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1. 发明授权

US07651802B2 Solid polymer electrolyte, proton conductive membrane, electrode electrolyte, electrode paste and membrane-electrode assembly 有权
标题翻译：固体聚合物电解质，质子传导膜，电极电解质，电极膏和膜电极组件
公开(公告)号：US07651802B2
公开(公告)日：2010-01-26
申请号：US11375141
申请日：2006-03-15
申请人： Yoshitaka Yamakawa , Toshihiro Ohtsuki , Kohei Goto , Toshiaki Kadota , Teruhiko Umehara , Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
发明人： Yoshitaka Yamakawa , Toshihiro Ohtsuki , Kohei Goto , Toshiaki Kadota , Teruhiko Umehara , Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
IPC分类号： H01M8/10 , C08J5/20 , C08G65/34
CPC分类号： H01M8/1023 , C08J5/2256 , C08J2371/12 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M2300/0082
摘要： Disclosed is a polymer electrolyte having a protonic acid group that is excellent in thermal stability and dimensional stability. The polymer electrolyte includes copolymers having a sulfonic acid group which has a structure represented by the following formula: wherein X is a divalent electron-withdrawing group; Y is an oxygen or a sulfur; Z and Q are each a direct bond, —O—, —S—, —CO—, —SO2—, —[C(R′)2]g— (g: integer of from 1 to 8), etc.; R, R′ and R1 to R16 are each a hydrogen, a fluorine, an alkyl, a fluorine-substituted alkyl, an aryl or a nitrile; m, n, p, q, r, s, t and u are each an integer of from 0 to 4 (with the proviso that p+q≧1); and A is a group represented by Formula (5a) or (5b) below: wherein W is a divalent electron-withdrawing group; S is a protonic acid group; i is an integer of from 1 to 5; and j is an integer of from 1 to 7.
摘要翻译：公开了具有优异的热稳定性和尺寸稳定性的质子酸基团的高分子电解质。聚合物电解质包括具有由下式表示的结构的磺酸基的共聚物：其中X是二价吸电子基团; Y是氧或硫; Z和Q各自为直接键，-O - ， - S - ， - CO - ， - SO 2 - ， - [C（R'）2] g-（g：1至8的整数）等; R，R'和R 1至R 16各自为氢，氟，烷基，氟取代的烷基，芳基或腈; m，n，p，q，r，s，t和u各自为0至4的整数（条件是p + q> = 1）; A是由下式（5a）或（5b）表示的基团：其中W是二价吸电子基团; S是质子酸基团; 我是1到5的整数; j为1〜7的整数。

2. 发明申请

US20060216566A1 Solid polymer electrolyte, proton conductive membrane, electrode electrolyte, electrode paste and membrane-electrode assembly 有权
标题翻译：固体聚合物电解质，质子传导膜，电极电解质，电极膏和膜电极组件
公开(公告)号：US20060216566A1
公开(公告)日：2006-09-28
申请号：US11375141
申请日：2006-03-15
申请人： Yoshitaka Yamakawa , Toshihiro Ohtsuki , Kohei Goto , Toshiaki Kadota , Teruhiko Umehara , Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
发明人： Yoshitaka Yamakawa , Toshihiro Ohtsuki , Kohei Goto , Toshiaki Kadota , Teruhiko Umehara , Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
IPC分类号： H01M8/10 , C08J5/20
CPC分类号： H01M8/1023 , C08J5/2256 , C08J2371/12 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M2300/0082
摘要： Disclosed is a polymer electrolyte having a protonic acid group that is excellent in thermal stability and dimensional stability. The polymer electrolyte includes copolymers having a sulfonic acid group which has a structure represented by the following formula: wherein X is a divalent electron-withdrawing group; Y is an oxygen or a sulfur; Z and Q are each a direct bond, —O—, —S—, —CO—, —SO2—, —[C(R′)2]g— (g: integer of from 1 to 8), etc.; R, R′ and R1 to R16 are each a hydrogen, a fluorine, an alkyl, a fluorine-substituted alkyl, an aryl or a nitrile; m, n, p, q, r, s, t and u are each an integer of from 0 to 4 (with the proviso that p+q≧1); and A is a group represented by Formula (5a) or (5b) below: wherein W is a divalent electron-withdrawing group; S is a protonic acid group; i is an integer of from 1 to 5; and j is an integer of from 1 to 7.
摘要翻译：公开了具有优异的热稳定性和尺寸稳定性的质子酸基团的高分子电解质。聚合物电解质包括具有由下式表示的结构的磺酸基的共聚物：其中X是二价吸电子基团; Y是氧或硫; Z和Q各自为直接键，-O - ， - S - ， - CO - ， - SO 2 - ， - [C（R'）2 < （g：1〜8的整数）等; R，R'和R 1至R 16各自为氢，氟，烷基，氟取代的烷基，芳基或腈; m，n，p，q，r，s，t和u各自为0至4的整数（条件是p + q> = 1）; A是由式（5a）或（5b）表示的基团：其中W是二价吸电子基团; S是质子酸基团; 我是1到5的整数; j为1〜7的整数。

3. 发明授权

US07163988B2 Aromatic sulfonic acid ester derivative, polyarylene, polyarylene having sulfonic acid group and process for producing the same, and polymer solid electrolyte and proton-conductive membrane 有权
标题翻译：芳族磺酸酯衍生物，聚亚芳基，具有磺酸基的聚亚芳基及其制备方法，以及聚合物固体电解质和质子传导膜
公开(公告)号：US07163988B2
公开(公告)日：2007-01-16
申请号：US10642694
申请日：2003-08-19
申请人： Igor Rozhanskii , Masayuki Takahashi , Kohei Goto , Yousuke Konno , Toshihiro Ohtsuki , Yoshitaka Yamakawa , Toshiaki Kadota
发明人： Igor Rozhanskii , Masayuki Takahashi , Kohei Goto , Yousuke Konno , Toshihiro Ohtsuki , Yoshitaka Yamakawa , Toshiaki Kadota
IPC分类号： C08F283/08 , C08G61/10
CPC分类号： C08G61/12 , C07C309/73 , C07C309/75
摘要： Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, —OSO3CH3 and —OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, Ra is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of —SO3Rb (wherein Rb is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.
摘要翻译：公开了由式（1）表示的芳族磺酸酯衍生物; 在该式中，X是选自除氟以外的卤素原子的原子或基团，-OSO 3 CH 3和-OSO 3 CF A是二价吸电子基团，B是二价给电子基团或直接键合，R a是1-20个碳原子的烃基，Ar 是具有-SO 3 R b的取代基的芳香族基团（其中R b为1〜20个碳原子的烃基）， m为0〜10的整数，n为0〜10的整数，k为1〜4的整数。还公开了具有磺酸基的聚亚芳基的制造方法，该方法包括使聚合的含有式（1）的衍生物的芳族化合物，以制备聚亚芳基并且聚亚芳基的水解，并且该方法具有高安全性并且易于控制引入聚合物的磺酸基团的量和引入位置那里 F。

4. 发明授权

US08349994B2 Electrode electrolyte for polymer-type fuel cell, and use thereof 有权
标题翻译：用于聚合物型燃料电池的电极电解质及其用途
公开(公告)号：US08349994B2
公开(公告)日：2013-01-08
申请号：US12600801
申请日：2008-05-16
申请人： Toshiaki Kadota , Yoshitaka Yamakawa , Fusao Nakagawa , Nagayuki Kanaoka , Takaki Nakagawa
发明人： Toshiaki Kadota , Yoshitaka Yamakawa , Fusao Nakagawa , Nagayuki Kanaoka , Takaki Nakagawa
IPC分类号： C08G75/00
CPC分类号： C08G65/4037 , C08G65/4006 , C08G65/4025 , C08G65/4056 , C08J5/2256 , C08J5/2262 , C08J2387/00 , H01M4/8668 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.
摘要翻译：公开了一种固体高分子型燃料电池用电极电解质，其使用含有含有-SO 3 H， - （O（CH 2）h SO 3 H或-O（CF 2）h SO 3 H（-O（CH 2）h SO 3 H）表示的取代基的含氮芳香环的聚亚芳基共聚物的聚合物电解质其中h表示1-12的整数），通过这样构成，能够以低成本制造固体高分子型燃料电池用电极电解质，同时质子传导性，尺寸稳定性，耐水热性和机械强度优异。此外，用于固体聚合物燃料电池的该电极电解质能够回收催化剂金属。

5. 发明申请

US20100167161A1 ELECTRODE ELECTROLYTE FOR POLYMER-TYPE FUEL CELL, AND USE THEREOF 有权
标题翻译：用于聚合物型燃料电池的电极电解质及其用途
公开(公告)号：US20100167161A1
公开(公告)日：2010-07-01
申请号：US12600801
申请日：2008-05-16
申请人： Toshiaki Kadota , Yoshitaka Yamakawa , Fusao Nakagawa , Nagayuki Kanaoka , Takaki Nakagawa
发明人： Toshiaki Kadota , Yoshitaka Yamakawa , Fusao Nakagawa , Nagayuki Kanaoka , Takaki Nakagawa
IPC分类号： H01M8/10
CPC分类号： C08G65/4037 , C08G65/4006 , C08G65/4025 , C08G65/4056 , C08J5/2256 , C08J5/2262 , C08J2387/00 , H01M4/8668 , H01M8/1023 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M2300/0082 , Y02P70/56
摘要： Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.
摘要翻译：公开了一种固体高分子型燃料电池用电极电解质，其使用含有含有-SO 3 H， - （O（CH 2）h SO 3 H或-O（CF 2）h SO 3 H（-O（CH 2）h SO 3 H）表示的取代基的含氮芳香环的聚亚芳基共聚物的聚合物电解质其中h表示1-12的整数），通过这样构成，能够以低成本制造固体高分子型燃料电池用电极电解质，同时质子传导性，尺寸稳定性，耐水热性和机械强度优异。此外，用于固体聚合物燃料电池的该电极电解质能够回收催化剂金属。

6. 发明授权

US08043762B2 Polyphenylene-containing electrode paste 有权
标题翻译：含聚苯撑的电极糊
公开(公告)号：US08043762B2
公开(公告)日：2011-10-25
申请号：US11995701
申请日：2006-06-30
申请人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
发明人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
IPC分类号： H01M8/10
CPC分类号： C08G61/02 , C08G73/028 , C08J5/2256 , C08J2371/12 , H01M4/8652 , H01M4/8807 , H01M4/92 , H01M4/926 , H01M8/0239 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/106
摘要： The present invention provides an electrode paste which comprises catalyst particles, a solvent and an varnish which comprises a solvent and an electrode electrolyte for a solid polymer fuel cell electrolyte, wherein the electrode electrolyte comprises a polymer with a structure having a main chain including a polyphenylene, a side chain including a sulfonic acid group and a repeating structural unit represented by formula (C) as a side chain including a nitrogen-containing heterocyclic group; wherein the structural variables are defined herein.
摘要翻译：本发明提供一种电极糊料，其包含催化剂颗粒，溶剂和清漆，其包含溶剂和用于固体聚合物燃料电池电解质的电极电解质，其中所述电极电解质包含具有主链的聚合物，所述主链包含聚亚苯基，包含磺酸基的侧链和由式（C）表示的重复结构单元作为包含含氮杂环基的侧链; 其中结构变量在本文中定义。

7. 发明授权

US08399148B2 Varnish for a solid polymer fuel cell 有权
标题翻译：固体聚合物燃料电池的清漆
公开(公告)号：US08399148B2
公开(公告)日：2013-03-19
申请号：US13205177
申请日：2011-08-08
申请人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
发明人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
IPC分类号： H01M8/10
CPC分类号： C08G61/02 , C08G73/028 , C08J5/2256 , C08J2371/12 , H01M4/8652 , H01M4/8807 , H01M4/92 , H01M4/926 , H01M8/0239 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/106
摘要： Provided is a varnish which contains a solvent and an electrode electrolyte for a solid polymer fuel cell electrolyte, which contains a polymer with a structure having a main chain including a polyphenylene, a side chain including a sulfonic acid group and a repeating structural unit as a side chain including a nitrogen-containing heterocyclic group.
摘要翻译：提供一种清漆，其含有固体高分子型燃料电池用电解质的溶剂和电极电解质，其含有具有主链的聚合物，所述主链包含聚亚苯基，包含磺酸基的侧链和重复结构单元作为侧链包括含氮杂环基。

8. 发明申请

US20120040271A1 ELECTRODE ELECTROLYTE FOR SOLID POLYMER-TYPE FUEL CELL 有权
标题翻译：用于固体聚合物型燃料电池的电极电解质
公开(公告)号：US20120040271A1
公开(公告)日：2012-02-16
申请号：US13205177
申请日：2011-08-08
申请人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
发明人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
IPC分类号： H01M8/10
CPC分类号： C08G61/02 , C08G73/028 , C08J5/2256 , C08J2371/12 , H01M4/8652 , H01M4/8807 , H01M4/92 , H01M4/926 , H01M8/0239 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/106
摘要： An electrode electrolyte for a solid polymer electrolyte-type fuel cell contains a polymer, which has a polyphenylene structure as a main chain and both a sulfonic acid group and a nitrogen-containing heterocyclic group as a side chain. A side chain having the nitrogen-containing heterocyclic group has a structure represented by the following general formula (D). where Z represents at least one kind of structures selected from a group consisting of a direct bond, —O— and —S—, Y represents at least one member selected from a group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)1— (1 is an integer of 1 to 10) and —C(CF3)2, R20 represents a specified nitrogen-containing heterocyclic group, q represents an integer of 1 to 5 and p represents an integer of 0 to 4.
摘要翻译：固体高分子电解质型燃料电池用电极电解质含有作为主链的聚亚苯基结构和磺酸基和含氮杂环基作为侧链的聚合物。具有含氮杂环基的侧链具有由以下通式（D）表示的结构。其中Z表示选自由直接键，-O-和-S-组成的组中的至少一种结构，Y表示选自-CO - ， - SO 2 - ， - SO 2 - 的至少一种，，-CONH-，-COO - ， - （CF 2）1 - （1为1〜10的整数）和-C（CF 3）2，R 20表示规定的含氮杂环基，q表示1〜 5，p表示0〜4的整数。

9. 发明申请

US20090130526A1 ELECTRODE ELECTROLYTE FOR USE IN SOLID POLYMER FUEL CELL 有权
标题翻译：用于固体聚合物燃料电池的电极电解质
公开(公告)号：US20090130526A1
公开(公告)日：2009-05-21
申请号：US11995701
申请日：2006-06-30
申请人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
发明人： Makoto Higami , Igor Rozhanskii , Yoshitaka Yamakawa , Nagayuki Kanaoka , Kaoru Fukuda , Ryoichiro Takahashi , Hiroshi Shinkai
IPC分类号： H01M8/10
CPC分类号： C08G61/02 , C08G73/028 , C08J5/2256 , C08J2371/12 , H01M4/8652 , H01M4/8807 , H01M4/92 , H01M4/926 , H01M8/0239 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/106
摘要： This invention provides an electrode electrolyte for a solid polymer-type fuel cell, in which a cost problem and a problem related to recovery of catalyst metals are solved, having excellent proton conductivity, dimensional stability and heat resistance.An electrode electrolyte for a solid polymer electrolyte-type fuel cell contains a polymer, which has a polyphenylene structure as a main chain and both a sulfonic acid group and a nitrogen-containing heterocyclic group as a side chain. A side chain having the nitrogen-containing heterocyclic group has a structure represented by the following general formula (D). (In formula, Z represents at least one kind of structures selected from a group consisting of a direct bond, —O— and —S—, Y represents at least one kind of structures selected from a group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)1— (1 is an integer of 1 to 10) and —C(CF3)2— and R20 represents a nitrogen-containing heterocyclic group. q represents an integer of 1 to 5 and p represents an integer of 0 to 4.)The above nitrogen-containing heterocyclic group is at least one kind of group derived from a compound selected from the group consisting of nitrogen-containing heterocyclic compounds including pyrrole, thiazole, isothiazole, oxazole, isoxazole, pyridine, imidazole, imidazoline, pyrazole, 1,3,5-triazine, pyrimidine, pyridazine, pyrazine, indole, quinoline, isoquinoline, purine, benzimidazole, benzoxazole, benzothiazole, tetrazole, tetrazine, triazole, carbazole, acridine, quinoxaline and quinazoline and derivatives thereof.
摘要翻译：本发明提供一种固体聚合物型燃料电池用电极电解质，其中解决了成本问题和与催化剂金属的回收相关的问题，具有优异的质子传导性，尺寸稳定性和耐热性。固体高分子电解质型燃料电池用电极电解质含有作为主链的聚亚苯基结构和磺酸基和含氮杂环基作为侧链的聚合物。具有含氮杂环基的侧链具有由以下通式（D）表示的结构。（式中，Z表示选自由直链，-O-和-S-组成的组中的至少一种结构，Y表示选自-CO - ， - SO 2的至少一种结构 - ， - SO - ， - CONH - ， - COO - ， - （CF 2）1 - （1为1〜10的整数）和-C（CF 3）2 - ，R 20为含氮杂环基 1〜5的整数，p表示0〜4的整数。）上述含氮杂环基是选自包含吡咯，噻唑等含氮杂环化合物的化合物中的至少一种异噻唑，恶唑，异恶唑，吡啶，咪唑，咪唑啉，吡唑，1,3,5-三嗪，嘧啶，哒嗪，吡嗪，吲哚，喹啉，异喹啉，嘌呤，苯并咪唑，苯并恶唑，苯并噻唑四唑，四嗪，三唑，，吖啶，喹喔啉和喹唑啉及其衍生物。

10. 发明申请

US20100174042A1 AROMATIC COMPOUND AND SULFONATED POLYARYLENE POLYMER 有权
标题翻译：芳香化合物和磺化聚亚烷基聚合物
公开(公告)号：US20100174042A1
公开(公告)日：2010-07-08
申请号：US12298385
申请日：2007-04-24
申请人： Yoshitaka Yamakawa , Yousuke Konno , Teruhiko Umehara
发明人： Yoshitaka Yamakawa , Yousuke Konno , Teruhiko Umehara
IPC分类号： C08G8/02 , C07C49/317 , C07C255/51 , C08G75/24
CPC分类号： C07C49/84 , C07C45/71 , C07C255/54 , C07C2603/18 , C08G65/40 , C08G65/4012 , C08G65/4031 , C08J5/2231 , C08J2365/02 , H01M8/0289 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , Y02E60/523
摘要： Sulfonated polymers have excellent processability and methanol resistance.An aromatic compound is represented by Formula (1) below: wherein A, D and E are each at least one structure selected from the group consisting of a direct bond, —O—, —S—, —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)f— (wherein f is an integer of 1 to 10), —(CH2)h— (wherein h is an integer of 1 to 10), —CR′2— (wherein R′ is an aliphatic hydrocarbon group, an aromatic hydrocarbon group or a halogenated hydrocarbon group), a cyclohexylidene group and a fluorenylidene group; each B is independently an oxygen atom or a sulfur atom; X is an atom or a group selected from halogen atoms other than fluorine, —OSO2CH3 and —OSO2CF3; R1 to R28 are the same or different from one another and are each at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, alkyl groups, partially or completely halogenated alkyl groups, allyl groups, aryl groups, nitro group and nitrile group; l and o are each an integer of 0 to 4; m is an integer of 1 to 4; q is an integer of 2 or greater; n and p indicate a composition ratio of the respective units and are each a number ranging from 0 to 1; n+p=1; and n is not 0.
摘要翻译：磺化聚合物具有优异的加工性和耐甲醇性。芳族化合物由下式（1）表示：其中A，D和E各自为至少一个选自直接键，-O - ， - S-，-CO-，-SO 2 - 的结构， - （CH 2）h - （其中h为1至10的整数），-CR（CH 2）n - ， - （CF 2）f - （其中f为1至10的整数） '2-（其中R'是脂族烃基，芳族烃基或卤代烃基），亚环己基和亚芴基; 每个B独立地是氧原子或硫原子; X是选自氟以外的卤素原子，-OSO 2 CH 3和-OSO 2 CF 3的原子或基团; R1至R28彼此相同或不同，并且各自为至少一个选自氢原子，氟原子，烷基，部分或完全卤化的烷基，烯丙基，芳基，硝基和腈基; l和o分别为0〜4的整数; m为1〜4的整数。 q是2或更大的整数; n和p表示各单元的组成比，分别为0〜1的数。 n + p = 1; 并且n不为0。

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