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1. 发明授权

US06953822B2 Aqueous (meth)acrylate copolymer dispersions, method for producing the same, and the use thereof 有权
标题翻译：（甲基）丙烯酸水溶液共聚物分散体，其制备方法及其用途
公开(公告)号：US06953822B2
公开(公告)日：2005-10-11
申请号：US10220823
申请日：2001-03-01
申请人： Wilma Löcken , Heinz-Peter Rink , Ursula Heimeier
发明人： Wilma Löcken , Heinz-Peter Rink , Ursula Heimeier
IPC分类号： C09K3/10 , C08F2/12 , C08F265/06 , C09D5/00 , C09D151/00 , C09J151/00 , C08F2/16
CPC分类号： C08F265/06 , C09D151/003 , C09J151/003
摘要： Aqueous (meth)acrylate copolymer dispersions preparable by (I) subjecting at least one monomer (a) containing at least one hydrophilic functional group which brings about the water-solubility or water-dispersibility of the (meth)acrylate copolymer to (co)polymerization in aqueous/organic solution using at least one oil-soluble initiator which provides free radicals, (II) where appropriate, fully or partly neutralizing the resulting (co)polymer I, (III) dispersing the resultant solution of the (co)polymer I, (partly) neutralized where appropriate, in water, and (IV) copolymerizing and/or graft-copolymerizing at least one monomer (b) in the presence of the resultant dispersion III using oil-soluble initiators which provide free radicals, the monomer or monomers (b) containing at least one hydrophilic functional group which brings about no substantial water-solubility or water-dispersibility of the (meth)acrylate copolymer, or at least one hydrophobic group, and being selected in nature and amount such that the resulting (meth)acrylate copolymer is soluble or dispersible in water.
摘要翻译：（I）的（甲基）丙烯酸酯共聚物分散体可以通过（I）使含至少一种含有（甲基）丙烯酸酯共聚物的水溶性或水分散性的亲水性官能团的单体（a）使用至少一种提供自由基的油溶性引发剂，（II）在适当时完全或部分中和得到的（共）聚合物I，（III），将所得（共）聚合物I 在适当时（部分）在水中中和，（Ⅳ）在得到的分散体III的存在下，使用提供自由基的油溶性引发剂共聚和/或接枝共聚至少一种单体（b），该单体或含有至少一个亲水官能团的单体（b），其不会导致（甲基）丙烯酸酯共聚物或至少一个疏水基团的实质上的水溶性或水分散性，并且在本质上选择所得到的（甲基）丙烯酸酯共聚物可溶于水或分散于水中。

2. 发明授权

US07129288B2 Polyurethanes containing sulphide groups, polymeric mixtures based thereon, production and use thereof 有权
标题翻译：含硫化物基团的聚氨酯，其上的聚合物混合物，其生产和用途
公开(公告)号：US07129288B2
公开(公告)日：2006-10-31
申请号：US10398132
申请日：2001-10-30
申请人： Wilma Löcken , Heinz-Peter Rink , Thomas Krüger , Stefan Schwarte , Hans-Ulrich Moritz , Hartmut Kagerer
发明人： Wilma Löcken , Heinz-Peter Rink , Thomas Krüger , Stefan Schwarte , Hans-Ulrich Moritz , Hartmut Kagerer
IPC分类号： C08L75/04 , C08L75/12 , C09D175/04 , C09D175/12 , C09J175/04
CPC分类号： C09D175/04 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/6659 , C08G18/765 , C08G2170/80 , Y10S528/905 , C08G18/3868
摘要： Novel polyurethanes containing sulfide groups which comprise at least one group of the general formula I in the polymer main chain and/or at least one group of the general formula II incorporated at the chain end: —X—A—S—B—Y— (I) —X—A—S—B—YH (II) in which the variables have the following definitions: S is the sulfur atom; X and Y independently of one another are oxygen atoms, sulfur atoms or groups —NZ where Z is the hydrogen atom or an alkyl radical of 1 to 10 carbon atoms; and A and B independently of one another are divalent organic radicals; novel polymer mixtures based thereon, and the use of the novel polyurethanes and polymer mixtures and dispersions thereof for the preparation of coating materials, adhesives and sealing compounds.
摘要翻译：在聚合物主链中包含至少一个通式I的基团的新型聚氨酯和/或在链末端结合的至少一个通式II的基团：<？in-line-formula description =“In - “公式”end =“lead”？> - XASBY-（I）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In - “公式”end =“lead”？> - XASB-YH（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中变量具有以下定义：S 是硫原子; X和Y彼此独立地是氧原子，硫原子或基团-NZ，其中Z是氢原子或1-10个碳原子的烷基; A和B彼此独立地是二价有机基团; 基于其的新型聚合物混合物，以及新型聚氨酯及其聚合物混合物及其分散体用于制备涂料，粘合剂和密封化合物的用途。

3. 发明授权

US07479520B2 Aqueous coating substance that is substantially or completely free of volatile organic substances, method for producing the same and the use thereof 有权
标题翻译：基本上或完全不含挥发性有机物质的水性涂料，其制造方法及其用途
公开(公告)号：US07479520B2
公开(公告)日：2009-01-20
申请号：US10250694
申请日：2002-02-13
申请人： Ralf Nickolaus , Heinz-Peter Rink , Reinhold Clauss , Elisabeth Wessling , Wilma Löcken , Maximilian Bendix , Dunja Mikolajetz
发明人： Ralf Nickolaus , Heinz-Peter Rink , Reinhold Clauss , Elisabeth Wessling , Wilma Löcken , Maximilian Bendix , Dunja Mikolajetz
IPC分类号： C08F3/00
CPC分类号： C09D151/00 , C08F291/00 , C08G18/0823 , C08G18/6659 , C08G18/807 , C09D175/04 , C08F2/22 , C08L2666/14 , C08L75/04
摘要： An aqueous coating material, substantially or completely free from volatile organic compounds and preparable by mixing with one another (A) at least one aqueous primary dispersion comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a diameter ≦500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive, and (B) at least one secondary aqueous polyurethane dispersion comprising at least one polyurethane and at least one light stabilizer selected from the group of the regenerable free-radical scavengers, a process for preparing it and its use.
摘要翻译：基本上或完全不含挥发性有机化合物并可通过彼此混合制备的水性涂料（A）至少一种包含分散和/或乳化的固体和/或液体聚合物颗粒和/或分散的固体核/ 在至少一种疏水性添加剂的存在下，通过自由基微乳液或至少一种烯属不饱和单体的细乳液聚合制备直径<= 500nm的壳颗粒，和（B）至少一种至少一种第二水性聚氨酯分散体，至少包含一种聚氨酯和至少一种选自可再生自由基清除剂的光稳定剂，其制备方法及其用途。

4. 发明授权

US06534588B1 Coating agent comprised of at least three constituents, method for the production thereof, and its use 失效
标题翻译：由至少三种组分组成的涂层剂，其制备方法及其用途
公开(公告)号：US06534588B1
公开(公告)日：2003-03-18
申请号：US09856951
申请日：2001-06-22
申请人： Wilma Löcken , Heinz-Peter Rink
发明人： Wilma Löcken , Heinz-Peter Rink
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/3206 , C08G18/4063 , C08G18/6254 , C08G18/6659
摘要： A coating composition consisting of at least three components, comprising a component (I) comprising at least one oligomeric or polymeric resin containing functional groups which react with isocyanate groups, as binder (A), a component (II) comprising at least one polyisocyanate as crosslinking agent (F), and a component (III) which consists of water or comprises water and at least one binder (A), wherein component (I) and/or (III) comprise or comprises at least one branched, cyclic and/or acyclic C9-C16-alkane which is functionalized using at least two hydroxyl groups.
摘要翻译：由至少三种组分组成的涂料组合物，其包含至少一种包含与异氰酸酯基团反应的官能团的低聚物或聚合树脂作为粘合剂（A）的组分（I），包含至少一种多异氰酸酯的组分（II）交联剂（F）和由水组成或包含水和至少一种粘合剂（A）的组分（III），其中组分（I）和/或（III）包含或包含至少一个支链，环状和/ 或使用至少两个羟基官能化的无环C 9 -C 16烷烃。

5. 发明授权

US07157526B2 Aqueous primary dispersion, substantially or completely devoid of volatile organic substances, method for the production thereof and use of the same 失效
标题翻译：水性初级分散体，基本上或完全没有挥发性有机物质，其制备方法和用途
公开(公告)号：US07157526B2
公开(公告)日：2007-01-02
申请号：US10250586
申请日：2002-02-13
申请人： Ralf Nickolaus , Heinz-Peter Rink , Reinhold Clauss , Elisabeth Wessling , Wilma Löcken , Nicole Freitag , Dunja Mikolajetz
发明人： Ralf Nickolaus , Heinz-Peter Rink , Reinhold Clauss , Elisabeth Wessling , Wilma Löcken , Nicole Freitag , Dunja Mikolajetz
IPC分类号： C08F283/02
CPC分类号： C09D151/08 , C08F2/22 , C08F283/02 , C09J151/08
摘要： Aqueous primary dispersion, substantially or entirely free of volatile organic compounds, and comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a particle diameter≦500 nm, preparable by free-radical micro- or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive and of at least one oligomeric polyester with a number-average molecular weight of from 150 to 1 500 daltons, a hydroxyl number of from 100 to 1 000 mg KOH/g, and an acid number
摘要翻译：基本上或完全不含挥发性有机化合物的水性初级分散体，并且包含粒径<= 500nm的分散和/或乳化的固体和/或液体聚合物颗粒和/或分散的固体核/壳颗粒，至少一种烯属不饱和单体在至少一种疏水性添加剂和至少一种数均分子量为150至1500道尔顿的低聚聚酯存在下的基团微乳液或微乳液聚合，羟基数为100 至1000mg KOH / g，酸值<20mg KOH / g，以及其制备方法及其作为涂料，粘合剂或密封剂的用途或制备涂料，粘合剂或密封剂。

6. 发明授权

US07151130B2 Polyurethane-modified copolymers, method for their production and the use thereof 失效
标题翻译：聚氨酯改性共聚物，其制备方法及其应用
公开(公告)号：US07151130B2
公开(公告)日：2006-12-19
申请号：US10468448
申请日：2002-03-08
申请人： Wolfgang Bremser , Thomas Krüger , Wilma Löcken , Stephan Schwarte , Heinz-Peter Rink
发明人： Wolfgang Bremser , Thomas Krüger , Wilma Löcken , Stephan Schwarte , Heinz-Peter Rink
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08F8/30 , C08F283/04
CPC分类号： C08G18/12 , C08F283/006 , C08G18/0823 , C08G18/4288 , C08G18/6659 , C08G18/765 , C09D175/04 , C08G18/62 , C08L33/00
摘要： Polyurethane-modified addition copolymers preparable by free-radically (co)polymerizing an olefinically unsaturated monomer (a) in an aqueous or nonaqueous medium comprising at least one reaction product (A/B) of(A) at least one addition copolymer containing on average per molecule at least 0.1 isocyanate-reactive functional groups and preparable by free-radical copolymerization of at least a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a1) and of the general formula I R1R2C═CR3R4 (I) in which the radicals R1, R2, R3, and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3, and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium or nonaqueous medium; and (B) at least one polyisocyanate; processes for preparing them, and their use.
摘要翻译：聚氨酯改性的加成共聚物可以通过在包含至少一种平均包含的至少一种加成共聚物的（A）的至少一种反应产物（A / B）的水性或非水性介质中自由基（共）聚合烯属不饱和单体（a）每分子至少0.1个异氰酸酯反应性官能团，并且可通过至少一种烯属不饱和单体的自由基共聚制备，和b）至少一种不同于烯属不饱和单体（a1）的烯属不饱和单体和一般的公式I <？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 2＆gt; 2＆lt; C-CR 3＆（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中基团R 1， R 2，R 3和R 4各自彼此独立地是氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基，条件是至少两个变量R 1，R 2，R 3，和 R 4是取代或未取代的芳基，芳基烷基或芳基环烷基，特别是取代或未取代的芳基; 在水性介质或非水介质中; 和（B）至少一种多异氰酸酯; 制备它们的过程及其用途。

7. 发明授权

US06649688B1 Coating composition comprising at least three components, it preparation and use 失效
标题翻译：包含至少三种组分的涂料组合物，其制备和使用
公开(公告)号：US06649688B1
公开(公告)日：2003-11-18
申请号：US09856950
申请日：2001-06-22
申请人： Bernd Mayer , Heinz-Peter Rink , Egbert Nienhaus , Wilma Löcken
发明人： Bernd Mayer , Heinz-Peter Rink , Egbert Nienhaus , Wilma Löcken
IPC分类号： C08F1604
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/4063 , C08G18/6254 , C08G18/6659 , C08G18/765 , C08G18/3206
摘要： A coating composition consisting of at least three components, comprising a component (I) comprising at least one hydroxyl-containing oligomeric or polymeric resin dispersed or dissolved in one or more organic, optionally water dilutable solvents, as binder (A), a component (II) comprising at least one polyisocyanate dispersed or dissolved in one or more organic, optionally water dilutable solvents, as crosslinking agent (F), and a component (III) which comprises water, wherein component (I) comprises at least one hydroxyl-containing polyacrylate resin (A) containing polyether sidegroups and/or endgroups of the general formula I Y—(—O—R—)n— (I) in which the index and variables have the following meanings: n=3 to 100; R=C2 to C6 alkanediyl and C3 to C8 cycloalkanediyl; Y=hydrogen atom or C1 to C4 alkyl; as binder (A).
摘要翻译：由至少三种组分组成的涂料组合物，其包含分散或溶解在一种或多种有机，任选的水可稀释溶剂中的至少一种含羟基的低聚物或聚合物树脂作为粘合剂（A），组分（ II）包含分散或溶解在一种或多种有机，任选水可稀释溶剂中的至少一种多异氰酸酯作为交联剂（F）和包含水的组分（III），其中组分（I）包含至少一个含羟基的含有聚醚侧基和/或通式Iin的端基的聚丙烯酸酯树脂（A），其指数和变量具有以下含义：n = 3〜100; R = C2〜C6烷二基和C3〜C8环烷二基; Y =氢原子或 C1〜C4烷基;作为粘合剂（A）。

8. 发明授权

US07001975B2 Polyurethane and polyurethane-based mixed graft polymers and their use for producing coating materials, adhesives and sealing compounds 失效
标题翻译：聚氨酯和聚氨酯基混合接枝聚合物及其用于生产涂料，粘合剂和密封剂的用途
公开(公告)号：US07001975B2
公开(公告)日：2006-02-21
申请号：US10486232
申请日：2002-09-12
申请人： Wolfgang Bremser , Thomas Krüger , Wilma Löcken , Peter-Heinz Rink , Stephan Schwarte
发明人： Wolfgang Bremser , Thomas Krüger , Wilma Löcken , Peter-Heinz Rink , Stephan Schwarte
IPC分类号： C08G18/10
CPC分类号： B82Y30/00 , C08F283/006 , C08F290/06 , C08F290/067 , C08G18/0823 , C08G18/12 , C08G18/4283 , C08G18/6659 , C08G2170/80 , C08L51/08 , C08L2666/02 , C09D151/08 , C09D175/04 , C09J151/08 , C08G18/2825
摘要： A hydrophilic or hydrophobic polyurethane containing on average per molecule at least one olefinically unsaturated structural unit selected from the group consisting of pendant, internal, and terminal, acyclic and cyclic terpene units; graft copolymers of the polyurethane with olefinically unsaturated monomers, processes for preparing the polyurethane and the graft copolymers, and their use for preparing coating materials, adhesives, and sealing compounds.
摘要翻译：平均每分子含有至少一种选自侧基，内部和末端，非环状和环状萜烯单元的烯属不饱和结构单元的亲水或疏水性聚氨酯; 聚氨酯与烯属不饱和单体的接枝共聚物，制备聚氨酯和接枝共聚物的方法，及其用于制备涂料，粘合剂和密封化合物的用途。

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