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    • 5. 发明授权
    • Nitrogen oxide storage catalyst
    • 氮氧化物储存催化剂
    • US06413904B1
    • 2002-07-02
    • US09417915
    • 1999-10-13
    • Wolfgang StrehlauUlrich GöbelRainer Domesle
    • Wolfgang StrehlauUlrich GöbelRainer Domesle
    • B01J2358
    • B01D53/9422B01D2255/1021B01D2255/1025B01D2255/202B01D2255/204B01D2255/2042B01D2255/2092B01D2255/407B01J23/58B01J23/63B01J27/053
    • A nitrogen oxide storage catalyst which contains at least one catalyst material and at least one nitrogen oxide storage component from the group of alkali and alkaline earth metals. The nitrogen oxide storage component, after completing catalyst preparation, is present as finely divided barium sulfate, strontium sulfate, a mixture or mixed crystals of the two sulfates, or as their complete or incomplete decomposition product with an average particle size of less than 1 &mgr;m. Barium sulfate and/or strontium sulfate act as feed materials for the active storage component in the storage catalyst according to the invention. As a result of the reductive exhaust gas compositions occurring under normal automobile driving conditions barium sulfate and strontium sulfate decompose to compounds which are able to store nitrogen oxides. This compensates for the loss of active storage components which occurs due to aging. Barium sulfate and/or strontium sulfate may be decomposed during production by means of reductive calcination in order to obtain a high initial loading of the catalyst with storage compounds. In this case, these sulfates are used as auxiliary agents in order to introduce the highest possible concentrations of storage compounds into the storage catalyst.
    • 含有至少一种催化剂材料和至少一种来自碱金属和碱土金属组的氮氧化物储存组分的氮氧化物储存催化剂。 完成催化剂制备后,氮氧化物储存组分以细碎的硫酸钡,硫酸锶,两种硫酸盐的混合物或混合物形式存在,或作为其完全或不完全的分解产物,平均粒度小于1um 。 硫酸钡和/或硫酸锶作为根据本发明的储存催化剂中的活性储存组分的进料。 由于在正常的汽车驾驶条件下发生的还原废气组合物的结果是硫酸钡和硫酸锶分解成能够存储氮氧化物的化合物。 这补偿了由于老化而发生的主动存储组件的损失。 硫酸钡和/或硫酸锶可以通过还原煅烧在生产过程中分解,以便用储存化合物获得催化剂的初始负载量。 在这种情况下,这些硫酸盐用作辅助剂,以便将最高可能浓度的储存化合物引入储存催化剂中。
    • 7. 发明授权
    • Process for evaluating performance deterioration of a nitrogen oxide storage catalyst
    • 用于评估氮氧化物存储催化剂的性能劣化的方法
    • US06216449B1
    • 2001-04-17
    • US09288075
    • 1999-04-08
    • Wolfgang StrehlauLothar MussmannUlrich Göbel
    • Wolfgang StrehlauLothar MussmannUlrich Göbel
    • F01N300
    • F01N3/0814B01D53/9495F01N3/0807F01N3/0842F01N3/0864F01N11/007F01N2550/03F01N2570/16F01N2900/0422F02D41/0235F02D41/1441F02D41/1456F02D2200/0808F02D2200/0816Y02T10/47
    • A process for evaluating performance deterioration of a nitrogen oxide storage catalyst which has a nitrogen oxide storage function and an oxygen storage function and is operated with cyclic alternation of the air/fuel ratio in the exhaust gas from lean to rich. The nitrogen oxides are stored during the lean phase and the nitrogen oxides are desorbed and converted during the rich phase. To check the serviceability of the storage catalyst, the air/fuel ratio of the exhaust gas is switched from lean to rich and the rich phase is extended beyond the time required for complete desorption of the nitrogen oxides until at least the rich exhaust gas passes right through the catalyst and the time interval &Dgr;t1 produced between the first change-over until breakthrough of the rich exhaust gas and, after again switching from rich to lean running, the time interval &Dgr;t2 produced between the second change-over and passage of oxygen through the catalyst are measured and the time differences &Dgr;t1 and &Dgr;t2 are used for separate assessment of the oxygen storage function and the nitrogen oxide storage function of the catalyst.
    • 一种用于评估具有氮氧化物存储功能和储氧功能的氮氧化物存储催化剂的性能劣化的方法,并且在废气中的空气/燃料比的循环交替从贫到富运行。 氮氧化物在稀相期间储存,氮氧化物在富相期间解吸和转化。 为了检查储存催化剂的使用性能,废气的空气/燃料比从稀释转为富,富相扩展到氮氧化物完全解吸所需的时间,直到至少富排气向右流动 通过催化剂和在第一次转换之间产生的时间间隔DELTAt1直到富排气的突破之间,并且在再次从富运行切换到稀薄运行之后,在氧气通过第二转换和通过之间产生的时间间隔DELTAt2 测量催化剂,并将时间差DELTAt1和DELTAt2用于分离评估催化剂的储氧功能和氮氧化物储存功能。