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1. 发明授权

US06482930B1 Monomeric neodymium carboxylate and its use in polymerization of conjugated diene 失效
标题翻译：单体钕羧酸盐及其在共轭二烯聚合中的应用
公开(公告)号：US06482930B1
公开(公告)日：2002-11-19
申请号：US09690385
申请日：2000-10-17
申请人： Gwang Hoon Kwag , Seung Hwon Lee , Young Chan Jang , A Ju Kim
发明人： Gwang Hoon Kwag , Seung Hwon Lee , Young Chan Jang , A Ju Kim
IPC分类号： C07F500
CPC分类号： C08F236/08 , C07F5/003 , C08F236/06 , C08F4/545
摘要： The invention is related to a novel compound represented by NdHA4 wherein A is a carboxylate, and to a diene polymerization catalyst using the novel compound. NdHA4 has monomeric structure and does not contain water, bases and salts. NdHA4 is mixed with a halogen compound and an organic metal compound to prepare a catalyst system. The catalyst system in the polymerization of 1,3-butadiene (BD) or isoprene produces high cis polydiene with a high activity (100 g BD/4.0×10−5 mole Nd) and without gel formation. The polydiene thus obtained is useful for tires and golf balls and as a polystyrene modifier.
摘要翻译：本发明涉及一种由NdHA4表示的新型化合物，其中A为羧酸酯，并涉及使用该新化合物的二烯聚合催化剂。 NdHA4具有单体结构，不含水，碱和盐。将NdHA4与卤素化合物和有机金属化合物混合以制备催化剂体系。 1,3-丁二烯（BD）或异戊二烯聚合中的催化剂体系产生高活性的高顺式聚二烯（100g BD / 4.0×10-5摩尔Nd），不形成凝胶。如此获得的聚二烯可用于轮胎和高尔夫球以及作为聚苯乙烯改性剂。

2. 发明授权

US07247695B2 High 1,4-cis polybutadiene-polyurethane copolymer and preparation method thereof 有权
标题翻译：高1,4-顺式聚丁二烯 - 聚氨酯共聚物及其制备方法
公开(公告)号：US07247695B2
公开(公告)日：2007-07-24
申请号：US10827001
申请日：2004-04-19
申请人： Gwang Hoon Kwag , Sam Min Kim , Young Chan Jang , Pil Sung Kim , Seung Hwon Lee , Seung Hwa Lee , A Ju Kim
发明人： Gwang Hoon Kwag , Sam Min Kim , Young Chan Jang , Pil Sung Kim , Seung Hwon Lee , Seung Hwa Lee , A Ju Kim
IPC分类号： C08F36/06 , C08F136/06
CPC分类号： C08L19/006 , C08C19/22 , C08C19/44 , C08F36/04 , C08L9/00 , C08L15/00 , C08F4/545
摘要： Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene. The high 1,4-cis polybutadiene-polyurethane copolymer thus obtained exhibits low cold flow and high affinity to silica or carbon black in admixture as well as excellent in elasticity and abrasion resistance: where l, m, n and o represent the number of repeating unit, 1 is 94 to 99%, m is 0 to 5%, n is 0 to 5%, l+m+n=100%, l/(m+n) is 15 to 100, o is 1 to 100%; and A and Y are C1-C20 alkyl or aryl, respectively.
摘要翻译：公开了一种新型高1,4-顺式聚丁二烯 - 聚氨酯共聚物及其制备方法。本发明提供由下式1表示的平均分子量至少为100,000的高1,4-顺式聚丁二烯 - 聚氨酯共聚物，以及制备高1,4-顺式聚丁二烯 - 聚氨酯共聚物的方法，其包括在非极性溶剂的存在下，用含有稀土类化合物，含卤素化合物和有机铝化合物的催化剂聚合1,3-丁二烯或丁二烯衍生物，制备具有高1,4-顺式含量的聚丁二烯至少95％; 然后将聚氨酯基团引入聚丁二烯。由此获得的高1,4-顺式聚丁二烯 - 聚氨酯共聚物表现出低的冷流和对二氧化硅或炭黑的高亲和性，并且具有优异的弹性和耐磨性：其中l，m，n和o表示重复的数目单元，1为94〜99％，m为0〜5％，n为0〜5％，l + m + n = 100％，l /（m + n）为15〜100，o为1〜100％ ; A和Y分别为C 1 -C 20烷基或芳基。

3. 发明授权

US06506865B2 Monomeric neodymium carboxylate and its use in polymerization of conjugated diene 失效
公开(公告)号：US06506865B2
公开(公告)日：2003-01-14
申请号：US10146312
申请日：2002-05-15
申请人： Gwang Hoon Kwag , Seung Hwon Lee , Young Chan Jang , A Ju Kim
发明人： Gwang Hoon Kwag , Seung Hwon Lee , Young Chan Jang , A Ju Kim
IPC分类号： C08F452
CPC分类号： C08F236/08 , C07F5/003 , C08F236/06 , C08F4/545
摘要： The invention is related to a novel compound represented by NdHA4 wherein A is a carboxylate, and to a diene polymerization catalyst using the novel compound. NdHA4 has monomeric structure and does not contain water, bases and salts. NdHA4 is mixed with a halogen compound and an organic metal compound to prepare a catalyst system. The catalyst system in the polymerization of 1,3-butadiene (BD) or isoprene produces high cis polydiene with a high activity (100 g BD/4.0×10−5 mole Nd) and without gel formation. The polydiene thus obtained is useful for tires and golf balls and as a polystyrene modifier.

4. 发明授权

US06451934B1 Process for preparation of high 1,4-CIS polybutadiene 有权
标题翻译：制备高分子量的1,4-丁二烯丁二烯的方法
公开(公告)号：US06451934B1
公开(公告)日：2002-09-17
申请号：US09539999
申请日：2000-03-30
申请人： Young Chan Jang , A Ju Kim , Gwang Hoon Kwag , Seung Hwon Lee
发明人： Young Chan Jang , A Ju Kim , Gwang Hoon Kwag , Seung Hwon Lee
IPC分类号： C08F452
CPC分类号： C08F136/06 , C08F4/7098 , C08F4/545
摘要： This invention relates to a process for preparation of high 1,4-cis polybutadiene and more particularly, to the process for preparing polybutadiene by polymerizing 1,3-butadiene monomer in the presence of a catalyst prepared by aging a mixture of a neodymium salt compound, a nickel salt compound, an organoaluminium compound and a borontrifluoride complex compound in the presence or absence of a conjugated diene compound. With much remarked catalytic activity, polybutadiene with a very high 1,4-cis content can be prepared in a high yield using a small amount of catalyst.
摘要翻译：本发明涉及一种制备高1,4-顺式聚丁二烯的方法，更具体地说，涉及通过在催化剂存在下聚合1,3-丁二烯单体制备聚丁二烯的方法，所述催化剂是将钕盐化合物，镍盐化合物，有机铝化合物和三氟化硼配位化合物，在共轭二烯化合物存在或不存在下。具有非常显着的催化活性，可以使用少量催化剂以高产率制备具有非常高的1,4-顺式含量的聚丁二烯。

5. 发明授权

US6136931A Process for preparing polybutadiene using catalyst with high activity 有权
标题翻译：使用高活性的催化剂制备聚丁二烯的方法
公开(公告)号：US6136931A
公开(公告)日：2000-10-24
申请号：US433073
申请日：1999-11-03
申请人： Young Chan Jang , Gwang Hoon Kwag , A Ju Kim , Seung Hwon Lee
发明人： Young Chan Jang , Gwang Hoon Kwag , A Ju Kim , Seung Hwon Lee
IPC分类号： C08F4/14 , C08F4/54 , C08F136/06 , C08F4/52
CPC分类号： C08F136/06
摘要： This invention relates to a process for preparing polybutadiene with high 1,4-cis content (over 97%) and high conversion (over 90%) in such a manner that 1,3-butadiene is polymerized using an aging catalyst, which has high homogeneity due to its excellent solubility in non-polar solvents, resulting in producing polybutadiene having low gel content and low solution viscosity. The aging catalyst is a mixture of a neodymium compound, an organoaluminum compound and a borontrifluoride complex, which is represented by the formula I or the formula II, in the presence or absence of a small portion of conjugated diene compound:Formula I is represented byBF.sub.3 OR.sub.1 R.sub.2wherein R.sub.1 and R.sub.2 can be the same or different, and are independent substituents, respectively which are alkyl, cycloalkyl, allyl, aryl or arylalkyl groups containing from 1 to 10 carbon atoms; andFormula II is represented by ##STR1## wherein R.sub.3 is an alkyl group containing from 2 to 10 carbon atoms.
摘要翻译：本发明涉及一种具有高1,4-顺式含量（超过97％）和高转化率（超过90％）的聚丁二烯的方法，使得使用老化催化剂聚合1,3-丁二烯，该催化剂具有高均匀性由于其在非极性溶剂中的优异溶解度，导致生产具有低凝胶含量和低溶液粘度的聚丁二烯。老化催化剂是在存在或不存在少量共轭二烯化合物的情况下由式I或式II表示的钕化合物，有机铝化合物和三氟化硼络合物的混合物：式I由 BF 3 OR 1 R 2，其中R 1和R 2可以相同或不同，并且分别是含有1至10个碳原子的烷基，环烷基，烯丙基，芳基或芳烷基的独立取代基; 式II表示为其中R 3为含有2至10个碳原子的烷基。

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