • Gwang Hoon KwagSam Min KimYoung Chan JangPil Sung KimSeung Hwon LeeSeung Hwa LeeA Ju Kim
    • Gwang Hoon KwagSam Min KimYoung Chan JangPil Sung KimSeung Hwon LeeSeung Hwa LeeA Ju Kim
    • C08F36/06C08F136/06
    • C08L19/006C08C19/22C08C19/44C08F36/04C08L9/00C08L15/00C08F4/545
    • Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene. The high 1,4-cis polybutadiene-polyurethane copolymer thus obtained exhibits low cold flow and high affinity to silica or carbon black in admixture as well as excellent in elasticity and abrasion resistance: where l, m, n and o represent the number of repeating unit, 1 is 94 to 99%, m is 0 to 5%, n is 0 to 5%, l+m+n=100%, l/(m+n) is 15 to 100, o is 1 to 100%; and A and Y are C1-C20 alkyl or aryl, respectively.
    • 公开了一种新型高1,4-顺式聚丁二烯 - 聚氨酯共聚物及其制备方法。 本发明提供由下式1表示的平均分子量至少为100,000的高1,4-顺式聚丁二烯 - 聚氨酯共聚物,以及制备高1,4-顺式聚丁二烯 - 聚氨酯共聚物的方法,其包括 在非极性溶剂的存在下,用含有稀土类化合物,含卤素化合物和有机铝化合物的催化剂聚合1,3-丁二烯或丁二烯衍生物,制备具有高1,4-顺式含量的聚丁二烯 至少95%; 然后将聚氨酯基团引入聚丁二烯。 由此获得的高1,4-顺式聚丁二烯 - 聚氨酯共聚物表现出低的冷流和对二氧化硅或炭黑的高亲和性,并且具有优异的弹性和耐磨性:其中l,m,n和o表示重复的数目 单元,1为94〜99%,m为0〜5%,n为0〜5%,l + m + n = 100%,l /(m + n)为15〜100,o为1〜100% ; A和Y分别为C 1 -C 20烷基或芳基。
    • 10. 发明授权
    • Method for preparing high 1,4-cis polybutadiene having controlled cold flow
    • 制备具有受控冷流的高1,4-顺式聚丁二烯的方法
    • US06908975B2
    • 2005-06-21
    • US10653542
    • 2003-09-02
    • Young Chan JangPil Sung KimShin HanGwang Hoon KwagSeung Hwon Lee
    • Young Chan JangPil Sung KimShin HanGwang Hoon KwagSeung Hwon Lee
    • C08F36/06C08F136/06
    • C08F136/06C08F4/545
    • The present invention relates to a method for preparing a high 1,4-cis polybutadiene having a controlled cold flow and, more particularly, to a novel method for preparing a high 1,4-cis polybutadiene having a controlled cold flow that involves initiating polymerization of a 1,3-butadiene in the presence of a non-polar solvent using, as a polymerization catalyst, a complex prepared by mixing a neodymium compound with or without a conjugated diene compound, a halogenated organoaluminum compound or a halogenated organic compound, and an organoaluminum compound irrespective of the addition order of the catalyst; and adding an organoborane compound as a cold flow controller of 1,4-cis polybutadiene after a predetermined time of the polymerization. Accordingly, a high 1,4-cis polybutadiene having an efficiently controlled cold flow can be prepared without causing a significant increase in the Mooney viscosity (molecular weight), an odor (bad smell), and a reduction in 1,4-cis content and polymerization yield.
    • 本发明涉及一种制备具有受控冷流的高1,4-顺式聚丁二烯的方法,更具体地说,涉及一种制备具有控制冷流的高1,4-顺式聚丁二烯的新方法,其涉及引发聚合 使用作为聚合催化剂的非极性溶剂存在下的1,3-丁二烯,通过将钕化合物与或不与共轭二烯化合物,卤化有机铝化合物或卤化有机化合物混合制备的络合物和 有机铝化合物,而不考虑催化剂的加成顺序; 并在预定的聚合时间之后加入有机硼烷化合物作为1,4-顺式聚丁二烯的冷流控制器。 因此,可以制备具有有效控制的冷流的高的1,4-顺式聚丁二烯,而不会导致门尼粘度(分子量),气味(难闻气味)的显着增加和1,4-顺式含量的降低 和聚合产率。