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    • 4. 发明申请
    • Two-phase silicate-based yellow phosphor
    • 两相硅酸盐基黄色荧光粉
    • US20060261309A1
    • 2006-11-23
    • US11417690
    • 2006-05-03
    • Yi-Qun LiYi DongShifan ChengDejie TaoNing Wang
    • Yi-Qun LiYi DongShifan ChengDejie TaoNing Wang
    • H01L33/00C09K11/54H01K11/00
    • C09K11/7734H01J61/35H01L33/502H01L2924/0002H01L2924/00
    • Novel two-phase yellow phosphors are disclosed having a peak emission intensity at wavelengths ranging from about 555 nm to about 580 nm when excited by a radiation source having a wavelength ranging from 220 nm to 530 nm. The present phosphors may be represented by the formula a[Srx(M1)1-x]zSiO4●(1-a)[Sry(M2)1-y]uSiO5:Eu2+D, wherein M1 and M2 are at least one of a divalent metal such as Ba, Mg, Ca, and Zn, the values of a, x, y, z and u follow the following relationships: 0.6≦a≦0.85; 0.3≦x≦0.6; 0.85≦y≦1; 1.5≦z≦2.5; 2.6≦u≦3.3; and Eu and D each range from 0.001 to about 0.5. D is an anion selected from the group consisting of F, Cl, Br, S, and N, and at least some of the D anion replaces oxygen in the host silicate lattice of the phosphor. The present yellow phosphors have applications in high brightness white LED illumination systems, LCD display panels, plasma display panels, and yellow LEDs and illumination systems.
    • 公开了当波长范围为220nm至530nm的辐射源激发时,波长范围为约555nm至约580nm的峰值发射强度的新型二相黄色荧光体。 本发明的荧光体可以由式a [Sr x 1(M 1)1-x N z SiO 2 S / >(1-a)[Sr y y(((u u Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu 2 + D,其中M1和M2是二价金属如Ba,Mg,Ca和Zn中的至少一种,a,x,y,z和u的值遵循以下关系 :0.6 <= a <= 0.85; 0.3 <= x <= 0.6; 0.85 <= y <= 1; 1.5 <= z <= 2.5; 2.6 <= u <= 3.3; 并且Eu和D各自为0.001至约0.5。 D是选自F,Cl,Br,S和N的阴离子,并且D阴离子中的至少一些取代荧光体的主体硅酸盐晶格中的氧。 目前的黄色荧光粉可用于高亮度白光LED照明系统,液晶显示面板,等离子显示面板以及黄色LED和照明系统。
    • 10. 发明申请
    • Silicate-based green phosphors
    • 硅酸盐绿色荧光粉
    • US20060145123A1
    • 2006-07-06
    • US11269953
    • 2005-11-08
    • Yi-Qun LiYi DongDejie TaoShifan ChengNing Wang
    • Yi-Qun LiYi DongDejie TaoShifan ChengNing Wang
    • H01L33/00C09K11/08
    • C09K11/7734C09K11/7737H01L33/502
    • Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).
    • 公开了新的绿色荧光体,其具有包含具有式(Sr,A 1 H 2)x Si(Si,Al 2)的硅酸盐基化合物 O,A 3 + 2 + x 2:Eu 2+,其中A 1至少是一个二价阳离子 (2+离子),包括Mg,Ca,Ba或Zn,或1+和3+阳离子的组合; A 2是3+,4+或5+阳离子,包括B,Al,Ga,C,Ge,N和P中的至少一种; A 3是1-,2-或3-阴离子,包括F,Cl,Br和S; x是1.5到2.5之间的任何值,包括两者之间的值。 该公式被写为表示A 1阳离子取代Sr; A 2阳离子取代Si,并且A 3 N阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统,红绿蓝色背光系统,白色LED和等离子显示面板(PDP)中都有应用。