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1. 发明授权

US5973047A Moisture-curing sealing and bonding compound 失效
标题翻译：水分固化密封和粘合剂
公开(公告)号：US5973047A
公开(公告)日：1999-10-26
申请号：US952246
申请日：1997-10-15
申请人： Wolfgang Ernst , Martin Majolo , Johann Klein , Michael Dziallas , Tore Podola
发明人： Wolfgang Ernst , Martin Majolo , Johann Klein , Michael Dziallas , Tore Podola
IPC分类号： C08L75/00 , C09D5/34 , C09J127/06 , C09J175/04 , C09K3/10 , C08K5/11 , C09J4/00
CPC分类号： C09K3/1021 , C09D5/34 , C09J127/06 , C09J175/04 , C08L75/00 , C09K2200/0447 , C09K2200/0635 , C09K2200/0682 , C09K2200/0685
摘要： Described is a moisture-curing sealing and bonding compound made from completely synthetic polymers, the compound containing, to improve its non-sag properties, a triglyceride, either as the sole non-sag agent or in addition to prior art agents. The triglyceride should have a melting point over 40.degree. C., preferably over 50.degree. C., and be derived from saturated fatty acids with 8 to 26 C-atoms. Even without using thixotropic agents, compounds can be obtained which do not sag at temperatures over 40.degree. C. Such joint sealants can be used to fill joints more than 35 mm wide without sagging.
摘要翻译： PCT No.PCT / EP96 / 01512 Sec。 371日期：1997年10月15日 102（e）1997年10月15日PCT PCT 1996年4月9日PCT公布。公开号WO96 / 33249 日期1996年10月24日描述的是由完全合成的聚合物制成的湿固化密封和粘结化合物，该化合物含有为了改善其不起伏性能，甘油三酸酯作为唯一的非起泡剂或除现有技术之外代理商甘油三酸酯应具有超过40℃，优选超过50℃的熔点，并且衍生自具有8至26个C原子的饱和脂肪酸。即使不使用触变剂，也可以获得在40℃以上不起伏的化合物。这种接头密封剂可用于填充超过35毫米宽的接缝而不会下垂。

2. 发明授权

US06790903B1 Dispersions of silyl-terminated polymers with a high solids content, their production and their use 有权
标题翻译：具有高固体含量的甲硅烷基封端的聚合物的分散体，它们的生产及其用途
公开(公告)号：US06790903B1
公开(公告)日：2004-09-14
申请号：US09857933
申请日：2001-06-11
申请人： Martin Majolo , Wolfgang Klauck , Johann Klein , Wolfgang Ernst , Gaby Schilling , Helmut Loth
发明人： Martin Majolo , Wolfgang Klauck , Johann Klein , Wolfgang Ernst , Gaby Schilling , Helmut Loth
IPC分类号： C08L7504
CPC分类号： C08J3/03 , C08G18/289 , C08G18/718 , C08J2300/108 , C09D5/34 , C09D201/10 , C09J201/10 , C09K3/1021
摘要： The invention relates to a polymer dispersion containing water and at least 60 wt. % of an organic polymer which has at least one group of general formula (I) A—Si(Z)n(OH)3-n. The invention also relates to a composition containing at least one organic polymer which has at least one group of general formula (I), and at least one other organic polymer or a mixture of two or more other organic polymers.
摘要翻译：本发明涉及含有水和至少60wt。％具有至少一个通式（I）A-Si（Z）n（OH）3-n的基团的有机聚合物。本发明还涉及含有至少一种具有至少一个通式（I）的基团的有机聚合物和至少一种其它有机聚合物或两种或更多种其它有机聚合物的混合物的组合物。

3. 发明申请

US20120108730A1 CURABLE COMPOSITION HAVING A SILANE-MODIFIED REACTIVE THINNER 失效
标题翻译：具有硅烷改性反应性薄膜的可固化组合物
公开(公告)号：US20120108730A1
公开(公告)日：2012-05-03
申请号：US13316935
申请日：2011-12-12
申请人： Lars Zander , Rolf Tenhaef , Johann Klein , Martin Majolo , Thomas Tamcke , Thomas Bachon , Jens Lückert , Thomas Plantenberg
发明人： Lars Zander , Rolf Tenhaef , Johann Klein , Martin Majolo , Thomas Tamcke , Thomas Bachon , Jens Lückert , Thomas Plantenberg
IPC分类号： C08L83/16 , C09J183/16 , C09D183/16 , C08G77/60
CPC分类号： C08G77/20 , C08G77/26 , C08G77/46 , C09D183/12
摘要： A solvent-free and anhydrous hardenable composition that contains at least one polymer A. Polymer A being obtainable by reacting a polyether with at least one ethylenically unsaturated silane in the presence of a radical starter, the ethylenically unsaturated silane carrying at least one hydrolyzable group on the silicon atom. The composition provides low viscosity prior to curing along with good elasticity after curing and a broad adhesion spectrum in a solvent-free and water-free hardenable composition. Also methods for producing the composition and use of the composition as an adhesive, sealant, or coating agent.
摘要翻译：含有至少一种聚合物A的无溶剂和无水可固化组合物。聚合物A可通过在自由基引发剂存在下使聚醚与至少一种烯属不饱和硅烷反应获得，所述烯属不饱和硅烷在至少一个可水解基团上载有硅原子。组合物在固化前具有低粘度以及固化后的良好弹性和在无溶剂和无水可硬化组合物中的宽粘附光谱。还有用于生产组合物的方法以及组合物作为粘合剂，密封剂或包衣剂的用途。

4. 发明申请

US20110166285A1 SEALING MASS THAT CAN BE CROSS-LINKED USING WATER 审中-公开
标题翻译：密封可以使用水交叉连接的质量
公开(公告)号：US20110166285A1
公开(公告)日：2011-07-07
申请号：US12954184
申请日：2010-11-24
申请人： Lars Zander , Jens Lueckert , Martin Majolo , Andreas Bolte , Johann Klein , Thomas Bachon , Sven Balk , Holger Kautz , Stephan Fengler
发明人： Lars Zander , Jens Lueckert , Martin Majolo , Andreas Bolte , Johann Klein , Thomas Bachon , Sven Balk , Holger Kautz , Stephan Fengler
IPC分类号： C08L53/00
CPC分类号： C09J153/00 , C08F290/068 , C08G18/4825 , C08G18/718 , C08G2190/00 , C08L53/00 , C08L2666/02 , C08L2666/06 , C09D153/00 , C09D175/04 , C09J175/04 , C08L2666/20
摘要： The invention relates to a cross-linkable composition containing 10-50% by weight of silane-group terminated polymers with a number average molecular weight of between 3,000 and 30,000 g/mol, 0.5 to 20% by weight of (meth)acrylate block copolymers of type A(BA)n, where n=1 to 5 and said copolymers contain at least two hydrolysable silane groups, 85 to 40% by weight of fillers and auxiliary agents, the sum of the constituents totalling 100%. The invention is characterised in that the (meth)acrylate block copolymers have a number average molecular weight of between 5,000 and 100,000 g/mol and that the silane groups are contained in at least one block A or B and said groups are not terminal in the polymer chain.
摘要翻译：本发明涉及一种可交联的组合物，其含有10-50％（重量）数均分子量为3,000至30,000g / mol的硅烷基封端的聚合物，0.5至20％（重量）的（甲基）丙烯酸酯嵌段共聚物的A（BA）n，其中n = 1至5，并且所述共聚物含有至少两个可水解硅烷基团，85至40重量％的填料和助剂，总和为100％。本发明的特征在于，（甲基）丙烯酸酯嵌段共聚物的数均分子量为5000〜100,000g / mol，硅烷基包含在至少一个嵌段A或B中，所述基团不在末端聚合物链。

5. 发明授权

US08450411B2 Curable composition having a silane-modified reactive thinner 失效
标题翻译：具有硅烷改性反应性稀释剂的可固化组合物
公开(公告)号：US08450411B2
公开(公告)日：2013-05-28
申请号：US13316935
申请日：2011-12-12
申请人： Lars Zander , Rolf Tenhaef , Johann Klein , Martin Majolo , Thomas Tamcke , Thomas Bachon , Jens Lückert , Thomas Plantenberg
发明人： Lars Zander , Rolf Tenhaef , Johann Klein , Martin Majolo , Thomas Tamcke , Thomas Bachon , Jens Lückert , Thomas Plantenberg
IPC分类号： C08L83/00 , C08G18/42
CPC分类号： C08G77/20 , C08G77/26 , C08G77/46 , C09D183/12
摘要： A solvent-free and anhydrous hardenable composition that contains at least one polymer A. Polymer A being obtainable by reacting a polyether with at least one ethylenically unsaturated silane in the presence of a radical starter, the ethylenically unsaturated silane carrying at least one hydrolyzable group on the silicon atom. The composition provides low viscosity prior to curing along with good elasticity after curing and a broad adhesion spectrum in a solvent-free and water-free hardenable composition. Also methods for producing the composition and use of the composition as an adhesive, sealant, or coating agent.
摘要翻译：含有至少一种聚合物A的无溶剂和无水可固化组合物。聚合物A可通过在自由基引发剂存在下使聚醚与至少一种烯属不饱和硅烷反应获得，所述烯属不饱和硅烷在至少一个可水解基团上载有硅原子。组合物在固化前具有低粘度以及固化后的良好弹性和在无溶剂和无水可硬化组合物中的宽粘附光谱。还有用于生产组合物的方法以及组合物作为粘合剂，密封剂或包衣剂的用途。

6. 发明申请

US20110028640A1 HARDENABLE COMPOSITIONS BASED ON SILYLATED POLYURETHANES 审中-公开
标题翻译：基于苯乙烯基聚氨酯的复合组合物
公开(公告)号：US20110028640A1
公开(公告)日：2011-02-03
申请号：US12906215
申请日：2010-10-18
申请人： Johann Klein , Sara Gonzalez , Lars Zander , Christiane Kunze , Thomas Bachon , Andreas Bolte , Martin Majolo , Thomas Tamcke
发明人： Johann Klein , Sara Gonzalez , Lars Zander , Christiane Kunze , Thomas Bachon , Andreas Bolte , Martin Majolo , Thomas Tamcke
IPC分类号： C08L83/08 , C08G77/08
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/227 , C08G2190/00 , C09J175/08 , C08G18/718
摘要： The invention relates to a method for producing cross-linkable formulations. In a first step of the method, at least one α,ω-difunctional organic polymer of formula (1) X-A-X (1) is converted into organyloxysilyl-terminated polymers P1, using organofunctional silanes of formula (2) Y—R—Si—(R1)m(—OR2)3m (2), in the presence of catalysts (A) selected from the group consisting of potassium, iron, indium, zinc, bismuth and copper compounds. In said formulae, R is a bivalent, optionally substituted hydrocarbon group which comprises between 1 and 12 carbon atoms and can be interrupted with heteroatoms, R1 and R2 are the same or different, monovalent, optionally substituted hydrocarbon groups which comprise between 1 and 12 carbon atoms and can be interrupted with heteroatoms, A is bivalent, optionally substituted hydrocarbon group which comprises at least 6 carbon atoms and can be interrupted with heteroatoms, m is equal to 0, 1 or 2, X is a hydroxyl group and Y is an isocyanate group, or X is an isocyanate group and Y is a hydroxyl group or a primary or secondary amino group. In a second step, the polymers P1 obtained in the first step are mixed with a silane condensation catalyst (B) selected from the group consisting of compounds of elements of the third main group and/or fourth secondary group and heterocyclic organic amines, amine complexes of the element compounds, or the mixtures thereof. Optionally, said mixture is mixed with other substances (C). The formulations do not contain organic tin compounds, and are suitable for using as adhesives, sealants, or coating agents.
摘要翻译：本发明涉及一种生产可交联制剂的方法。在该方法的第一步中，使用式（2）的有机官能硅烷将至少一种式（1）XAX（1）的α，ω-双官能有机聚合物转化为有机甲硅烷基封端的聚合物P1，Y-R-Si- （R1）m（-OR2）3m（2），在选自钾，铁，铟，锌，铋和铜化合物的催化剂（A）的存在下。在所述式中，R是二价任选取代的烃基，其包含1至12个碳原子并且可被杂原子间隔，R 1和R 2是相同或不同的，包含1至12个碳的单价，任选取代的烃基原子并且可以被杂原子中断，A是二价的，任选取代的烃基，其包含至少6个碳原子并且可以被杂原子间隔，m等于0,1或2，X是羟基，Y是异氰酸酯基团，或X为异氰酸酯基团，Y为羟基或伯或仲氨基。在第二步骤中，将第一步中获得的聚合物P1与选自第三主族和/或第四仲
子的元素化合物和杂环有机胺的硅烷缩合催化剂（B），胺络合物的元素化合物，或其混合物。任选地，将所述混合物与其它物质（C）混合。配方不含有机锡化合物，适用于粘合剂，密封剂或涂层剂。

7. 发明授权

US06726798B2 Polystyrene binders 失效
标题翻译：聚苯乙烯粘合剂
公开(公告)号：US06726798B2
公开(公告)日：2004-04-27
申请号：US09011614
申请日：1998-02-11
申请人： Kai Boege , Michael Dziallas , Klaus Helpenstein , Wolfgang Klauck , Johann Klein , Helmut Loth , Hartmut Urbath , Udo Windhoevel
发明人： Kai Boege , Michael Dziallas , Klaus Helpenstein , Wolfgang Klauck , Johann Klein , Helmut Loth , Hartmut Urbath , Udo Windhoevel
IPC分类号： C09J10900
CPC分类号： C09D125/06 , C08K5/10 , C08L2666/26 , C08L2666/34 , C09J125/06 , C09K3/10 , C09K2200/0441 , C09K2200/0447 , C09K2200/0632 , C08L93/04
摘要： The invention relates to polystyrene binders modified by fatty compounds. The fatty compounds used are, in particular, esters of fatty acids or fatty alcohols, more especially triglycerides of higher fatty acids, preferably natural fats and oils. They may be added to the binder in high concentrations without adversely affecting the properties of the binder. However, their addition is of advantage in regard to the wetting properties, resistance to water and, above all, hardness. Dispersion adhesives, hotmelt adhesives and sealing compounds in particular can be improved with the binders according to the invention.
摘要翻译：本发明涉及通过脂肪族化合物改性的聚苯乙烯粘结剂。所使用的脂肪族化合物尤其是脂肪酸或脂肪醇的酯，更特别是高级脂肪酸的甘油三酸酯，优选天然的脂肪和油。它们可以以高浓度加入到粘合剂中，而不会不利地影响粘合剂的性能。然而，它们的添加在润湿性能，耐水性以及尤其是硬度方面是有利的。分散粘合剂，热熔粘合剂和密封化合物尤其可以通过根据本发明的粘合剂改进。

8. 发明授权

US08802785B2 Process for preparing AB diblock copolymers with a bimodally distributed A block 有权
标题翻译：制备具有双峰分布的A嵌段的AB二嵌段共聚物的方法
公开(公告)号：US08802785B2
公开(公告)日：2014-08-12
申请号：US13125177
申请日：2009-10-06
申请人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
发明人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
IPC分类号： C08F293/00 , C09D153/00 , C09J153/00
CPC分类号： C09K3/10 , C08F293/005 , C08F2438/01 , C09J153/00 , C09K2200/0625
摘要： The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad bimodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.
摘要翻译：本发明涉及一种用于制备具有窄单峰分子量分布的B嵌段的基于（甲基）丙烯酸酯的AB二嵌段共聚物的受控聚合方法和具有宽双峰分子量分布的A嵌段及其用途，例如作为粘合剂或密封剂中的粘合剂。

9. 发明授权

US08642669B2 Foamable low-viscosity mixtures 有权
标题翻译：可发泡的低粘度混合物
公开(公告)号：US08642669B2
公开(公告)日：2014-02-04
申请号：US13010344
申请日：2011-01-20
申请人： Wilfried Huebner , Milan Sebestian , Christiane Kunze , Lars Zander , Johann Klein
发明人： Wilfried Huebner , Milan Sebestian , Christiane Kunze , Lars Zander , Johann Klein
IPC分类号： C08G77/04
CPC分类号： C08J9/143 , C08G18/10 , C08G18/163 , C08G18/289 , C08G18/4216 , C08G18/4845 , C08G18/809 , C08G2101/00 , C08G2190/00 , C08J9/141 , C08J9/142 , C08J2207/04 , C08J2375/04 , C08G18/48 , C08G18/32 , C08G18/66
摘要： The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.
摘要翻译：本发明涉及一种可发泡混合物，其含有至少一个烷氧基硅烷封端的预聚物，其可由以下物质制备：a）至少一种烷氧基硅烷，其被异氰酸酯基团官能化，并且可由至少一种羟基官能和/或氨基官能的烷氧基硅烷制备，至少一种二异氰酸酯或多异氰酸酯，和b）至少一种含有至少一个OH基团的化合物和至少一种发泡剂，其特征在于可发泡混合物的动态粘度为100至25,000mPas，优选为500至10,000mPas ，在23℃。本发明还涉及一种生产所述可发泡混合物的方法。根据本发明的可发泡混合物适用于密封，绝缘和安装接头，屋顶表面，窗户和门，或用于填充中空空间。

10. 发明申请

US20100331480A1 HARDENABLE COMPOSITIONS CONTAINING SOFT-ELASTIC SILYLATED POLYURETHANES 审中-公开
标题翻译：包含软 - 弹性硅烷基聚氨酯的复合组合物
公开(公告)号：US20100331480A1
公开(公告)日：2010-12-30
申请号：US12832356
申请日：2010-07-08
申请人： Noelle Wrubbel , Helene Boudet , Andrea Krlejova , Andreas Bolte , Lars Zander , Johann Klein , Christiane Kunze
发明人： Noelle Wrubbel , Helene Boudet , Andrea Krlejova , Andreas Bolte , Lars Zander , Johann Klein , Christiane Kunze
IPC分类号： C08L75/04 , C08G71/04
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/4879 , C08G18/718 , C08G65/30 , C08G65/33351 , C08G65/336 , C08G65/337 , C08G2190/00
摘要： Silyated polyurethanes can be manufactured by (A) converting (i) at least one polyol compound A with a molecular weight of 500-20,000 Dalton, in particular 4000-10,000 Dalton, (ii) with a dihalogenide to a polyol compound B with a molecular weight of 4000-40,000 Dalton, in particular 8000-20,000 Dalton, and subsequent (B) conversion of this polyol B with one or more isocyanatosilanes of formula (1): OCN—R—Si—(R1)m(-OR2)3-m where m is 0.1 or 2, each R2 is an alkyl radical with 1 to 4 carbon atoms, each R1 is an alkyl radical with 1 to 4 carbon atoms and R is a difunctional organic pump. These silylated polyurethanes are suited to use as adhesives, sealant or coating agent in preparations containing one or more such silylated polyurethane.
摘要翻译：可以通过（A）将（i）至少一种分子量为500-20,000道尔顿，特别是4000-10,000道尔顿的多元醇化合物A，（ii）与二卤化物转化成多元醇化合物B的分子式重量为4000-40,000道尔顿，特别是8000-20,000道尔顿，随后（B）将该多元醇B与一种或多种式（1）的异氰酸基硅烷转化：OCN-R-Si-（R1）m（-OR2）3 -m其中m为0.1或2，每个R 2为具有1至4个碳原子的烷基，每个R 1为具有1至4个碳原子的烷基，R为双官能有机泵。这些甲硅烷基化聚氨酯适于在含有一种或多种这种甲硅烷基化聚氨酯的制剂中用作粘合剂，密封剂或包衣剂。

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