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1. 发明申请

US20060154039A1 Carbon fiber-reinforced resin composite materials 有权
公开(公告)号：US20060154039A1
公开(公告)日：2006-07-13
申请号：US10543137
申请日：2004-01-28
申请人： Yoshinori Suzuki , Yutaka Miura , Katsura Horikoshi , Mitsuhiro Yada
发明人： Yoshinori Suzuki , Yutaka Miura , Katsura Horikoshi , Mitsuhiro Yada
IPC分类号： D04H13/00
CPC分类号： C08J5/24 , C08G59/1461 , Y10T428/249924 , Y10T428/2913 , Y10T428/2933
摘要： The present invention discloses: a composition comprising (A) an epoxy group-containing vinyl ester resin having, in the molecule, 0.8 to 0.3 equivalent of epoxy group and 0.2 to 0.7 equivalent of an ethylenically unsaturated group, (B) a radical-polymerizable monomer, (C) a curing agent, and (D) a carbon fiber impregnated with 0.5 to 5% by mass of (d) a vinyl ester resin as a sizing agent, obtained by an addition reaction of an epoxy resin and an ethylenically unsaturated carboxylic acid, and a carbon fiber-reinforced resin composite material produced by curing the above composition.

2. 发明授权

US07585558B2 Carbon fiber-reinforced resin composite materials 有权
标题翻译：碳纤维增强树脂复合材料
公开(公告)号：US07585558B2
公开(公告)日：2009-09-08
申请号：US10543137
申请日：2004-01-28
申请人： Yoshinori Suzuki , Yutaka Miura , Katsura Horikoshi , Mitsuhiro Yada
发明人： Yoshinori Suzuki , Yutaka Miura , Katsura Horikoshi , Mitsuhiro Yada
IPC分类号： D04H13/00
CPC分类号： C08J5/24 , C08G59/1461 , Y10T428/249924 , Y10T428/2913 , Y10T428/2933
摘要： The present invention discloses: a composition comprising (A) an epoxy group-containing vinyl ester resin having, in the molecule, 0.8 to 0.3 equivalent of epoxy group and 0.2 to 0.7 equivalent of an ethylenically unsaturated group, (B) a radical-polymerizable monomer, (C) a curing agent, and (D) a carbon fiber impregnated with 0.5 to 5% by mass of (d) a vinyl ester resin as a sizing agent, obtained by an addition reaction of an epoxy resin and an ethylenically unsaturated carboxylic acid, and a carbon fiber-reinforced resin composite material produced by curing the above composition.
摘要翻译：本发明公开了一种组合物，其包含（A）含有环氧基的乙烯基酯树脂，其分子中具有0.8〜0.3当量的环氧基和0.2〜0.7当量的烯键式不饱和基，（B）可自由基聚合单体，（C）固化剂，（D）浸渍有0.5〜5质量％的（d）乙烯基酯树脂作为上胶剂的碳纤维，其通过环氧树脂和烯属不饱和基团的加成反应得到羧酸和通过固化上述组合物制备的碳纤维增强树脂复合材料。

3. 发明授权

US09181217B2 Method for producing optically active naphthalene compound 有权
标题翻译：光学活性萘化合物的制造方法
公开(公告)号：US09181217B2
公开(公告)日：2015-11-10
申请号：US14240466
申请日：2012-08-24
申请人： Koji Matsuyama , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Koichi Tanimoto
发明人： Koji Matsuyama , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Koichi Tanimoto
IPC分类号： C07B53/00 , C07C25/06 , C07C255/03 , C07D401/04
CPC分类号： C07D401/04 , C07B53/00 , C07C25/06 , C07C255/03
摘要： The present invention provides an industrially advantageous method for producing an optically active naphthalene compound useful as a therapeutic agent for dermatitis or the like. Specifically, the present invention provides a method for producing an optically active naphthalene compound [I], which comprises: a step of reacting a compound [a-1] and a compound [b-1] with each other in the presence of a base and a catalyst that is composed of a Pd compound and a tertiary phosphine ligand (step a); a step of asymmetrically hydrogenating a compound [c-1] in the presence of a hydrogen donor and a complex that is prepared from a ruthenium compound and a chiral ligand, or alternatively in the presence of an optically active oxazaborolidine compound (a CBS catalyst) and a boron hydride compound (step b); and a step of treating a compound [d-1] with a reducing agent (step c). (In the above formulae, Ra and Rb represent the same or different lower alkyl groups; and X1 represents a halogen atom.).
摘要翻译：本发明提供了用于制造用作皮炎等的治疗剂的光学活性萘化合物的工业上有利的方法。具体而言，本发明提供了一种光学活性萘化合物[I]的制造方法，其特征在于，在碱的存在下，使化合物[a-1]和化合物[b-1] 和由Pd化合物和叔膦配体组成的催化剂（步骤a）; 在氢供体和由钌化合物和手性配体制备的络合物的存在下，或者在光学活性的恶唑硼烷化合物（CBS催化剂）存在下，不对称地氢化化合物[c-1] 和硼氢化合物（步骤b）; 和用还原剂处理化合物[d-1]（步骤c）的步骤。（上述式中，Ra和Rb表示相同或不同的低级烷基，X1表示卤素原子。

4. 发明申请

US20050261458A1 Polycarboxylic acid resin, polycarboxylic acid resin composition, and cured article obtained therefrom 审中-公开
标题翻译：聚羧酸树脂，聚羧酸树脂组合物和由其获得的固化物
公开(公告)号：US20050261458A1
公开(公告)日：2005-11-24
申请号：US10522979
申请日：2003-06-13
申请人： Shu Guo , Takuya Kikawa , Mitsuhiro Yada , Yoshikazu Hosoda
发明人： Shu Guo , Takuya Kikawa , Mitsuhiro Yada , Yoshikazu Hosoda
IPC分类号： C08G59/14 , C08F299/02 , C08G59/20 , C08G59/42 , C08G63/21 , C08G63/46 , C08G63/47 , C08G63/58 , C08G63/66 , C08G63/91 , G03F7/00 , G03F7/027 , G03F7/032 , G03F7/038 , C08G65/00 , C08G63/42
CPC分类号： C08G63/47 , C08G59/42 , C08G59/4292 , C08G63/58 , C08G63/66 , C08G63/91 , G03F7/0007 , G03F7/027 , G03F7/032 , G03F7/038 , G03F7/0388
摘要： To provide a polycarboxylic acid resin which is obtained by reacting an epoxy resin (a) having two glycidyl groups with, e.g. itaconic acid (b) and ethylenic monocarboxylic acid (c) to obtain linear adduct polymer (A); and by reacting linear adduct polymer (A) with polybasic acid anhydride (d). According to the present invention, there are provided a polycarboxylic acid resin, its composition, and its cured product. The composition can facilely be dried upon preliminary heating and show an improved tack-free property, an excellent photo-curing property, an excellent development property in an aqueous alkali solution, and excellent physical properties such as electrical, mechanical, heat resistance, solvent resistance, adhesiveness, flexibility, etc.
摘要翻译：提供通过使具有两个缩水甘油基的环氧树脂（a）与例如二甲基甲酰胺反应获得的多元羧酸树脂。衣康酸（b）和乙烯基单羧酸（c），得到线性加合物聚合物（A）; 并通过使线性加合物聚合物（A）与多元酸酐（d）反应。根据本发明，提供了多元羧酸树脂及其组合物及其固化产物。组合物可以在预热下容易地干燥，显示出改善的无粘性，优异的光固化性，碱性水溶液中的显影性优异，以及优异的物理性能如电，机械，耐热性，耐溶剂性，粘合性，柔韧性等

5. 发明申请

US20150152082A1 METHOD FOR PRODUCING OPTICALLY ACTIVE NAPHTHALENE COMPOUND 有权
标题翻译：用于生产光学活性萘基化合物的方法
公开(公告)号：US20150152082A1
公开(公告)日：2015-06-04
申请号：US14240466
申请日：2012-08-24
申请人： Koji Matsuyama , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Koichi Tanimoto
发明人： Koji Matsuyama , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Koichi Tanimoto
IPC分类号： C07D401/04 , C07C255/03 , C07C25/06
CPC分类号： C07D401/04 , C07B53/00 , C07C25/06 , C07C255/03
摘要： The present invention provides an industrially advantageous method for producing an optically active naphthalene compound useful as a therapeutic agent for dermatitis or the like. Specifically, the present invention provides a method for producing an optically active naphthalene compound [I], which comprises: a step of reacting a compound [a-1] and a compound [b-1] with each other in the presence of a base and a catalyst that is composed of a Pd compound and a tertiary phosphine ligand (step a); a step of asymmetrically hydrogenating a compound [c-1] in the presence of a hydrogen donor and a complex that is prepared from a ruthenium compound and a chiral ligand, or alternatively in the presence of an optically active oxazaborolidine compound (a CBS catalyst) and a boron hydride compound (step b); and a step of treating a compound [d-1] with a reducing agent (step c). (In the above formulae, Ra and Rb represent the same or different lower alkyl groups; and X1 represents a halogen atom.)
摘要翻译：本发明提供了用于制造用作皮炎等的治疗剂的光学活性萘化合物的工业上有利的方法。具体而言，本发明提供了一种光学活性萘化合物[I]的制造方法，其特征在于，在碱的存在下，使化合物[a-1]和化合物[b-1] 和由Pd化合物和叔膦配体组成的催化剂（步骤a）; 在氢供体和由钌化合物和手性配体制备的络合物的存在下，或者在光学活性的恶唑硼烷化合物（CBS催化剂）存在下，不对称地氢化化合物[c-1] 和硼氢化合物（步骤b）; 和用还原剂处理化合物[d-1]（步骤c）的步骤。（上式中，Ra和Rb表示相同或不同的低级烷基，X1表示卤素原子。）

6. 发明申请

US20080108726A1 POLYCARBOXYLIC ACID RESINS, THEIR COMPOSITIONS, AND THEIR CURED PRODUCTS 审中-公开
标题翻译：聚碳酸树脂，其组合物及其固化产品
公开(公告)号：US20080108726A1
公开(公告)日：2008-05-08
申请号：US11876016
申请日：2007-10-22
申请人： Shu Guo , Takuya Kikawa , Mitsuhiro Yada , Yoshikazu Hosoda
发明人： Shu Guo , Takuya Kikawa , Mitsuhiro Yada , Yoshikazu Hosoda
IPC分类号： C08G63/42 , C08G65/00
CPC分类号： C08G63/47 , C08G59/42 , C08G59/4292 , C08G63/58 , C08G63/66 , C08G63/91 , G03F7/0007 , G03F7/027 , G03F7/032 , G03F7/038 , G03F7/0388
摘要： To provide a polycarboxylic acid resin which is obtained by reacting an epoxy resin (a) having two glycidyl groups with, e.g. itaconic acid (b) and ethylenic monocarboxylic acid (c) to obtain linear adduct polymer (A); and by reacting linear adduct polymer (A) with polybasic acid anhydride (d). According to the present invention, there are provided a polycarboxylic acid resin, its composition, and its cured product. The composition can facilely be dried upon preliminary heating and show an improved tack-free property, an excellent photo-curing property, an excellent development property in an aqueous alkali solution, and excellent physical properties such as electrical, mechanical, heat resistance, solvent resistance, adhesiveness, flexibility, etc.
摘要翻译：提供通过使具有两个缩水甘油基的环氧树脂（a）与例如二甲基甲酰胺反应获得的多元羧酸树脂。衣康酸（b）和乙烯基单羧酸（c），得到线性加合物聚合物（A）; 并通过使线性加合物聚合物（A）与多元酸酐（d）反应。根据本发明，提供了多元羧酸树脂及其组合物及其固化产物。组合物可以在预热下容易地干燥，显示出改善的无粘性，优异的光固化性，碱性水溶液中的显影性优异，以及优异的物理性能如电，机械，耐热性，耐溶剂性，粘合性，柔韧性等

7. 发明授权

US6017588A Method for reinforcing structures 失效
标题翻译：加固结构的方法
公开(公告)号：US6017588A
公开(公告)日：2000-01-25
申请号：US30755
申请日：1998-02-25
申请人： Takeshi Watanabe , Hiroaki Katano , Tsuneo Tanaka , Joji Shibata , Mitsuhiro Yada , Takeshi Nemoto
发明人： Takeshi Watanabe , Hiroaki Katano , Tsuneo Tanaka , Joji Shibata , Mitsuhiro Yada , Takeshi Nemoto
IPC分类号： C08G59/22 , C08G59/62 , C08L63/00 , E04C5/07 , B29C63/00 , B05D7/24 , B32B27/08 , B32B27/12
CPC分类号： E04G23/0218 , C08G59/226 , C08G59/623 , C08L63/00 , E04C5/07
摘要： The present invention relates to a method for reinforcing a structure comprising the steps of forming a primer layer on the surface of a structure to be reinforced; forming if necessary a putty layer on the primer layer; applying an impregnating resin on the formed primer layer provided that the putty layer in case where the putty layer is formed on the primer layer, before, after or before and after cladding with the fiber sheets, to allow the resin to penetrate into the spaces in the fiber sheets; and curing the resin,the said primer, putty and impregnating resin comprising a resin composition which can cure at a temperature not more than 5.degree. C.
摘要翻译：本发明涉及一种用于加强结构的方法，包括以下步骤：在待加固结构的表面上形成底漆层; 必要时在底漆层上形成油灰层; 在形成的底漆层上施加浸渍树脂，只要在底漆层上形成油灰层之前，在用纤维片材包覆之前，之后或之后以及在包覆纤维片材之前和之后，可以使树脂渗透到空间中纤维片; 并固化树脂，所述底漆，油灰和浸渍树脂包括可在不高于5℃的温度下固化的树脂组合物。

8. 发明授权

US09056850B2 Process for the preparation of compounds useful as inhibitors of SGLT 有权
公开(公告)号：US09056850B2
公开(公告)日：2015-06-16
申请号：US12578934
申请日：2009-10-14
申请人： Walter Ferdinand Maria Filliers , Rudy Laurent Maria Broeckx , Patrick Hubert J. Nieste , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Christopher Teleha
发明人： Walter Ferdinand Maria Filliers , Rudy Laurent Maria Broeckx , Patrick Hubert J. Nieste , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada , Christopher Teleha
IPC分类号： C07D409/04 , C07D333/12 , C07D409/10
CPC分类号： C07D333/12 , C07D409/10 , C07H7/04 , C07H13/04
摘要： The present invention is directed to a novel process for the preparation of compounds having inhibitory activity against sodium-dependent glucose transporter (SGLT) being present in the intestine or kidney.

9. 发明申请

US20100099883A1 PROCESS FOR THE PREPARATION OF COMPOUNDS USEFUL AS INHIBITORS OF SGLT 有权
标题翻译：制备作为SGLT抑制剂的化合物的方法
公开(公告)号：US20100099883A1
公开(公告)日：2010-04-22
申请号：US12578934
申请日：2009-10-14
申请人： Walter Ferdinand Maria Fillers , Rudy Laurent Maria Broeckx , Patrick Hubert J. Nieste , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada
发明人： Walter Ferdinand Maria Fillers , Rudy Laurent Maria Broeckx , Patrick Hubert J. Nieste , Masanori Hatsuda , Masahiko Yoshinaga , Mitsuhiro Yada
IPC分类号： C07D409/04 , C07D409/10 , C07D333/12
CPC分类号： C07D333/12 , C07D409/10 , C07H7/04 , C07H13/04
摘要： The present invention is directed to a novel process for the preparation of compounds having inhibitory activity against sodium-dependent glucose transporter (SGLT) being present in the intestine or kidney.
摘要翻译：本发明涉及一种制备具有抑制活性的化合物的新方法，所述化合物对存在于肠或肾中的钠依赖性葡萄糖转运蛋白（SGLT）具有抑制活性。

10. 发明授权

US06727042B2 Photosensitive resin composition 失效
标题翻译：感光树脂组合物
公开(公告)号：US06727042B2
公开(公告)日：2004-04-27
申请号：US10169927
申请日：2002-07-11
申请人： Toru Takagi , Mitsuhiro Yada , Takeshi Saitou
发明人： Toru Takagi , Mitsuhiro Yada , Takeshi Saitou
IPC分类号： C03F7027
CPC分类号： G03F7/0388 , C08G59/1438 , C08G59/182 , C08K5/0025 , C08L63/00 , C08L63/10 , C08L67/00 , G03F7/027 , H01L23/49894 , H01L2924/0002 , H05K3/287 , C08L2666/22 , H01L2924/00
摘要： A photosensitive resin composition according to the invention includes (A) a photosensitive resin, (B) an epoxy resin, (C) a photopolymerization initiator, and (D) a polymerizable unsaturated compound and/or a solvent, which photosensitive resin (A) is obtained by allowing an epoxy resin (a) to react with a compound (b) having one primary alcoholic hydroxyl group and one functional group selected from a carboxyl group and a secondary amino group per molecule and an unsaturated monobasic acid (c) to yield a reaction product (I) and allowing a saturated or unsaturated polybasic acid anhydride (d) to react with the reaction product (I). The photosensitive resin composition of the invention is used as a solder resist in printed circuit boards, can be satisfactorily developed in a dilute basic aqueous solution and can yield a cured film that is excellent in flexibility, water resistance, adhesion, solder heat resistance, electroless gold plating resistance and pressure cooker test (PCT) resistance.
摘要翻译：根据本发明的感光性树脂组合物包含（A）感光性树脂，（B）环氧树脂，（C）光聚合引发剂和（D）可聚合不饱和化合物和/或溶剂，该感光性树脂（A）通过使环氧树脂（a）与每分子具有一个伯醇羟基和一个选自羧基和仲氨基的官能团和不饱和一元酸（c）的化合物（b）反应，得到反应产物（I）并使饱和或不饱和多元酸酐（d）与反应产物（I）反应。本发明的感光性树脂组合物用作印刷电路板中的阻焊剂，可以在稀碱水溶液中令人满意地显影，并且可以得到柔软性，耐水性，粘合性，焊料耐热性，无电解的优异的固化膜镀金电阻和压力锅试验（PCT）电阻。

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