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    • 1. 发明授权
    • Method for preparing positive active material for rechargeable lithium battery and positive active material prepared by same
    • 用于制备可再充电锂电池的正极活性材料和由其制备的正极活性材料的方法
    • US07326498B2
    • 2008-02-05
    • US10996724
    • 2004-11-22
    • Yong-Chul ParkGeun-Bae KimJun-Won SuhWon-Il Jung
    • Yong-Chul ParkGeun-Bae KimJun-Won SuhWon-Il Jung
    • H01M4/58
    • H01M4/525H01M4/131H01M4/366H01M4/62H01M10/0525
    • Disclosed is a method of preparing a positive active material for a rechargeable lithium battery including adding first and second compounds to a solvent to prepare an acidic solution with a pH from 0.01 to 3, the first compound including an element that is capable of forming a double bond with an oxygen of a lithium metal oxide, and the second compound including at least one element selected from the group consisting of alkali metals, alkali earth metals, group 13 elements, group 14 elements, transition metals and rare-earth elements; adding a lithium-containing compound to the acidic coating solution to coat the lithium-containing compound; and heat-treating the coated lithium-containing compound to form a surface-treatment layer comprising a compound represented by the formula MXOk where M is an element selected from the group consisting of alkali metals, alkali earth metals, group 13 elements, group 14 elements, transition metals, rare-earth elements and combinations thereof; X is an element that is capable of forming a double bond with oxygen; and k is an integer from 2 to 4.
    • 公开了一种制备用于可再充电锂电池的正极活性材料的方法,包括将第一和第二化合物加入到溶剂中以制备pH为0.01至3的酸性溶液,所述第一化合物包括能够形成双 与锂金属氧化物的氧结合,所述第二化合物包括选自碱金属,碱土金属,第13族元素,第14族元素,过渡金属和稀土元素中的至少一种元素; 向酸性涂料溶液中加入含锂化合物以涂覆含锂化合物; 并且对所述涂覆的含锂化合物进行热处理以形成表面处理层,所述表面处理层包含由式MXO compound表示的化合物,其中M是选自碱金属,碱土金属 ,第13族元素,第14族元素,过渡金属,稀土元素及其组合; X是能够与氧形成双键的元素; k为2〜4的整数。
    • 9. 发明授权
    • Process of preparing active material for battery and active material for battery prepared therefrom
    • 制备用于电池的活性材料和由其制备的电池的活性材料的方法
    • US07473493B2
    • 2009-01-06
    • US10408124
    • 2003-04-08
    • Jae-Phil ChoYong-Chul ParkWon-Il JungGeun-Bae Kim
    • Jae-Phil ChoYong-Chul ParkWon-Il JungGeun-Bae Kim
    • H01M6/08
    • C01G53/42C01G53/006C01G53/50C01P2002/52C01P2002/88C01P2004/61C01P2006/40H01M4/131H01M4/366H01M4/505H01M4/525H01M4/5825H01M10/052H01M10/0587H01M10/4235H01M2004/028
    • A process for preparing an active material for a battery includes the steps of preparing a coating liquid by adding a compound comprising an element X that is capable of forming a double bond with oxygen, and a compound comprising at least one from the group consisting of an alkali metal, an alkaline earth metal, a group 13 element, a group 14 element, a transition metal, and a rare-earth element, to water, adding a metal source to the coating liquid to surface-treat the metal source material, drying the surface-treated metal source material to prepare an active material precursor; mixing the active material precursor with a lithium source; and heat-treating the resultant mixture to produce an active material with a surface-treatment layer comprising the compound of the formula (1): MXOk  (1) wherein M is at least one selected from the group consisting of an alkali metal, an alkaline earth metal, a group 13 element, a group 14 element, a transition metal, and a rare-earth element; X is an element that can form a double bond with oxygen; and k is a numerical value in the range of 2 to 4.
    • 制备电池用活性物质的方法包括以下步骤:通过加入包含能够与氧形成双键的元素X的化合物和包含至少一种来自下组的化合物来制备涂布液: 碱金属,碱土金属,第13族元素,第14族元素,过渡金属和稀土类元素,向水中添加金属源,对金属源物质进行表面处理,干燥 表面处理的金属源材料以制备活性材料前体; 将活性物质前体与锂源混合; 并对所得混合物进行热处理以制备具有包含式(1)化合物的表面处理层的活性材料:<?in-line-formula description =“In-line Formulas”end =“lead”→> MXOk(1)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中M是选自碱金属,碱土金属,第13族中的至少一种 元素,14族元素,过渡金属和稀土元素; X是可与氧形成双键的元素; k为2〜4的数值。