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    • 1. 发明授权
    • Ceramic substrate having a metallic layer thereon and a process for
manufacturing the same
    • 其上具有金属层的陶瓷基板及其制造方法
    • US5008149A
    • 1991-04-16
    • US274481
    • 1988-11-22
    • Yasunori TagaHideya YamaderaKeiji AokiTadashi Hattori
    • Yasunori TagaHideya YamaderaKeiji AokiTadashi Hattori
    • C23C14/02B32B15/04C04B41/52C04B41/88C04B41/89C04B41/90C23C14/06C23C14/16C23C14/58
    • C04B41/009B32B15/04C04B41/52C04B41/89Y10T428/265Y10T428/31678
    • A ceramic substrate and a metallic layer formed thereon are bonded closely by means of a bonding layer formed between the ceramic substrate and the metallic layer. The ceramic substrate comprises either alumina or a ceramic containing alumina, and the metallic layer comprises either molybdenum (Mo) or an alloy composed of molybdenum (Mo) and at least one of titanium (Ti), zirconium (Zr) and niobium (Nb). The bonding layer comprises composite oxides of aluminum and at least one of titanium (Ti), zirconium (Zr) and niobium (Nb) and formed by either a process of (1) forming an intermediate layer comprising at least one of titanium (Ti), zirconium (Zr) and niobium (Nb) between the ceramic substrate and the metallic layer, and subjecting the laminated substance to a heat treatment to a cause a reaction between alumina and the intermediate layer; or (2) forming an alloy layer comprising an alloy of molybdenum (Mo) and at least one of titanium (Ti), zirconium (Zr) and niobium (Nb) directly on the ceramic substrate, and subjecting the laminated substance to a heat treatment to cause a reaction between alumina and at least one of titanium (Ti), zirconium (Zr) and niobium (Nb) contained in the alloy layer.
    • 陶瓷基板和形成在其上的金属层通过形成在陶瓷基板和金属层之间的接合层紧密地接合。 陶瓷基板包括氧化铝或含有氧化铝的陶瓷,金属层包括钼(Mo)或由钼(Mo)和钛(Ti),锆(Zr)和铌(Nb)中的至少一种组成的合金, 。 所述接合层包括铝的复合氧化物和钛(Ti),锆(Zr)和铌(Nb)中的至少一种,并且通过以下工艺形成:(1)形成包含钛(Ti) ,锆(Zr)和铌(Nb)在陶瓷基板和金属层之间,并对叠层物进行热处理以引起氧化铝和中间层之间的反应; 或(2)直接在陶瓷基板上形成包含钼(Mo)和钛(Ti),锆(Zr)和铌(Nb)中的至少一种的合金的合金层,并对层叠物进行热处理 引起氧化铝与合金层中所含的钛(Ti),锆(Zr)和铌(Nb)中的至少一种的反应。
    • 8. 发明授权
    • Optical resonator type organic electroluminescent element
    • 光谐振器型有机电致发光元件
    • US06406801B1
    • 2002-06-18
    • US09243479
    • 1999-02-03
    • Shizuo TokitoKoji NodaHisayoshi FujikawaYasunori Taga
    • Shizuo TokitoKoji NodaHisayoshi FujikawaYasunori Taga
    • H05B3312
    • H01L51/5265Y10S428/917Y10T428/24942
    • An optical resonator type organic electroluminescent element has a multilayered film mirror 30, a transparent electrode 12, an electron hole transportation layer 14 and a luminescent layer 16 configuring an organic layer, and a metallic electrode mirror 20, formed on a glass substrate 10. The optical resonator type organic electroluminescent element amplifies a specific wavelength (especially, in a range of about 30 nm toward a shorter wavelength side from a luminescence peak wavelength of the organic layer) in luminescence light by a minute optical resonator, which comprises the multilayered film mirror 30 and the metallic electrode mirror 20. It is determined that the minute optical resonator has an optical length L which is twice as long as a resonance wavelength, the organic layer has a thickness of 100 nm or more, and the transparent electrode has a thickness of 50 nm or more or a thickness so to have a sheet resistance of 30 &OHgr;/□ or less. Thus, the transparent electrode can be prevented from generating heat even when a large current is caused to flow into it, and the element characteristics can be reliably prevented from being deteriorated. Moreover, the reliability of this element can be improved because the organic layer containing the luminescent layer has a sufficient thickness.
    • 光谐振器型有机电致发光元件具有形成在玻璃基板10上的多层膜反射镜30,透明电极12,电子空穴传输层14和构成有机层的发光层16和金属电极镜20。 光谐振器型有机电致发光元件通过微小的光谐振器在发光中放大特定波长(特别是在距离有机层的发光峰值波长的较短波长侧在约30nm的范围内),其包括多层膜镜 30和金属电极镜20.确定微型光谐振器的光学长度L是谐振波长的两倍,有机层的厚度为100nm以上,透明电极的厚度 为50nm以上,厚度为30Ω/□以下。 因此,即使当大电流流入其中时,也可以防止透明电极产生热量,并且可以可靠地防止元件特性劣化。 此外,由于含有发光层的有机层具有足够的厚度,所以可以提高该元件的可靠性。