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1. 发明申请

US20060052563A1 Process for producing branched polymer and polymer 审中-公开
标题翻译：制备支链聚合物和聚合物的方法
公开(公告)号：US20060052563A1
公开(公告)日：2006-03-09
申请号：US11199392
申请日：2005-08-09
申请人： Yoshiki Nakagawa , Shigeki Ono , Masayuki Fujita , Kenichi Kitano
发明人： Yoshiki Nakagawa , Shigeki Ono , Masayuki Fujita , Kenichi Kitano
IPC分类号： C08F20/10
CPC分类号： C08F299/00 , C08F290/04 , C08F290/046 , C08F290/06 , C08F291/00 , C08F2438/01
摘要： This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon-carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having a well controlled side chain molecular weights.
摘要翻译：本发明涉及一种支化聚合物的制备方法，其包括使大分子单体[I]聚合，所述大分子单体[I]是通过自由基聚合可获得的乙烯基聚合物，并且每个分子终端具有一个可聚合的含碳 - 碳双键的基团。此外，通过活性自由基聚合，特别是原子转移自由基聚合制备大分子单体，可以制备具有良好控制的侧链分子量的上述聚合物或凝胶。

2. 发明授权

US06979716B1 Process for producing branched polymer and polymer 失效
标题翻译：制备支链聚合物和聚合物的方法
公开(公告)号：US06979716B1
公开(公告)日：2005-12-27
申请号：US09719580
申请日：1999-06-18
申请人： Yoshiki Nakagawa , Shigeki Ono , Masayuki Fujita , Kenichi Kitano
发明人： Yoshiki Nakagawa , Shigeki Ono , Masayuki Fujita , Kenichi Kitano
IPC分类号： C08F290/04 , C08F290/06 , C08F291/00 , C08F20/10
CPC分类号： C08F299/00 , C08F290/04 , C08F290/046 , C08F290/06 , C08F291/00 , C08F2438/01
摘要： This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon—carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having well controlled side chain molecular weights.
摘要翻译：本发明涉及一种支化聚合物的制备方法，其包括使大分子单体[I]聚合，所述大分子单体[I]是通过自由基聚合可获得的乙烯基聚合物，并且每个分子终端具有一个可聚合的含碳 - 碳双键的基团。此外，通过活性自由基聚合，特别是原子转移自由基聚合制备大分子单体，可以制备具有良好控制的侧链分子量的上述聚合物或凝胶。

3. 发明授权

US07781534B2 Process for producing vinyl polymer, vinyl polymer, and curable composition 有权
标题翻译：制备乙烯基聚合物，乙烯基聚合物和可固化组合物的方法
公开(公告)号：US07781534B2
公开(公告)日：2010-08-24
申请号：US11987469
申请日：2007-11-30
申请人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
发明人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
IPC分类号： C08J3/28 , C08C2/04 , C08C19/25
CPC分类号： C08F8/26 , C08F8/16 , C08F8/48 , C08F2810/30 , C08F2810/40 , Y10T436/196666
摘要： The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.
摘要翻译：本发明提供了一种制备乙烯基聚合物的方法，该乙烯基聚合物含有每千克1,000mg以下的卤素，其中含有通过乙烯基单体的原子转移自由基聚合产生的卤素的乙烯基聚合物在温度为范围为140至250℃，以使乙烯基聚合物脱卤; 通过该方法获得的乙烯基聚合物; 和含有乙烯基聚合物的氢化硅烷化反应性固化组合物。

4. 发明授权

US07323519B2 Process for producing vinyl polymer, vinyl polymer, and curable composition 失效
公开(公告)号：US07323519B2
公开(公告)日：2008-01-29
申请号：US10501023
申请日：2003-01-21
申请人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
发明人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
IPC分类号： C08J3/28 , C08C2/04
CPC分类号： C08F8/26 , C08F8/16 , C08F8/48 , C08F2810/30 , C08F2810/40 , Y10T436/196666
摘要： The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.

5. 发明申请

US20080160621A1 Process for producing vinyl polymer, vinyl polymer, and curable composition 有权
标题翻译：制备乙烯基聚合物，乙烯基聚合物和可固化组合物的方法
公开(公告)号：US20080160621A1
公开(公告)日：2008-07-03
申请号：US11987469
申请日：2007-11-30
申请人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
发明人： Kenichi Kitano , Akihisa Hirota , Masanao Takeda , Kosuke Tanaka , Yoshiki Nakagawa , Shigeru Hagimori , Naoki Furukawa , Shigeki Ono , Nao Fujita
IPC分类号： G01N33/00 , C08F130/08
CPC分类号： C08F8/26 , C08F8/16 , C08F8/48 , C08F2810/30 , C08F2810/40 , Y10T436/196666
摘要： The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.
摘要翻译：本发明提供了一种制备乙烯基聚合物的方法，该乙烯基聚合物含有每千克1,000mg以下的卤素，其中含有通过乙烯基单体的原子转移自由基聚合产生的卤素的乙烯基聚合物在温度为范围为140至250℃，以使乙烯基聚合物脱卤; 通过该方法获得的乙烯基聚合物; 和含有乙烯基聚合物的氢化硅烷化反应性固化组合物。

6. 发明授权

US06964999B1 Polymer and curable composition 有权
标题翻译：聚合物和可固化组合物
公开(公告)号：US06964999B1
公开(公告)日：2005-11-15
申请号：US09622931
申请日：1999-03-01
申请人： Yoshiki Nakagawa , Masayuki Fujita , Kenichi Kitano
发明人： Yoshiki Nakagawa , Masayuki Fujita , Kenichi Kitano
IPC分类号： C08F2/48 , C08F8/00 , C08F8/14 , C08F299/00 , C09J4/02
CPC分类号： C08F299/00 , C08F8/14 , C08F2810/20 , C08F2810/30 , C08F2810/40 , C08J3/28 , C08J2333/04 , C08F8/26 , C08F120/18 , C08F8/06
摘要： A vinyl polymer having at least one terminal group of the general formula (1) per molecule; —OC(O)C(R)═CH2 (1) wherein R represents hydrogen or an organic group containing 1 to 20 carbon atoms; a curable composition containing said polymer; an aqueous emulsion containing either said polymer or said curable composition; a pressure sensitive adhesive composition and a pressure sensitive adhesive each comprising said curable composition or aqueous emulsion.
摘要翻译：每个分子具有至少一个通式（1）的末端基团的乙烯基聚合物; -OC（O）C（R）-CH 2（1）<βin-line-formula description =“In-line formula”end =“lead” 式中，R表示氢或含有1〜20个碳原子的有机基团，含有所述聚合物的可固化组合物; 含有所述聚合物或所述可固化组合物的水乳液; 压敏粘合剂组合物和压敏粘合剂，其各自包含所述可固化组合物或水性乳液。

7. 发明授权

US06479584B1 Resin composition, polymer, and process for producing polymer 失效
标题翻译：树脂组合物，聚合物和聚合物的制造方法
公开(公告)号：US06479584B1
公开(公告)日：2002-11-12
申请号：US09763151
申请日：2001-08-09
申请人： Yoshiki Nakagawa , Katsuhiko Kimura , Masayuki Fujita , Kenichi Kitano
发明人： Yoshiki Nakagawa , Katsuhiko Kimura , Masayuki Fujita , Kenichi Kitano
IPC分类号： C08F800
CPC分类号： C09J153/00 , C08F2/00 , C08F8/00 , C08F293/005 , C08F2438/01 , C08F2800/10 , C08F2800/20 , C08F2810/20 , C08F2810/40 , C08L53/00 , C08L53/005 , C08L2666/02 , C09J153/005 , C08F2220/1825
摘要： The invention provides a resin composition comprising a crosslinking silyl-terminated stellar-structure vinyl polymer or a stellar-structure vinyl block copolymer or chain-extended vinyl block copolymer. The invention provides a method of producing a stellar-structure vinyl block copolymer or chain-extended vinyl block copolymer which comprises forming a block copolymer using living radical polymerization and adding a compound having two or more polymerizable carbon-carbon double bonds at the end point of polymerization of the block copolymer.
摘要翻译：本发明提供了一种树脂组合物，其包含交联甲硅烷基封端的恒星结构的乙烯基聚合物或恒星结构的乙烯基嵌段共聚物或链延长的乙烯基嵌段共聚物。本发明提供了一种制备恒星型乙烯基嵌段共聚物或链 - 延伸的乙烯基嵌段共聚物，其包括使用活性自由基聚合形成嵌段共聚物，并在嵌段共聚物的聚合端点加入具有两个或更多个可聚合碳 - 碳双键的化合物。

8. 发明申请

US20070004874A1 Polymer and epoxy resin compositions 失效
公开(公告)号：US20070004874A1
公开(公告)日：2007-01-04
申请号：US11516590
申请日：2006-09-07
申请人： Kenichi Kitano , Yoshiki Nakagawa , Masayuki Fujita
发明人： Kenichi Kitano , Yoshiki Nakagawa , Masayuki Fujita
IPC分类号： C08L63/00
CPC分类号： C08L61/06 , C08F8/00 , C08F8/02 , C08F8/26 , C08F2810/40 , C08G8/10 , C08G8/38 , C08G59/02 , C08G59/027 , C08G59/50 , C08L33/18 , C08L63/00 , C08L61/04 , C08L33/00 , C08L2666/04 , C08F120/18
摘要： The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living-radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition-having an epoxy group at a main chain terminus thereof.

9. 发明授权

US07056983B2 Block copolymer 失效
标题翻译：嵌段共聚物
公开(公告)号：US07056983B2
公开(公告)日：2006-06-06
申请号：US09446521
申请日：1999-04-28
申请人： Yoshiki Nakagawa , Masayuki Fujita , Kenichi Kitano , Tomoki Hiiro , Katsuhiko Kimura
发明人： Yoshiki Nakagawa , Masayuki Fujita , Kenichi Kitano , Tomoki Hiiro , Katsuhiko Kimura
IPC分类号： C08F20/18 , C08F255/00
CPC分类号： C08F290/02 , C08F293/005 , C08F297/00 , C08F2438/01
摘要： Processes for producing an AB block copolymer, an ABA block copolymer or a multiblock copolymer are provided, which comprises adding an alkenyl-containing polymer (I) to a living or to an atom transfer radical polymerization system or a living cationic polymerization system.
摘要翻译：提供了制备AB嵌段共聚物，ABA嵌段共聚物或多嵌段共聚物的方法，其包括向活性或原子转移自由基聚合体系或活性阳离子聚合体系中加入含链烯基的聚合物（I）。

10. 发明授权

US06653429B1 Process for producing polymer, the polymer, and curable composition comprising the polymer 失效
标题翻译：制备聚合物的方法，聚合物和包含聚合物的可固化组合物
公开(公告)号：US06653429B1
公开(公告)日：2003-11-25
申请号：US09701696
申请日：2001-02-09
申请人： Yoshiki Nakagawa , Kenichi Kitano , Masayuki Fujita
发明人： Yoshiki Nakagawa , Kenichi Kitano , Masayuki Fujita
IPC分类号： C08J12016
CPC分类号： C08F8/44 , C08F2810/30 , C08F2810/40 , C08F120/18 , C08F8/26
摘要： This invention provides method of producing a polymer which comprises substitution of carboxylic acid group for a terminal halogen group of a polymer obtainable by atom transfer radical polymerization. The carboxylic acid group may be a carboxylic acid salt group, more preferably a carboxylic acid potassium salt group. In carrying out the atom transfer radical polymerization in the practice of the invention, a transition metal complex can be used as a polymerization catalyst. The transition metal complex may be a transition metal complex with an element of the group 7, 8, 9, 10 or 11 of the periodic table as the central atom, more preferably a copper, nickel, ruthenium or iron complex and, in particular, a copper complex is used. The polymer obtainable by atom transfer radical polymerization is obtained by polymerization of a (meth)acrylic monomer, particularly the polymer obtained by polymerization of an acrylic acid ester monomer.
摘要翻译：本发明提供聚合物的制造方法，该方法包括用羧酸取代通过原子转移自由基聚合可得到的聚合物的末端卤素基团。羧酸基团可以是羧酸盐基团，更优选羧酸钾盐基团。在本发明的实施中进行原子转移自由基聚合时，可以使用过渡金属络合物作为聚合催化剂。过渡金属络合物可以是与元素周期表第7,8,9,10或11族元素作为中心原子的过渡金属络合物，更优选铜，镍，钌或铁络合物，特别是，使用铜络合物。通过原子转移自由基聚合可得到的聚合物是通过聚合（甲基）丙烯酸单体，特别是通过丙烯酸酯单体的聚合得到的聚合物获得的。

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