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1. 发明授权

US06858193B2 Catalyst for lowering the amount of nitrogen oxides in the exhaust gas from lean burn engines 有权
标题翻译：用于降低来自稀燃燃烧发动机的废气中的氮氧化物的量的催化剂
公开(公告)号：US06858193B2
公开(公告)日：2005-02-22
申请号：US10306675
申请日：2002-11-27
申请人： Lutz Marc Ruwisch , Ulrich Göbel , Juliane Theis , Rainer Domesle
发明人： Lutz Marc Ruwisch , Ulrich Göbel , Juliane Theis , Rainer Domesle
IPC分类号： F01N3/08 , B01D53/94 , B01J21/00 , B01J23/40 , B01J23/58 , B01J23/63 , B01J37/02 , F01N3/10 , F01N3/20 , B01J21/04 , B01J21/10 , B01J23/02 , B01J23/10
CPC分类号： B01D53/9422 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/407 , B01J21/005 , B01J23/58 , B01J23/63 , B01J37/0203 , B01J37/0215 , B01J37/0248
摘要： The invention relates to a catalyst for lowering the amount of NOx in the lean exhaust gas from lean burn engines, comprising active aluminum oxide, magnesium oxide and at least one noble metal of the platinum group of the periodic table of the elements, as well as at least one nitrogen oxide storage material. The catalyst is characterized in that the magnesium oxide forms a homogeneous mixed oxide with aluminum oxide and is present in a concentration of about 1 to about 40 wt.-%, based on the total weight of the mixed oxide.
摘要翻译：本发明涉及一种用于降低来自贫燃发动机的贫废气中的NOx的量的催化剂，其包括活性氧化铝，氧化镁和至少一种元素周期表铂族的贵金属，以及至少一种氮氧化物储存材料。催化剂的特征在于，氧化镁与氧化铝形成均匀的混合氧化物，并且以混合氧化物的总重量计约1至约40重量％的浓度存在。

2. 发明授权

US06413904B1 Nitrogen oxide storage catalyst 有权
标题翻译：氮氧化物储存催化剂
公开(公告)号：US06413904B1
公开(公告)日：2002-07-02
申请号：US09417915
申请日：1999-10-13
申请人： Wolfgang Strehlau , Ulrich Göbel , Rainer Domesle
发明人： Wolfgang Strehlau , Ulrich Göbel , Rainer Domesle
IPC分类号： B01J2358
CPC分类号： B01D53/9422 , B01D2255/1021 , B01D2255/1025 , B01D2255/202 , B01D2255/204 , B01D2255/2042 , B01D2255/2092 , B01D2255/407 , B01J23/58 , B01J23/63 , B01J27/053
摘要： A nitrogen oxide storage catalyst which contains at least one catalyst material and at least one nitrogen oxide storage component from the group of alkali and alkaline earth metals. The nitrogen oxide storage component, after completing catalyst preparation, is present as finely divided barium sulfate, strontium sulfate, a mixture or mixed crystals of the two sulfates, or as their complete or incomplete decomposition product with an average particle size of less than 1 &mgr;m. Barium sulfate and/or strontium sulfate act as feed materials for the active storage component in the storage catalyst according to the invention. As a result of the reductive exhaust gas compositions occurring under normal automobile driving conditions barium sulfate and strontium sulfate decompose to compounds which are able to store nitrogen oxides. This compensates for the loss of active storage components which occurs due to aging. Barium sulfate and/or strontium sulfate may be decomposed during production by means of reductive calcination in order to obtain a high initial loading of the catalyst with storage compounds. In this case, these sulfates are used as auxiliary agents in order to introduce the highest possible concentrations of storage compounds into the storage catalyst.
摘要翻译：含有至少一种催化剂材料和至少一种来自碱金属和碱土金属组的氮氧化物储存组分的氮氧化物储存催化剂。完成催化剂制备后，氮氧化物储存组分以细碎的硫酸钡，硫酸锶，两种硫酸盐的混合物或混合物形式存在，或作为其完全或不完全的分解产物，平均粒度小于1um 。硫酸钡和/或硫酸锶作为根据本发明的储存催化剂中的活性储存组分的进料。由于在正常的汽车驾驶条件下发生的还原废气组合物的结果是硫酸钡和硫酸锶分解成能够存储氮氧化物的化合物。这补偿了由于老化而发生的主动存储组件的损失。硫酸钡和/或硫酸锶可以通过还原煅烧在生产过程中分解，以便用储存化合物获得催化剂的初始负载量。在这种情况下，这些硫酸盐用作辅助剂，以便将最高可能浓度的储存化合物引入储存催化剂中。

3. 发明授权

US06338831B1 Storage material for sulfur oxides 有权
标题翻译：硫氧化物的储存材料
公开(公告)号：US06338831B1
公开(公告)日：2002-01-15
申请号：US09276903
申请日：1999-03-26
申请人： Wolfgang Strehlau , Ulrich Göbel , Rainer Domesle , Egbert Lox , Thomas Kreuzer
发明人： Wolfgang Strehlau , Ulrich Göbel , Rainer Domesle , Egbert Lox , Thomas Kreuzer
IPC分类号： B01D5350
CPC分类号： B01J20/08 , B01D53/508 , B01D53/94 , B01J20/041 , B01J20/28042 , B01J20/28057 , B01J20/3078 , B01J20/3204 , B01J20/3236
摘要： A sulfur oxide storage material contains a magnesium-aluminum spinel (MgO.Al2O3) and can be used as a so-called “sulfur trap” to remove sulfur oxides from oxygen-containing exhaust gases of industrial processes. In particular, it can be used for the catalytic purification of exhaust gas from internal-combustion engines to remove the sulfur oxides from the exhaust gas in order to protect the exhaust gas catalysts from sulfur poisoning. The material displays a molar ratio of magnesium oxide to aluminum oxide in the range of over 1.1:1, and the magnesium oxide present in stoichiometric excess is homogeneously distributed in a highly disperse form in the storage material.
摘要翻译：硫氧化物储存材料含有镁 - 铝尖晶石（MgO·Al 2 O 3），并且可以用作所谓的“硫阱”，以从工业过程的含氧废气中除去硫氧化物。特别地，其可以用于从内燃机排出的废气的催化净化，以从废气中除去硫氧化物，以保护废气催化剂免受硫中毒。该材料显示氧化铝与氧化铝的摩尔比在1.1:1以上，以化学计量过量存在的氧化镁以高分散形式均匀地分布在储存材料中。

4. 发明授权

US06475951B1 Catalyst material 有权
标题翻译：催化剂材料
公开(公告)号：US06475951B1
公开(公告)日：2002-11-05
申请号：US09513341
申请日：2000-02-25
申请人： Rainer Domesle , Ulrich Göbel , Lothar Mussmann , Egbert Lox , Thomas Kreuzer
发明人： Rainer Domesle , Ulrich Göbel , Lothar Mussmann , Egbert Lox , Thomas Kreuzer
IPC分类号： B01J2300
CPC分类号： B01D53/945 , B01J23/002 , B01J23/58 , B01J23/63 , B01J37/0205 , B01J37/0248 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/48
摘要： A powdered catalyst material based on aluminum oxide, which contains at least one basic metal oxide and at least one noble metal from the platinum group of the Periodic Table of Elements in addition to aluminum oxide. The catalyst material is obtainable by loading a support material already stabilized by basic oxides by renewed impregnation with further basic oxides. After drying and calcining this post-impregnated material at temperatures below 800° C., the catalytically active noble metals are also incorporated into the support material by impregnation.
摘要翻译：基于氧化铝的粉末状催化剂材料，其除了氧化铝之外还含有至少一种碱金属氧化物和至少一种来自元素周期表的铂族的贵金属。催化剂材料可以通过用另外的碱性氧化物再次浸渍加载已经通过碱性氧化物稳定的载体材料而获得。在低于800℃的温度下干燥和煅烧该浸渍后材料之后，催化活性的贵金属也通过浸渍掺入载体材料中。

5. 发明授权

US06350421B1 Nitrogen oxide storage material and nitrogen oxide storing catalyst prepared therefrom 有权
标题翻译：氮氧化物储存材料和由其制备的氮氧化物储存催化剂
公开(公告)号：US06350421B1
公开(公告)日：2002-02-26
申请号：US09378693
申请日：1999-08-23
申请人： Wolfgang Strehlau , Ulrich Göbel , Lothar Mussmann , Rainer Domesle
发明人： Wolfgang Strehlau , Ulrich Göbel , Lothar Mussmann , Rainer Domesle
IPC分类号： B01D5392
CPC分类号： F01N3/0864 , B01D53/9422 , B01D2255/1021 , B01D2255/1025 , B01D2255/2042 , B01D2255/2045 , B01D2255/2066 , B01D2255/2068 , B01D2255/20707 , B01D2255/407 , B01D2255/9207 , B01J23/02 , B01J23/10 , B01J23/63 , B01J35/023 , B01J37/03 , F01N3/0807 , F01N3/0842 , Y10S502/514
摘要： A nitrogen oxide storage material is disclosed which contains at least one storage component for nitrogen oxides in the form of an oxide, mixed oxide, carbonate or hydroxide of the alkaline earth metals magnesium, calcium, strontium and barium and the alkali metals potassium and caesium on a high surface area support material. The support material can be doped cerium oxide, cerium/zirconium mixed oxide, calcium titanate, strontium titanate, barium titanate, barium stannate, barium zirconate, magnesium oxide, lanthanum oxide, praseodymium oxide, samarium oxide, neodymium oxide, yttrium oxide, zirconium silicate, yttrium barium cuprate, lead titanate, tin titanate, bismuth titanate, lanthanum cobaltate, lanthanum manganate and barium cuprate or mixtures thereof.
摘要翻译：公开了一种氮氧化物储存材料，其含有至少一种以碱土金属镁，钙，锶和钡的氧化物，混合氧化物，碳酸盐或氢氧化物形式的氮氧化物和碱金属钾和铯的形式的储存组分高表面积的支撑材料。载体材料可以掺杂氧化铈，铈/锆混合氧化物，钛酸钙，钛酸锶，钛酸钡，锡酸钡，锆酸钡，氧化镁，氧化镧，氧化镨，氧化钐，氧化钕，氧化钇，硅酸锆，钇钡铜酸盐，钛酸铅，钛酸钇，钛酸铋，钴酸镧，锰酸镧和铜酸钡或其混合物。

6. 发明申请

US20080247931A1 Method for Producing Multi-Constituent, Metal Oxide Compounds Containing Alkali Metals,and thus Produced Metal Oxide Compounds 审中-公开
标题翻译：生产含有碱金属和因此生产的金属氧化物化合物的多组分金属氧化物的方法
公开(公告)号：US20080247931A1
公开(公告)日：2008-10-09
申请号：US11662125
申请日：2005-09-10
申请人： Rainer Domesle , Stefan Ambrousius , Thomas Kreuzer
发明人： Rainer Domesle , Stefan Ambrousius , Thomas Kreuzer
IPC分类号： C01F17/00 , C01F7/04 , C01G45/02 , C01G51/04 , C01G25/02 , C01G49/02 , C01G37/02 , C01G53/04 , C01G9/02
CPC分类号： C01G25/00 , C01B13/20 , C01B13/34 , C01F7/043 , C01G45/1242 , C01G45/125 , C01G45/1257 , C01G51/42 , C01G51/54 , C01G53/42 , C01P2002/50 , C01P2002/60 , C01P2004/61 , C01P2006/12 , C01P2006/82
摘要： The preparation of finely divided, alkali metal-containing metal oxide powders which contain at least one alkali metal and at least one further metal from the group consisting of the transition metals, the remaining main group metals, the lanthanides and actinides is described. Precursor compounds of these components are introduced in solid form or in the form of a solution or a suspension into a pulsation reactor having a gas flow resulting from a flameless combustion and partly or completely converted into the desired multicomponent metal oxide powder.
摘要翻译：描述了含有至少一种碱金属和至少一种另外的金属的细碎的含碱金属的金属氧化物粉末的制备，所述金属氧化物粉末由过渡金属，剩余的主要金属，镧系元素和锕系元素组成。将这些组分的前体化合物以固体形式或溶液或悬浮液的形式引入到具有由无焰燃烧产生的气流并且部分或完全转化为所需多组分金属氧化物粉末的脉动反应器中。

7. 发明授权

US06627257B1 Process for coating the flow channels in a monolithic catalyst carrier with a coating dispersion 有权
标题翻译：用涂布分散体涂覆整体式催化剂载体中的流动通道的方法
公开(公告)号：US06627257B1
公开(公告)日：2003-09-30
申请号：US09377157
申请日：1999-08-19
申请人： Martin Foerster , Josef Piroth , Ulrich Schlachter , Rainer Domesle , Willi Krampe
发明人： Martin Foerster , Josef Piroth , Ulrich Schlachter , Rainer Domesle , Willi Krampe
IPC分类号： B05D312
CPC分类号： B01J37/0215
摘要： A process for coating the flow channels in a monolithic, cylindrically shaped catalyst carrier with a coating dispersion, wherein the carrier has two end faces which are connected to each other by flow channels arranged parallel to the axis of the cylinder, by vertically aligning the axis of the cylindrical carrier, placing a predetermined amount of coating dispersion from a storage container on the upper end face of the carrier and drawing the dispersion through the flow channels under suction, removing excess coating dispersion from the flow channels by emptying the flow channels under suction, returning the excess dispersion to the storage container and fixing the dispersion coating by calcination. The coating dispersion is drawn through the flow channels under suction at a rate of flow of 0.1 to 1 m/s and after completion of passage under suction the excess coating dispersion is removed from the flow channels by applying a suction impulse from below, wherein the suction air is drawn through the flow channels under suction at a rate of flow between 40 and 1 m/s and the excess coating dispersion discharged with the air stream is separated from the air stream within a time of less than 100 ms after discharge from the catalyst carrier.
摘要翻译：一种用于在具有涂层分散体的整体式圆柱形催化剂载体中涂覆流动通道的方法，其中载体具有两个端面，所述两个端面通过平行于圆柱体的轴线布置的流动通道彼此连接，将预定量的涂布分散体从储存容器放置在载体的上端面上，并在抽吸下将分散体抽吸通过流动通道，通过在抽吸下排空流动通道从流动通道中除去多余的涂层分散体将过量的分散体返回到储存容器中并通过煅烧固定分散涂层。涂层分散体在抽吸下以0.1至1m / s的流速抽吸通过流动通道，并且在抽吸完成之后，通过从下方施加抽吸冲击从流动通道中除去多余的涂层分散体，其中吸入空气以40〜1m / s之间的流量在吸入下被抽吸通过流动通道，并且在排出之后，在空气流中排出的过量涂层分散体在小于100ms的时间内与空气流分离催化剂载体。

8. 发明授权

US5073532A Catalyst for purifying exhaust gases from internal combustion engines and method of making the catalyst 失效
标题翻译：用于从内燃机中净化排气的催化剂及制备催化剂的方法
公开(公告)号：US5073532A
公开(公告)日：1991-12-17
申请号：US559095
申请日：1990-07-30
申请人： Rainer Domesle , Bernd Engler , Edgar Koberstein , Peter Schubert
发明人： Rainer Domesle , Bernd Engler , Edgar Koberstein , Peter Schubert
IPC分类号： B01D53/94 , B01J23/56 , B01J23/63 , B01J23/89 , B01J37/02
CPC分类号： B01D53/945 , B01J23/63 , B01J23/894 , Y02T10/22
摘要： A catalyst is described made of active aluminum oxide with additives of CeO.sub.2, ZrO.sub.2, and Fe.sub.2 O.sub.3 and/or NiO as carrier and an active phase, applied thereon and consisting of platinum, palladium and/or rhodium, and a base metal, which is obtainable by impregnation of the additive-containing carrier with solutions of salts of the metals for the active phase, wherein the base metal of the active phase is cerium, by drying, and by heating to 250.degree. to 650.degree. C. The catalyst can be used for the oxidation and/or reduction of exhaust gases from internal combustion engines.
摘要翻译：催化剂由具有CeO 2，ZrO 2和Fe 2 O 3和/或NiO作为载体的添加剂和施加在其上并由铂，钯和/或铑和贱金属组成的活性相的活性氧化铝制成，其可获得通过用活性相的金属盐溶液浸渍含添加剂的载体，其中活性相的贱金属是铈，通过干燥，加热至250〜650℃。可以使用催化剂用于氧化和/或还原来自内燃机的废气。

9. 发明授权

US06685900B2 Catalyst for purifying the exhaust gases of diesel engines, and process for the preparation thereof 有权
标题翻译：用于净化柴油发动机废气的催化剂及其制备方法
公开(公告)号：US06685900B2
公开(公告)日：2004-02-03
申请号：US09789718
申请日：2001-02-22
申请人： Rainer Domesle , Harald Klein , Thomas Kreuzer , Egbert Lox
发明人： Rainer Domesle , Harald Klein , Thomas Kreuzer , Egbert Lox
IPC分类号： B01J802
CPC分类号： B01J29/068 , B01D53/944 , B01D53/945 , B01J21/12 , B01J23/42 , B01J37/0246 , B01J37/0248 , F01N3/022 , F01N3/2803 , F01N2370/04 , Y02A50/2324 , Y02A50/2341 , Y02T10/22
摘要： A catalyst for purifying the exhaust gases of diesel engines, which catalyst contains at least one zeolite and, additionally, at least one of the support oxides aluminum oxide, silicon dioxide, titanium dioxide and aluminum silicate and at least one of the noble metals platinum, palladium, rhodium and iridium. In this catalyst the atoms of the noble metals have a mean oxidation number of less than +2.5, on average more than 3 metal ligands and less than 3 oxygen ligands and are present on the zeolites and support oxides in the form of crystallites having a mean particle size of from 1 to 6 nm.
摘要翻译：一种用于净化柴油发动机废气的催化剂，该催化剂含有至少一种沸石，另外，至少一种载体氧化物氧化铝，二氧化硅，二氧化钛和硅酸铝以及至少一种贵金属铂，钯，铑和铱。在该催化剂中，贵金属的原子具有平均氧化数小于+2.5，平均多于3个金属配体和少于3个氧配体，并且存在于沸石和以平均形式存在的微晶形式的载体氧化物上粒度为1〜6nm。

10. 发明授权

US06596056B2 Process for coating a ceramic honeycomb body 有权
标题翻译：涂覆陶瓷蜂窝体的方法
公开(公告)号：US06596056B2
公开(公告)日：2003-07-22
申请号：US09745176
申请日：2000-12-22
申请人： Rainer Domesle , Thomas Kreuzer , Egbert Lox
发明人： Rainer Domesle , Thomas Kreuzer , Egbert Lox
IPC分类号： B05D722
CPC分类号： C04B41/009 , B01J35/04 , B01J37/0217 , C04B41/52 , C04B2111/0081 , C04B2111/00844 , F01N3/2828 , F01N2260/18 , Y10S55/30 , Y10T428/24149 , C04B41/502 , C04B41/4539 , C04B41/457 , C04B41/50 , C04B38/0006
摘要： A process for coating, with a suspension, a ceramic honeycomb body which has a cylindrical shape with two flat end-faces and one jacket, and through which channels parallel to the axis, formed by channel walls, run from one flat end-face to the other, the honeycomb body being coated by suitable processes. The honeycomb body is partially wetted and then coated.
摘要翻译：一种用悬浮液涂覆陶瓷蜂窝体的方法，陶瓷蜂窝体具有两个平坦的端面和一个护套的圆柱形形状，并且通过通道壁形成的平行于轴线的通道通过该通道从一个平坦的端面延伸到另一方面，蜂窝体被适当的工艺涂覆。蜂窝体被部分润湿然后涂覆。

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