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1. 发明授权

US4950824A Process for the production of 2,6-diisopropylnaphthalene 失效
标题翻译： 2,6-二异丙基萘的制备方法
公开(公告)号：US4950824A
公开(公告)日：1990-08-21
申请号：US388393
申请日：1989-08-02
申请人： Yoshimi Shiroto , Mitsunori Shimura , Kenji Shimokawa , Yoshio Fukui , Sachio Asaoka , Hiroto Tajima , Kazuaki Ueda , Yakudo Tachibana , Kazuhiko Tate , Hiroaki Taniguchi
发明人： Yoshimi Shiroto , Mitsunori Shimura , Kenji Shimokawa , Yoshio Fukui , Sachio Asaoka , Hiroto Tajima , Kazuaki Ueda , Yakudo Tachibana , Kazuhiko Tate , Hiroaki Taniguchi
IPC分类号： C07C2/66 , C07C6/12 , C07C7/13 , C07C15/24
CPC分类号： C07C15/24 , C07C2/66 , C07C6/126 , C07C7/13
摘要： A process for the production of 2,6-diisopropylnaphthalene is disclosed wherein an isopropylation reaction mixture containing isopropylated naphthalenes is subjected to transalkylation with a triisopropylnaphthalene-containing mixture to obtain a mixture containing mono-, di- and tri-isopropylnaphthalenes which is then separated into a first fraction containing monisopropylnaphthalenes, a second fraction containing diisopropylnaphthalenes and a third fraction containing triisopropylnaphthalenes. The first and third fractions are recycled to the above system, while the second fraction is subjected to separation treatments for the recovery of 2,6-diisopropylnaphthalene. The second fraction from which 2,6-diisopropylnaphthalene has been removed is subjected to transalkylation with naphthalene to obtain a monoisopropylnaphthalene-rich mixture which is to be fed to the isopropylation step.
摘要翻译：公开了制备2,6-二异丙基萘的方法，其中将含有异丙基化萘的异丙基化反应混合物与含三异丙基萘的混合物进行烷基转移，得到含有单 - ，二 - 和三 - 异丙基萘的混合物，然后将其分离成含有异丙基萘的第一级分，含有二异丙基萘的第二馏分和含有三异丙基萘的第三级分。将第一和第三馏分再循环至上述系统，而第二馏分进行分离处理以回收2,6-二异丙基萘。已经除去2,6-二异丙基萘的第二部分用萘进行烷基转移，得到富含单异丙基萘的混合物，将其加入到异丙基化步骤中。

2. 发明授权

US4367165A Catalyst for hydrotreating heavy hydrocarbon oils and method of preparing same 失效
标题翻译：用于加氢处理重质烃油的催化剂及其制备方法
公开(公告)号：US4367165A
公开(公告)日：1983-01-04
申请号：US210049
申请日：1980-11-24
申请人： Sachio Asaoka , Takeo Ono , Yoshimi Shiroto
发明人： Sachio Asaoka , Takeo Ono , Yoshimi Shiroto
IPC分类号： C10G49/02 , B01J21/14 , B01J21/16 , B01J23/00 , B01J23/22 , B01J27/12 , B01J27/18 , B01J27/198 , B01J35/10 , C10G11/02 , C10G45/04 , C10G47/12 , C10G49/04 , B01J21/00
CPC分类号： C10G47/12 , B01J21/14 , B01J21/16 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G11/02 , C10G2300/107
摘要： A catalyst for hydrotreating a heavy hydrocarbon oil comprises a carrier which is a calcined composite of a mixture of a clay mineral consisting mainly of magnesium silicate having a double-chain structure and a pseudoboehmite which shows a powder X-ray diffraction spectrum obtained by applying a CuK.sub..alpha. ray such that the half value width of the peak on the (020) plane is between about 0.8.degree. and 4.0.degree. and the intensity of said peak is between 1.2 and 8.0 times as high as that at 2.theta.=10.degree.. At least one catalytic metal component is composited with the carrier, the metal of the catalytic metal component being selected from the group consisting of metals belonging to Groups VB, VIB, VIII and IB of the Periodic Table. Disclosed also are a method of preparing such a catalyst, and a process for the hydrotreatment of heavy hydrocarbon oils containing asphaltenes and heavy metals.
摘要翻译：用于加氢处理重质烃油的催化剂包括载体，其是主要由具有双链结构的硅酸镁组成的粘土矿物和假勃姆石的混合物的煅烧复合物，其显示通过施加粉末X射线衍射光谱获得的粉末X射线衍射光谱（020）平面上的峰的半值宽度在约0.8°至4.0°之间，并且所述峰的强度在2θ= 10°时的强度在1.2至8.0倍之间。至少一种催化金属组分与载体复合，催化金属组分的金属选自属于元素周期表的VB族，VIB族，VIII族和IB族的金属。还公开了制备这种催化剂的方法，以及用于加氢处理含有沥青质和重金属的重质烃油的方法。

3. 发明授权

US5334755A Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst 失效
标题翻译：使用负载铑催化剂从甲醇和一氧化碳生产乙酸的方法
公开(公告)号：US5334755A
公开(公告)日：1994-08-02
申请号：US49303
申请日：1993-04-21
申请人： Noriyuki Yoneda , Yoshimi Shiroto , Kazuhiko Hamato , Sachio Asaoka , Tetsuo Maejima
发明人： Noriyuki Yoneda , Yoshimi Shiroto , Kazuhiko Hamato , Sachio Asaoka , Tetsuo Maejima
IPC分类号： B01J31/16 , B01J31/18 , C07C51/12 , C07C67/36 , C07C51/10
CPC分类号： B01J31/181 , B01J31/1658 , C07C51/12 , B01J2531/822
摘要： A liquid feed containing methanol, carbon monoxide, an alkyl iodide and a solvent is contacted with a supported rhodium catalyst to produce acetic acid at a temperature of 140.degree.-250.degree. C. and a pressure of 15-60 kg/cm.sup.2 G with a partial pressure of carbon monoxide of 7-30 kg/cm.sup.2 while maintaining (a) the water concentration of the product solution in the range of 0.5-10% by weight and (b) the carbonylation degree C.sub.r, defined in the specification, of the solution within the reactor at 0.15 or more. The solvent may be a carboxylic acid or a carboxylic acid ester.
摘要翻译：将含有甲醇，一氧化碳，烷基碘和溶剂的液体原料与负载的铑催化剂接触，在140-250℃的温度和15-60kg / cm2G的压力下制备乙酸，一氧化碳压力为7-30kg / cm2，同时维持（a）产品溶液的水浓度在0.5-10重量％的范围内，（b）溶液中规定的羰基化度Cr 在反应器内为0.15以上。溶剂可以是羧酸或羧酸酯。

4. 发明授权

US4439312A Catalyst for hydrotreating heavy hydrocarbon oils, method of preparing same and process for hydrotreating heavy hydrocarbon oils 失效
标题翻译：用于加氢处理重质烃油的催化剂，其制备方法和加氢处理重质烃油的方法
公开(公告)号：US4439312A
公开(公告)日：1984-03-27
申请号：US379926
申请日：1982-05-19
申请人： Sachio Asaoka , Takeo Ono , Yoshimi Shiroto
发明人： Sachio Asaoka , Takeo Ono , Yoshimi Shiroto
IPC分类号： C10G49/02 , B01J21/14 , B01J21/16 , B01J23/00 , B01J23/22 , B01J27/12 , B01J27/18 , B01J27/198 , B01J35/10 , C10G11/02 , C10G45/04 , C10G47/12 , C10G49/04 , C10G45/08
CPC分类号： C10G47/12 , B01J21/14 , B01J21/16 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G11/02 , C10G2300/107
摘要： A catalyst for hydrotreating a heavy hydrocarbon oil comprises a carrier which is a calcined composite of a mixture of a clay mineral consisting mainly of magnesium silicate having a double-chain structure and a pseudoboehmite which shows a powder X-ray diffraction spectrum obtained by applying a CuK.sub..alpha. ray such that the half value width of the peak on the (020) plane is between about 0.8.degree. and 4.0.degree. and the intensity of said peak is between 1.2 and 8.0 times as high as that at 2.theta.=10.degree.. At least one catalytic metal component is composited with the carrier, the metal of the catalytic metal component being selected from the group consisting of metals belonging to Groups VB, VIB, VIII and IB of the Periodic Table. Disclosed also are a method of preparing such a catalyst, and a process for the hydrotreatment of heavy hydrocarbon oils containing asphaltenes and heavy metals.
摘要翻译：用于加氢处理重质烃油的催化剂包括载体，其是主要由具有双链结构的硅酸镁组成的粘土矿物和假勃姆石的混合物的煅烧复合物，其显示通过施加粉末X射线衍射光谱获得的粉末X射线衍射光谱（020）平面上的峰的半值宽度在约0.8°至4.0°之间，并且所述峰的强度在2θ= 10°时的强度在1.2和8.0倍之间。至少一种催化金属组分与载体复合，催化金属组分的金属选自属于元素周期表的VB族，VIB族，VIII族和IB族的金属。还公开了制备这种催化剂的方法，以及用于加氢处理含有沥青质和重金属的重质烃油的方法。

5. 发明授权

US4444655A Hydrotreatment of heavy hydrocarbon oils containing asphaltenes, and catalysts therefor 失效
标题翻译：含沥青质的重质烃油的加氢处理及其催化剂
公开(公告)号：US4444655A
公开(公告)日：1984-04-24
申请号：US428796
申请日：1982-09-30
申请人： Yoshimi Shiroto , Takeo Ono , Sachio Asaoka , Munekazu Nakamura
发明人： Yoshimi Shiroto , Takeo Ono , Sachio Asaoka , Munekazu Nakamura
IPC分类号： B01J21/00 , B01J23/74 , B01J23/85 , B01J23/882 , B01J23/887 , B01J35/00 , B01J35/10 , C10G45/04 , C10G47/10 , C10G55/06 , C10G65/04 , C10G65/12
CPC分类号： B01J23/882 , B01J23/85 , B01J23/8872 , B01J35/10 , B01J35/002 , B01J35/1019 , B01J35/1061 , B01J35/108 , C10G2300/107
摘要： A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.sup.2 /g. The catalyst has an average catalyst diameter ACD, expressed in millimeters, of not greater than a value of the formula, ACD=(APD/100).sup.0.5. Disclosed also are a method of preparing such a catalyst, and a process for hydrotreating a heavy hydrocarbon oil containing asphaltenes in the presence of such a catalyst.
摘要翻译：用于加氢处理含有沥青质的重烃油的催化剂包括由一种或多种选自元素周期表II，III和IV族中的至少一种元素的一种或多种无机氧化物组成的多孔载体，以及至少一种催化金属组分与承运人。催化金属组分的金属选自元素周期表的VB，VIB，VIII和IB族。该催化剂含有约1至30重量％的这种催化金属组分，并且对于其直径为75埃或更高的孔具有以下孔特性：平均孔径APD为约180至500安培姆，总孔体积PV以cc / g表示，等于或大于直径为约180至500的孔的体积至少约0.2cc / g，具有直径的孔的体积至少1500安培角不大于约0.03cc / g，总表面积为至少约60m 2 / g。催化剂的平均催化剂直径ACD（以毫米表示）不大于式的值ACD =（APD / 100）0.5。还公开了制备这种催化剂的方法，以及在这种催化剂存在下，对含有沥青质的重质烃油进行加氢处理的方法。

6. 发明授权

US4424142A Catalyst for hydrotreatment of heavy hydrocarbon oils 失效
标题翻译：用于加氢处理重质烃油的催化剂
公开(公告)号：US4424142A
公开(公告)日：1984-01-03
申请号：US242987
申请日：1981-03-12
申请人： Sachio Asaoka , Yoshimi Shiroto , Munekazu Nakamura , Takeo Ono
发明人： Sachio Asaoka , Yoshimi Shiroto , Munekazu Nakamura , Takeo Ono
IPC分类号： B01J21/16 , B01J23/22 , B01J27/04 , B01J35/10 , C10G45/04 , C10G47/16 , B01J23/88
CPC分类号： B01J35/10 , B01J23/22 , B01J27/04 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G2300/107
摘要： A catalyst for the hydrotreatment of heavy hydrocarbon oils, which is prepared by supporting more than 2% by weight of VS.sub.x, wherein x represents about 1.1-1.59 in terms of an atomic ratio of S/V, on a substrate composed of a clay mineral which consists of magnesium silicate as a major component and having a double-chain structure and a process for preparing the catalyst are provided. The catalyst is prepared by accumulating the VS.sub.x on the substrate using a heavy hydrocarbon oil which contains particularly large amounts of vanadium and sulfur.
摘要翻译：用于加氢处理重质烃油的催化剂，其通过支持超过2重量％的VSx制备，其中x以S / V的原子比计约1.1-1.59，在由粘土矿物组成的基材上提供了由硅酸镁作为主要组分并具有双链结构和制备催化剂的方法。使用含有特别大量的钒和硫的重质烃油将VSx堆积在基材上来制备催化剂。

7. 发明授权

US4326991A Process for preparing a catalyst for hydrotreatment of heavy hydrocarbon oils 失效
标题翻译：制备用于加氢处理重质烃油的催化剂的方法
公开(公告)号：US4326991A
公开(公告)日：1982-04-27
申请号：US084764
申请日：1979-10-15
申请人： Sachio Asaoka , Yoshimi Shiroto , Munekazu Nakamura
发明人： Sachio Asaoka , Yoshimi Shiroto , Munekazu Nakamura
IPC分类号： B01J23/22 , B01J27/04 , B01J35/10 , C10G45/04 , B01J21/06 , B01J21/10
CPC分类号： B01J35/10 , B01J23/22 , B01J27/04 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , C10G2300/107
摘要： A catalyst for the hydrotreatment of heavy hydrocarbon oils, which is prepared by supporting more than 2% by weight of VS.sub.x, wherein x represents about 1.1-1.59 in terms of an atomic ratio of S/V, on a substrate composed of a clay mineral which consists of magnesium silicate as a major component and having a double-chain structure and a process for preparing the catalyst are provided. The catalyst is prepared by accumulating the VS.sub.x on the substrate using a heavy hydrocarbon oil which contains particularly large amounts of vanadium and sulfur.
摘要翻译：用于加氢处理重质烃油的催化剂，其通过支持超过2重量％的VSx制备，其中x以S / V的原子比计约1.1-1.59，在由粘土矿物组成的基材上提供了由硅酸镁作为主要组分并具有双链结构和制备催化剂的方法。使用含有特别大量的钒和硫的重质烃油将VSx堆积在基材上来制备催化剂。

8. 发明授权

US4422960A Catalysts for hydrotreatment of heavy hydrocarbon oils containing asphaltenes 失效
标题翻译：用于加氢处理含有沥青质的重质烃油的催化剂
公开(公告)号：US4422960A
公开(公告)日：1983-12-27
申请号：US210059
申请日：1980-12-14
申请人： Yoshimi Shiroto , Takeo Ono , Sachio Asaoka , Munekazu Nakamura
发明人： Yoshimi Shiroto , Takeo Ono , Sachio Asaoka , Munekazu Nakamura
IPC分类号： B01J21/00 , B01J23/74 , B01J23/85 , B01J23/882 , B01J23/887 , B01J35/00 , B01J35/10 , C10G45/04 , C10G47/10 , C10G55/06 , C10G65/04 , C10G65/12 , B01J21/04 , B01J23/22 , B01J23/24 , B01J27/04
CPC分类号： B01J23/882 , B01J23/85 , B01J23/8872 , B01J35/10 , B01J35/002 , B01J35/1019 , B01J35/1061 , B01J35/108 , C10G2300/107
摘要： A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.sup.2 /g. The catalyst has an average catalyst diameter ACD, expressed in millimeters, of not greater than a value of the formula, ACD=(APD/100).sup.0.5. Disclosed also are a method of preparing such a catalyst, and a process for hydrotreating a heavy hydrocarbon oil containing asphaltenes in the presence of such a catalyst.
摘要翻译：用于加氢处理含有沥青质的重烃油的催化剂包括由一种或多种选自元素周期表II，III和IV族中的至少一种元素的一种或多种无机氧化物组成的多孔载体，以及至少一种催化金属组分与承运人。催化金属组分的金属选自元素周期表的VB，VIB，VIII和IB族。该催化剂含有约1至30重量％的这种催化金属组分，并且对于其直径为75埃或更高的孔具有以下孔特性：平均孔径APD为约180至500安培姆，总孔体积PV以cc / g表示，等于或大于直径为约180至500的孔的体积至少约0.2cc / g，具有直径的孔的体积至少1500安培角不大于约0.03cc / g，总表面积为至少约60m 2 / g。催化剂的平均催化剂直径ACD（以毫米表示）不大于式的值ACD =（APD / 100）0.5。还公开了制备这种催化剂的方法，以及在这种催化剂存在下，对含有沥青质的重质烃油进行加氢处理的方法。

9. 发明授权

US06340437B1 Process for preparing synthesis gas by autothermal reforming 有权
标题翻译：通过自热重整制备合成气的方法
公开(公告)号：US06340437B1
公开(公告)日：2002-01-22
申请号：US09254636
申请日：1999-03-11
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
IPC分类号： C07C102
CPC分类号： B01J23/40 , C01B3/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed is a process for producing a synthesis gas by an autothermal reforming method including a step of partially oxidizing a carbon-containing organic compound to produce a high temperature mixed gas, and a synthesis producing step of reacting the unreacted carbon-containing organic compound contained in the high temperature mixed gas with carbon dioxide and/or steam, wherein a catalyst having a considerably suppressed carbon deposition activity is used as a catalyst for the synthesis gas producing step. The catalyst is characterized in that the catalyst comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m2/g or less, in that metal ion of the carrier metal oxide has electronegativity of 13.0 or less, and in that the amount of the catalytic metal supported is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide.
摘要翻译：公开了一种通过自热重整法制备合成气的方法，该方法包括将含碳有机化合物部分氧化以产生高温混合气体的步骤，以及合成制备步骤，使含有具有二氧化碳和/或蒸汽的高温混合气体，其中具有显着抑制的碳沉积活性的催化剂用作合成气生产步骤的催化剂。催化剂的特征在于催化剂包含由金属氧化物形成的载体和至少一种选自铑，钌，铱，钯和铂的催化金属并负载在载体上，因为催化剂具有比表面积 25m 2 / g以下，载体金属氧化物的金属离子的电负性为13.0以下，并且，以金属为基准，载体的载体量为0.0005〜0.1摩尔％金属氧化物。

10. 发明授权

US06312660B1 Process for preparing synthesis gas 有权
标题翻译：合成气的制备方法
公开(公告)号：US06312660B1
公开(公告)日：2001-11-06
申请号：US09254635
申请日：1999-03-11
申请人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
发明人： Fuyuki Yagi , Atsuro Nagumo , Yukitaka Wada , Mitsunori Shimura , Sachio Asaoka , Shuhei Wakamatsu
IPC分类号： C01B326
CPC分类号： C01B3/40 , B01J23/40 , C01B32/40 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , Y02P20/52
摘要： Disclosed is a process for producing a synthesis gas by reacting a carbon-containing organic compound with steam and/or carbon dioxide using a catalyst whose carbon deposition activity is considerably suppressed. The catalyst is characterized in that it comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m2/g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the catalytic metal is 0.0005-0.1 mole %, in terms of metal, based on the carrier metal oxide.
摘要翻译：公开了一种通过使碳含量有机化合物与蒸汽和/或二氧化碳反应的催化剂，其碳沉积活性受到显着抑制而制备合成气的方法。该催化剂的特征在于其包含由金属氧化物形成的载体和至少一种选自铑，钌，铱，钯和铂的催化金属并负载在载体上，因为催化剂的比表面积为25 m 2 / g以下，其中载体金属氧化物的金属离子的电负性为13.0以下，催化剂金属的量为0.0005〜0.1摩尔％，以金属计，基于载体金属氧化物。

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