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    • 1. 发明授权
    • Aluminum alloy clad material for heat exchangers exhibiting excellent erosion-corrosion resistance
    • 用于热交换器的铝合金包覆材料具有优异的抗腐蚀性能
    • US06316126B1
    • 2001-11-13
    • US09417803
    • 1999-10-14
    • Yoshiharu HasegawaHaruhiko MiyachiHisao KatoHirokazu TanakaHiroshi IkedaYoshifusa Shoji
    • Yoshiharu HasegawaHaruhiko MiyachiHisao KatoHirokazu TanakaHiroshi IkedaYoshifusa Shoji
    • B32B1520
    • F28F21/089B32B15/016F28F19/004F28F19/06F28F21/084Y10S428/933Y10T428/12736Y10T428/12764Y10T428/12986Y10T428/31678
    • An aluminum alloy clad material for heat exchangers exhibiting excellent erosion-corrosion resistance, corrosion resistance, pitting resistance, and brazability, which is suitably used as an aluminum alloy clad sheet for forming a constituent member, in particular, a tube for an aluminum heat exchanger such as a radiator and heater, and as a pipe for circulating a working fluid in the aluminum heat exchanger or a pipe connected to the heat exchangers. The aluminum alloy clad sheet comprises a sacrificial anode material clad on one side of a core material, wherein the core material comprises an Al—Mn alloy and the sacrificial anode material comprises an aluminum alloy, for example, an aluminum alloy comprising 3.0-12.0% of Si with the remaining portion consisting of Al and impurities, or an aluminum alloy comprising 3.0-12.0% of Si, 1-10% of Zn, and 0.15-1.2% of Fe with the remaining portion consisting of Al and impurities. The sacrificial anode material may comprise trace amounts of one or more of In, Sn, and Mg. The clad sheet may have a three-layered clad material in which an Al—Si-type brazing material is clad on the side of the core material.
    • 特别是用于形成构成部件的铝合金包覆板,特别是用于铝热交换器的管的铝合金包覆材料,其表现出优异的耐腐蚀性,耐腐蚀性,耐点蚀性和钎焊性 例如散热器和加热器,以及用于在铝热交换器中循环工作流体的管道或连接到热交换器的管道。 铝合金复合板包括包覆在芯材一侧的牺牲阳极材料,其中芯材料包括Al-Mn合金,牺牲阳极材料包括铝合金,例如包含3.0-12.0% 的Si,其余部分由Al和杂质组成,或者包含3.0-12.0%的Si,1-10%的Zn和0.15-1.2%的Fe,其余部分由Al和杂质组成的铝合金。 牺牲阳极材料可以包含痕量的In,Sn和Mg中的一种或多种。 复合板可以具有其中Al-Si型钎焊材料包覆在芯材侧的三层包覆材料。
    • 6. 发明授权
    • Aluminum heat exchanger excellent in corrosion resistance
    • 铝合金热交换器耐腐蚀性优良
    • US07250223B2
    • 2007-07-31
    • US10860560
    • 2004-06-03
    • Haruhiko MiyachiYoshiharu HasegawaMasamichi MakiharaYasunaga ItohNaoki YamashitaToshihiko Fukuda
    • Haruhiko MiyachiYoshiharu HasegawaMasamichi MakiharaYasunaga ItohNaoki YamashitaToshihiko Fukuda
    • F28F23/00F28F1/12F28F1/42F28F21/08B32B7/02B32B15/01B32B15/20
    • F28F19/06F28F1/126F28F21/084F28F21/089Y10S165/905Y10T428/12764Y10T428/31678
    • The present invention provides a heat exchanger which is assembled by brazing an aluminum fin material to the outer surface of an aluminum tube material formed by bending a sheet material, in particular, an aluminum heat exchanger which can be suitably used as an automotive heat exchanger such as a condenser or evaporator. The tube material is formed of a two-layer clad sheet which includes a core material and an Al—Zn alloy layer clad on the core material. The Al—Zn alloy layer is clad on the outer surface of the tube material and brazed to the aluminum fin material. The potential of the Al—Zn alloy layer in a normal corrosive solution is at least 100 mV lower than the potential of the core material in the normal corrosive solution. The potential of the Al—Zn alloy layer in the normal corrosive solution is lower than the potential of the core material in high-concentration corrosive water. The normal corrosive solution refers to an aqueous solution containing 10 g/l of NaCl and 0.3 g/l of Na2SO4, and the high-concentration corrosive water refers to an aqueous solution in which the NaCl concentration is increased by 30 times by concentrating the above aqueous solution.
    • 本发明提供一种热交换器,其通过将铝翅片材料钎焊到通过弯曲板材形成的铝管材料的外表面而组装,特别是铝热交换器,铝热交换器可适合用作汽车热交换器 作为冷凝器或蒸发器。 管材由包含芯材和在芯材上包覆的Al-Zn合金层的双层包覆板形成。 Al-Zn合金层被覆在管材的外表面上并钎焊到铝翅片材料上。 正常腐蚀性溶液中Al-Zn合金层的电位比正常腐蚀性溶液中芯材的电位低至少100mV。 正常腐蚀性溶液中Al-Zn合金层的电位低于高浓度腐蚀性水中芯材的电位。 正常腐蚀性溶液是指含有10g / l NaCl和0.3g / l Na 2 SO 4·4的水溶液,高浓度腐蚀性水是指 通过浓缩上述水溶液使NaCl浓度增加30倍的水溶液。
    • 9. 发明授权
    • Aluminum alloy brazing sheet for use in vacuum brazing
    • 用于真空钎焊的铝合金钎焊板
    • US06063510A
    • 2000-05-16
    • US811047
    • 1997-03-04
    • Yoshihito InabayashiHiroshi KanoNoboru SogaHaruhiko MiyachiEiichi Torigoe
    • Yoshihito InabayashiHiroshi KanoNoboru SogaHaruhiko MiyachiEiichi Torigoe
    • B23K35/28B32B15/01F28D1/03F28F21/08B32B15/20
    • F28F21/089B23K35/286B23K35/288B32B15/016F28D1/0333F28F21/084B23K2201/14B23K2203/10Y10S165/905Y10S428/933Y10T428/12764
    • The present invention relates to an Al alloy brazing sheet for use in vacuum brazing, which is applied to manufacture a heat exchanger having a tank portion and a refrigerant passage respectively formed by bonding press-formed brazing sheets together by means of vacuum brazing. The brazing sheet includes an Al alloy core material having a composition consisting of 0.5 to 2.0 mass % (hereinafter abbreviated simply as %) of Mn, 0.1 to 1.0% of Cu, 0.05 to 0.5% of Mg and 0 to 0.3%. of Ti, with the remainder being Al and inevitable impurities. An Al--Si--Mg alloy brazing filler metal or an alloy brazing filler metal prepared by further adding 0.05 to 1.0% of Sn to the Al--Si--Mg alloy brazing filler metal, is clad on both surfaces of the sheet to a thickness of 5 to 20% the total sheet thickness. An intermediate layer consisting of an Al alloy having a composition consisting of 0.5 to 2.0% of Mn, 0.05 to 0.5% of Mg and 0 to 0.3% of Ti, with the remainder being Al and inevitable impurities, is provided between the core material and the brazing filler metal corresponding to the outside of the tank portion and the refrigerant passage and has a thickness of 30 .mu.m or more, preferably 80 .mu.m or more, and 35% or less of the total sheet thickness. This Al alloy brazing sheet provides excellent outside corrosion resistance for the heat exchanger.
    • 本发明涉及一种用于真空钎焊的Al合金钎焊片,其用于制造具有通过真空钎焊将压制成形的钎焊片粘合在一起的具有罐部和制冷剂通道的热交换器。 钎焊片包括由0.5〜2.0质量%(以下简称为%)Mn,0.1〜1.0%的Cu,0.05〜0.5%的Mg和0〜0.3%组成的Al合金芯材。 的Ti,其余为Al和不可避免的杂质。 通过向Al-Si-Mg合金钎料中进一步添加0.05〜1.0%的Sn而制备的Al-Si-Mg合金钎焊料或合金钎焊料被覆在板的两面上,厚度为 总厚度的5〜20%。 由Al合金组成的中间层,其组成为Mn为0.5〜2.0%,Mg为0.05〜0.5%,Ti为0〜0.3%,余量为Al和不可避免的杂质,芯材与 对应于罐部分和制冷剂通道外侧的钎料,其厚度为30μm以上,优选为80μm以上,35mm以下。 该铝合金钎焊板为热交换器提供优异的外部耐腐蚀性。