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1. 发明授权

US5128417A 3-methylbutene-1 polymer, composition containing said polymer, and molded articles of said composition 失效
标题翻译： 3-甲基丁烯-1聚合物，含有所述聚合物的组合物和所述组合物的模塑制品
公开(公告)号：US5128417A
公开(公告)日：1992-07-07
申请号：US539296
申请日：1990-06-18
申请人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Yasuo Maruyama
发明人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Yasuo Maruyama
IPC分类号： C08F255/08 , C08L23/20 , H05K1/03
CPC分类号： C08F255/08 , C08L23/20 , H05K1/032
摘要： A modified 3-methylbutene-1 polymer as prepared by grafting a monomer containing an unsaturated group onto a 3-methylbutene-1 homo- or copolymer, a 3-methylbutene-1 polymer composition comprising a 3-methylbutene-1 polymer and a fibrous material, and a molded article comprising a mold of a 3-methylbutene-1 polymer and a thin metallic layer provided on the mold.
摘要翻译：通过将含有不饱和基团的单体接枝到3-甲基丁烯-1均聚物或共聚物上制备的改性的3-甲基丁烯-1聚合物，包含3-甲基丁烯-1聚合物和纤维材料的3-甲基丁烯-1聚合物组合物以及包含3-甲基丁烯-1聚合物的模具和设置在模具上的薄金属层的模制品。

2. 发明授权

US4645797A 3-Methylbutene-1 polymer composition and process for its production 失效
标题翻译： 3-甲基丁烯-1聚合物组合物及其生产方法
公开(公告)号：US4645797A
公开(公告)日：1987-02-24
申请号：US835112
申请日：1986-02-24
申请人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Yasuo Maruyama
发明人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Yasuo Maruyama
IPC分类号： C08L23/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/08 , C08F10/14 , C08F297/08 , C08L7/00 , C08L21/00 , C08L23/16 , C08L23/18 , C08L23/20 , C08L101/00 , C08L53/00
CPC分类号： C08F10/08 , C08F297/08 , C08L23/20
摘要： A 3-methylbutene-1 polymer composition comprising from 10 to 95% by weight of a 3-methylbutene-1 homopolymer, or a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 12 carbon atoms, which has a 3-methylbutene-1 content of higher than 90% by weight, and from 5 to 90% by weight of a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 12 carbon atoms, which has a 3-methylbutene-1 content of from 40 to 90% by weight, and a process for its production.
摘要翻译： PCT No.PCT / JP85 / 00344 Sec。一九八六年二月二十四日 102（e）日期1986年2月24日PCT归档1985年6月18日PCT公布。出版物WO86 / 0031600 日本1986年1月16日。一种3-甲基丁烯-1聚合物组合物，其包含10-95重量％的3-甲基丁烯-1均聚物，或3-甲基丁烯-1与其它α-烯烃的共聚物，其具有2〜 12个碳原子，其具有高于90重量％的3-甲基丁烯-1含量和5至90重量％的3-甲基丁烯-1与其它具有2至12个碳原子的α-烯烃的共聚物，其具有40至90重量％的3-甲基丁烯-1含量及其生产方法。

3. 发明授权

US4824704A 3-Methylbutene-1 polymer composition, process for its preparation and container made thereof 失效
标题翻译： 3-甲基丁烯-1聚合物组合物，其制备方法和由其制成的容器
公开(公告)号：US4824704A
公开(公告)日：1989-04-25
申请号：US173583
申请日：1988-03-25
申请人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Hidehito Kato , Katsuji Shibata
发明人： Yoshinori Suga , Eiji Tanaka , Nobuo Enokido , Hidehito Kato , Katsuji Shibata
IPC分类号： C08L23/20 , C08L23/10 , B65D1/22 , B65D1/26
CPC分类号： C08L23/20 , Y10T428/1352 , Y10T428/1397
摘要： A 3-methylbutene-1 polymer composition comprising:(a) from 10 to 85% by weight of a 3-methylbutene-1 homopolymer or a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms, which has a heat of fusion of at least 7 cal/g as measured by a differential scanning calorimeter;(b) from 10 to 85% by weight of a copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms, which has a heat of fusion of more than 1 cal/g and less than 7 cal/g as measured by a differential scanning calorimeter; and(c) from 3 to 40% by weight of an elastomeric copolymer of 3-methylbutene-1 with other .alpha.-olefin having from 2 to 18 carbon atoms or an elastomeric copolymer of at least two other olefins having from 2 to 18 carbon atoms, which shows no peak in fusion as measured by a differential scanning calorimeter.

4. 发明授权

US5576400A Process for producing olefin polymer 失效
标题翻译：生产烯烃聚合物的方法
公开(公告)号：US5576400A
公开(公告)日：1996-11-19
申请号：US100183
申请日：1993-08-02
申请人： Yoshinori Suga , Nobuo Enokido
发明人： Yoshinori Suga , Nobuo Enokido
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00 , C08F4/642 , C08F10/02
CPC分类号： C08F10/00
摘要： A process for producing an olefin polymer comprising polymerizing an olefin or olefins in the presence of a catalyst system, in which the catalyst system comprises of (A) a hydrocarbon-insoluble solid catalyst component obtained by treating a uniform hydrocarbon solution containing (a) an magnesium compound, e.g., a dialkoxymagnesium, (b) an titanium compound, e.g., a titanium tetraalkoxide, and (c) a polyalkyltitanate represented by formula (I): ##STR1## wherein R.sup.3 's, which may be the same or different, each represent an alkyl group, an aryl group, or a cycloalkyl group; and p represents an integer of from 2 to 20, with a halogenating agent and (B) an organoaluminum compound. The resulting olefin polymer has broad molecular weight distribution, high melt tension, and high melt elasticity and is freed of fish eye by kneading under ordinary conditions.
摘要翻译：一种制备烯烃聚合物的方法，其包括在催化剂体系存在下使烯烃或烯烃聚合的催化剂体系，其中催化剂体系包含（A）通过处理均匀烃溶液获得的烃不溶性固体催化剂组分，所述烃溶液含有（a）镁化合物，例如二烷氧基镁，（b）钛化合物，例如四烷氧基钛，和（c）由式（I）表示的聚烷基钛酸酯：酰胺或不同，各自表示烷基，芳基或环烷基和p表示2至20的整数，与卤化剂和（B）有机铝化合物。所得烯烃聚合物具有宽分子量分布，高熔体张力和高熔体弹性，并且在普通条件下通过捏合而不含鱼眼。

5. 发明授权

US3989881A Catalyst and process for polymerization of olefin 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US3989881A
公开(公告)日：1976-11-02
申请号：US565196
申请日：1975-04-04
申请人： Kazuo Yamaguchi , Natsuki Kanoh , Toru Tanaka , Nobuo Enokido , Atsushi Murakami , Seiji Yoshida
发明人： Kazuo Yamaguchi , Natsuki Kanoh , Toru Tanaka , Nobuo Enokido , Atsushi Murakami , Seiji Yoshida
IPC分类号： C01G23/00 , C01G31/00 , C08F4/02 , C08F4/10 , C08F4/16 , C08F4/20 , C08F4/62 , C08F10/00 , C08F10/02
CPC分类号： C08F4/022 , C01G23/002 , C01G31/006 , C08F10/00 , C01P2006/60 , C01P2006/80
摘要： A solid catalytic complex for the polymerization of an olefin has the formula:[MgM.sub.1-n ]X.sub.m . xYwherein M represents a transition metal selected from the group consisting of titanium and vanadium; X represents a halogen atom; Y represents an aliphatic ether or a cyclic ether; n is 0.01 - 0.99; 2
摘要翻译：用于烯烃聚合的固体催化络合物具有下式：

6. 发明授权

US4202958A Process for the preparation of polyolefins using a reduced vanadium halide catalyst 失效
标题翻译：使用还原的卤化钒催化剂制备聚烯烃的方法
公开(公告)号：US4202958A
公开(公告)日：1980-05-13
申请号：US865196
申请日：1977-12-28
申请人： Kazuo Yamaguchi , Toru Tanaka , Shigeaki Okano , Nobuo Enokido , Masatoshi Suzuki
发明人： Kazuo Yamaguchi , Toru Tanaka , Shigeaki Okano , Nobuo Enokido , Masatoshi Suzuki
IPC分类号： C08F4/00 , C08F4/60 , C08F10/00 , C08F4/68
CPC分类号： C08F10/00
摘要： A process for the preparation of polyolefins, polymerizing olefins with use of a solid catalyst separated from a reaction mixture which is obtained by reducing a halogen-containing compound of vanadium with an organic aluminum compound in the presence of an ether and an organic aluminum compound.
摘要翻译：一种制备聚烯烃的方法，使用从反应混合物中分离的固体催化剂聚合烯烃，所述反应混合物是通过在有机铝化合物存在下用有机铝化合物还原含钒化合物而获得的。

7. 发明授权

US5547722A Ethylene polymer and fuel tank comprising the same 失效
标题翻译：乙烯聚合物和包含该乙烯聚合物的燃料箱
公开(公告)号：US5547722A
公开(公告)日：1996-08-20
申请号：US414231
申请日：1995-03-31
申请人： Yumito Uehara , Nobuo Enokido , Kiyotoshi Fujioka , Nobuyuki Shimizu , Motonori Ueda
发明人： Yumito Uehara , Nobuo Enokido , Kiyotoshi Fujioka , Nobuyuki Shimizu , Motonori Ueda
IPC分类号： B32B27/08 , C08F10/02 , B65D88/12 , B32B27/32 , B32B27/34
CPC分类号： B32B27/08 , C08F10/02 , Y10T428/1352 , Y10T428/1383 , Y10T428/31746 , Y10T428/31913 , Y10T428/31928
摘要： An ethylene homopolymer or copolymer comprising ethylene and not more than 10% by weight of an .alpha.-olefin having from 3 to 20 carbon atoms and a fuel tank obtained therefrom are disclosed, said ethylene homopolymer or copolymer having (1) an intrinsic viscosity [.eta.] of from 2 to 6 dl/g, (2) a density of from 0.945 to 0.970 g/cm.sup.3, (3) an R value of from 2.5 to 4, said R value being defined as a .sigma..sub.2 /.rho..sub.1 ratio, wherein .sigma..sub.1 and .sigma..sub.2 mean stress in elongation with a strain at 2 sec and 4 sec, respectively, under a flow at an elongational strain rate .epsilon. of 0.5 sec.sup.-1, and (4) a relationship between high-velocity impact strength (HRI-IZOD) measured at -30.degree. C. and a melt index under a load of 21.6 kg (HLMI) satisfying formula:HRI-IZOD.gtoreq.-log HLMI+1.15The ethylene polymer exhibits high melt tension and excellent molding properties such as uniform stretchability in blow molding to provide molded articles, such as a fuel tank, having excellent mechanical characteristics, such as high stiffness and high impact resistance, and excellent fire resistance.
摘要翻译：公开了包含乙烯和不超过10重量％的具有3至20个碳原子的α-烯烃的乙烯均聚物或共聚物和由其获得的燃料箱，所述乙烯均聚物或共聚物具有（1）特性粘度[η ]为2〜6dl / g，（2）密度为0.945〜0.970g / cm3，（3）R值为2.5〜4，所述R值定义为σ2 / rho 1比，其中σ1和σ2分别表示在伸长应变速率+ E，点ε+ EE为0.5秒-1的流动下，在2秒和4秒时应变的伸长应力，以及（4）在-30℃下测量的高速冲击强度（HRI-IZOD）和21.6kg负载下的熔体指数（HLMI）满足公式：HRI-IZOD> / = - log HLMI + 1.15乙烯聚合物显示高熔体张力和优异的成型性能，例如吹塑成型中的均匀拉伸性，以提供具有优异机械性能的模制品，例如燃料箱特性如高刚度，高耐冲击性，耐火性优良。

8. 发明授权

US4525554A Process for polymerizing olefin 失效
标题翻译：烯烃聚合方法
公开(公告)号：US4525554A
公开(公告)日：1985-06-25
申请号：US240480
申请日：1981-03-04
申请人： Toru Tanaka , Kazutoshi Iwatani , Nobuo Enokido , Atsushi Murakami , Yukio Yamaguchi
发明人： Toru Tanaka , Kazutoshi Iwatani , Nobuo Enokido , Atsushi Murakami , Yukio Yamaguchi
IPC分类号： C08F10/00 , C08F4/02
CPC分类号： C08F10/00
摘要： In a process for polymerizing an olefin in the presence of a catalyst system combining an organoaluminum compound with a hydrocarbon insoluble solid catalytic component prepared by treating a hydrocarbon solution containing a magnesium compound, and a titanium compound with an aluminum halide having the formulaAlR.sub.l.sup.1 X.sub.3-l.sup.1(R.sup.1 represents an alkyl, aryl or cycloalkyl group and X.sup.1 represents a halogen atom, and l is 1.ltoreq.l.ltoreq.2),an improvement characterized in that the magnesium compound is a compound having the formulaMg(OR.sup.2).sub.m X.sub.2-m.sup.2(R.sup.2 represents an alkyl, aryl or cycloalkyl group; X.sup.2 represents a halogen atom; and m is 1 or 2) and the titanium compound is a compound having the formulaTi(OR.sup.3).sub.n X.sub.4-n.sup.3(R.sup.3 represents an alkyl, aryl or cycloalkyl group; X.sup.3 represents a halogen atom; n is 1, 2 or 3).
摘要翻译：在将有机铝化合物与通过处理含有镁化合物的烃溶液制备的烃不溶性固体催化剂组分的催化剂体系和具有式AlRl 1 X 3 -11的卤化铝的钛化合物的催化剂体系聚合的方法中，（R1表示烷基，芳基或环烷基，X1表示卤素原子，l表示1〜2），其特征在于镁化合物为具有式Mg（OR 2）m X 2的化合物 -m2（R2表示烷基，芳基或环烷基; X2表示卤素原子，m表示1或2），钛化合物是具有式Ti（OR 3）n X 4-n 3的化合物（R3表示烷基，芳基或环烷基; X3表示卤素原子; n为1,2或3）。

9. 发明授权

US4151337A Process for preparing polyolefin 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4151337A
公开(公告)日：1979-04-24
申请号：US800177
申请日：1977-05-25
申请人： Natsuki Kanoh , Toru Tanaka , Nobuo Enokido
发明人： Natsuki Kanoh , Toru Tanaka , Nobuo Enokido
IPC分类号： C08F4/00 , B01J27/08 , B01J31/26 , C08F4/60 , C08F10/00 , C08F4/66 , C08F10/02
CPC分类号： B01J31/143 , B01J27/08 , B01J31/2208 , B01J31/36 , B01J31/38 , C08F10/00 , B01J2231/12 , B01J2531/46 , B01J2531/56 , B01J27/10
摘要： Polyolefin is prepared by polymerizing an olefin by using a catalyst system combining an auxiliary catalytic component of an organoaluminum compound and a solid catalytic component obtained by reacting a mixture of a vanadium trichloride ether complex and a titanium trichloride ether complex with an aluminum halide and/or a boron halide.
摘要翻译：聚烯烃是通过使用将有机铝化合物的辅助催化剂组分和通过使三氯化铝复合物和三氯化钛配合物的混合物与卤化铝和/或卤化硼。

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