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    • 5. 发明授权
    • Washing agents containing, as additives, carboxyl-containing copolymers
which are neutralized or amidated with amines
    • 作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂
    • US4702858A
    • 1987-10-27
    • US888957
    • 1986-07-24
    • Walter DenzingerHeinrich HartmannWolfgang TrieseltErhard KlahrAlbert Hettche
    • Walter DenzingerHeinrich HartmannWolfgang TrieseltErhard KlahrAlbert Hettche
    • C08F8/32C08F8/44C11D3/37
    • C11D3/3761C11D3/3769
    • Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.
    • 洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂,丙烯酸和甲基丙烯酸的均聚物,丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的(a)烯属不饱和二羧酸 4至6个碳原子,和(b)丙烯酸,甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元,其中以自由基形式存在的均聚物和共聚物 酸的中和或酰胺化形式的重均分子量为5000至500,000,每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和,其中R为C8-C18 - 烷基或R 1 -O-CH 2 - (CH 2)n - ,n为1至3,R 1为C 1 -C 18烷基,R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50% 的所述羧基为衍生自原料的酰胺形式 芳胺和仲胺。