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1. 发明授权

US06677261B1 Alumina-bound high strength ceramic honeycombs 有权
标题翻译：氧化铝结合的高强度陶瓷蜂窝
公开(公告)号：US06677261B1
公开(公告)日：2004-01-13
申请号：US10210674
申请日：2002-07-31
申请人： William P. Addiego , Cecilia S. Magee
发明人： William P. Addiego , Cecilia S. Magee
IPC分类号： C04B3510
CPC分类号： C04B35/6365 , C04B35/111 , C04B35/6303 , C04B38/0006 , C04B2235/3217 , C04B2235/322 , C04B2235/5436 , C04B35/01 , C04B2103/0067
摘要： Strong, high-surface-area honeycombs of alumina or other ceramic composition are provided by compounding and shaping a moldable ceramic powder extrusion batches including a cellulosic temporary binder and a high-surface-area boehmite precursor for a permanent binder, hydrating the shaped honeycomb to develop a boehmite binding phase, and calcining the hydrated body to develop the binder and provide a ceramic honeycomb of high strength and porosity.
摘要翻译：通过将包括纤维素临时粘合剂和高表面积勃姆石前体的可模塑陶瓷粉末挤出批料混合并成型为永久性粘合剂，将成形蜂窝体保湿至水合，形成强氧化铝或其它陶瓷组合物的高表面积蜂窝开发勃姆石结合相，并煅烧水合体以开发粘合剂并提供高强度和多孔性的陶瓷蜂窝体。

2. 发明授权

US6109095A Metal oxide semiconductor catalyst hydrocarbon sensor 失效
标题翻译：金属氧化物半导体催化剂烃传感器
公开(公告)号：US6109095A
公开(公告)日：2000-08-29
申请号：US985123
申请日：1997-12-04
申请人： William P. Addiego
发明人： William P. Addiego
IPC分类号： G01N31/00 , G01N27/12 , G01N33/00 , G01N7/00
CPC分类号： G01N27/12 , G01N33/0047 , F01N2550/02
摘要： A sensor for selectively detecting HC classes, e.g., alkanes, alkenes and aromatics, in a gas mixture comprising a metal oxide seiniconductor catalyst which is catalytically active for the selective HC classes; the reactions selected from the group consisting of partial oxidation, oxidative dehydrogenation, oxidative coupling and isomerization. Each of these reactions results in imparting a change in the electrical conductivity of the metal oxide which is proportional to the concentration of the HC in the gas mixture. Suitable metal oxide catalysts include Bi.sub.2 O.sub.3 --MoO.sub.3, CoO--MoO.sub.3, SnO.sub.2 --MoO.sub.3, TeO.sub.2 --MoO.sub.3, Sb.sub.2 O.sub.5 --V.sub.2 O.sub.5 --MoO.sub.3, SnO.sub.2 --Sb.sub.2 O.sub.5, Nb.sub.2 O--V.sub.2 O.sub.5 --MoO.sub.3, V.sub.2 O.sub.5 --MoO.sub.3, ZnO--Fe.sub.2 O.sub.3, Li.sub.2 O--MgO, V.sub.2 O.sub.5 --P.sub.2 O.sub.5, metal oxide compounds of a spinel or perovskite crystalline structure, and mixtures thereof. A method carried out by the sensor comprises the following steps: (1) contacting the gas mixture with a metal oxide semiconductor catalyst capable of initiating chemisorption and/or at least one catalytic reaction of a selected hydrocarbon class; and, thereafter measuring the resultant change in the electrical conductivity of the metal oxide and thereafter converting the change to the concentration of the total non-methane hydrocarbons in the gas mixture.
摘要翻译：用于选择性地检测HC级别的传感器，例如烷烃，烯烃和芳族化合物，其包含对于选择性HC级别具有催化活性的金属氧化物半导体催化剂; 反应选自部分氧化，氧化脱氢，氧化偶联和异构化。这些反应中的每一个导致金属氧化物的电导率的变化，其与气体混合物中的HC的浓度成比例。合适的金属氧化物催化剂包括Bi2O3-MoO3，CoO-MoO3，SnO2-MoO3，TeO2-MoO3，Sb2O5-V2O5-MoO3，SnO2-Sb2O5，Nb2O-V2O5-MoO3，V2O5-MoO3，ZnO-Fe2O3，Li2O-MgO，V2O5 -P 2 O 5，尖晶石或钙钛矿晶体结构的金属氧化物化合物及其混合物。由传感器执行的方法包括以下步骤：（1）使气体混合物与能够引发选择的烃类化学吸附和/或至少一种催化反应的金属氧化物半导体催化剂接触; 然后测量所得金属氧化物的电导率的变化，然后将该变化转化为气体混合物中的总非甲烷烃的总浓度。

3. 发明授权

US07244689B2 Method of producing alumina-silica catalyst supports 有权
标题翻译：生产氧化铝 - 二氧化硅催化剂载体的方法
公开(公告)号：US07244689B2
公开(公告)日：2007-07-17
申请号：US10715602
申请日：2003-11-17
申请人： William P. Addiego , Kevin R. Brundage , Christopher R. Glose
发明人： William P. Addiego , Kevin R. Brundage , Christopher R. Glose
IPC分类号： B01J23/02 , B01J20/00 , B01J21/00
CPC分类号： B01J37/0018 , B01J21/12 , B01J35/002 , B01J35/04 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0045
摘要： Alumina-silica catalyst supports having substantially high surfaces areas are formed by extrusion, drying and firing of a plasticized batch including an alumina-silica powder component, acid, organic binder and water. The alumina-silica powder component can be formed either by the mixing of alumina- and silica-source powders or by forming a slurry therefrom which is spray dried to form a particulate material prior to batching.
摘要翻译：具有基本上高的表面积的氧化铝 - 二氧化硅催化剂载体通过包括氧化铝 - 二氧化硅粉末组分，酸，有机粘合剂和水的塑化批料的挤出，干燥和焙烧而形成。氧化铝 - 二氧化硅粉末组分可以通过混合氧化铝和二氧化硅源粉末或通过形成其中的浆料来形成，其在批量化之前被喷雾干燥以形成颗粒材料。

4. 发明申请

US20120047952A1 CREEP-RESISTANT ZIRCON ARTICLE AND METHOD OF MANUFACTURING SAME 有权
标题翻译：抗蠕虫ZIRCON制品及其制造方法
公开(公告)号：US20120047952A1
公开(公告)日：2012-03-01
申请号：US13206005
申请日：2011-08-09
申请人： William P. Addiego , Michael J. Bennett
发明人： William P. Addiego , Michael J. Bennett
IPC分类号： C03B17/06 , C03B13/00 , B05D7/24 , C04B35/488 , C04B35/49
CPC分类号： C03B17/064 , C04B35/481 , C04B2235/3232 , C04B2235/5436 , C04B2235/5472 , C04B2235/656 , C04B2235/6565 , C04B2235/6567 , C04B2235/77 , C04B2235/783 , C04B2235/786 , C04B2235/96
摘要： A creep-resistant zircon article and a method of manufacturing the creep-resistant zircon article are described herein. In one example, the creep-resistant zircon article has the shape of a forming apparatus (e.g., isopipe) which is used in the fusion process to manufacture glass sheets.
摘要翻译：本文描述了抗蠕变锆石制品和制造抗蠕变锆石制品的方法。在一个实例中，抗蠕变锆石制品具有用于制造玻璃板的熔合过程中使用的成形装置（例如，等压槽）的形状。

5. 发明授权

US06461995B1 Extruded honeycomb dehydrogenation catalyst and method 失效
标题翻译：挤压蜂窝状脱氢催化剂及方法
公开(公告)号：US06461995B1
公开(公告)日：2002-10-08
申请号：US09566544
申请日：2000-05-08
申请人： William P. Addiego , Wei Liu
发明人： William P. Addiego , Wei Liu
IPC分类号： B01J2300
CPC分类号： B01J37/0009 , B01J23/78 , B01J23/8872 , B01J35/04 , C07C5/3332 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/745 , C07C2523/78 , Y10T428/24149 , C07C15/46
摘要： Extruded honeycomb dehydrogenation catalysts of high structural integrity, composed of potassium oxide (carbonate)-promoted oxide-stabilized iron oxides and having a honeycomb cell density in the range of 15-400 channels per square inch, a channel wall thickness in the range of 0.2-3 mm, and an axial crushing strength in excess of 100 psi, are prepared from extrusion batches incorporating polymer binders exhibiting improved compatibility with high batch concentrations of dissolved catalyst precursors or constituents.
摘要翻译：具有高度结构完整性的挤压蜂窝状脱氢催化剂，由氧化钾（碳酸盐） - 氧化物稳定的氧化铁组成，蜂窝状电池密度在15-400通道/平方英寸的范围内，通道壁厚在0.2 -3mm，并且轴向破碎强度超过100psi，由挤出批料制备，其包含与高批次浓度的溶解的催化剂前体或组分具有改善的相容性的聚合物粘合剂。

6. 发明授权

US6004896A Hydrocarbon adsorbers, method of making and use therefor 失效
标题翻译：烃吸附剂，其制备和使用方法
公开(公告)号：US6004896A
公开(公告)日：1999-12-21
申请号：US72661
申请日：1998-05-04
申请人： William P. Addiego
发明人： William P. Addiego
IPC分类号： B01D53/04 , B01D53/94 , B01J20/18 , B01J20/32 , B01J29/06
CPC分类号： B01D53/02 , B01D53/944 , B01J20/186 , B01J20/2803 , B01J20/28045 , B01J20/3007 , B01J20/3042 , B01J20/3078 , B01J20/3085 , B01J20/3204 , B01J20/3238 , B01J20/3408 , B01J20/3458 , B01J20/3483 , B01D2253/108 , B01D2253/308 , B01D2253/311 , B01D2253/3425 , B01D2256/24 , B01D2257/702 , B01D2258/01
摘要： A method for improving the adsorption properties of a hydrocarbon adsorber involves contacting a molecular sieve hydrocarbon adsorber at ambient temperature with an agent for modifying the acid sites of the molecular sieve to impregnate the molecular sieve with the agent. The average pore diameter of the intracrystalline porosity of the molecular sieve is about 3 to 20 angstroms. The agent has an anionic portion which is retained within the structure of the molecular sieve. The modified molecular sieve has the ability to retain adsorbed hydrocarbons at higher temperatures than the unmodified molecular sieve. The acid-modified molecular sieve can be used to remove hydrocarbons from a hydrocarbon-containing stream. The hydrocarbon-containing stream is passed through the modified adsorber at atmospheric pressure at a temperature ranging from room temperature to about 150.degree. C. to cause adsorption and retention of the hydrocarbons. The adsorbed hydrocarbons can then be desorbed at a higher temperature than would otherwise occur with an unmodified adsorber.
摘要翻译：提高烃吸附剂的吸附性质的方法包括使环境温度下的分子筛烃吸附器与用于改变分子筛的酸性位点的试剂接触以使试剂浸渍分子筛。分子筛的结晶孔隙度的平均孔径约为3至20埃。该试剂具有保留在分子筛结构内的阴离子部分。改性分子筛具有在比未改性分子筛更高的温度下保留吸附的烃的能力。酸改性分子筛可用于从含烃流中除去烃。含烃流在大气压下在室温至约150℃的温度下通过改性吸附器，引起烃的吸附和保留。吸附的碳氢化合物可以在比未改性的吸附器发生的温度更高的温度下解吸。

7. 发明授权

US5260241A Controlled pore size phosphate-alumina material and method for producing same 失效
标题翻译：受控孔径磷酸盐 - 氧化铝材料及其制造方法
公开(公告)号：US5260241A
公开(公告)日：1993-11-09
申请号：US928337
申请日：1992-08-12
申请人： William P. Addiego , Irwin M. Lachman , Mallanagouda D. Patil , Jimmie L. Williams
发明人： William P. Addiego , Irwin M. Lachman , Mallanagouda D. Patil , Jimmie L. Williams
IPC分类号： B01D53/94 , B01D53/86 , B01J23/40 , B01J27/16 , B01J27/185 , B01J29/83 , B01J35/10 , B01J37/02 , C01B25/37 , B01J21/04 , B01J27/18
CPC分类号： B01J27/16 , B01J23/40 , B01J35/1014 , B01J35/1061
摘要： A phosphate-Al.sub.2 O.sub.3 material is disclosed wherein the phosphate is homogeneously dispersed throughout, the specific surface area as measured by N.sub.2 BET method is at least about 50 m.sup.2 /g, and the average pore radius is no greater than about 200.ANG.. A method is disclosed for producing the material which comprises forming a precursor material by wet-mixing a phosphate yielding species and an aluminum oxide yielding species which can be aluminum oxide, aluminum hydroxylated oxides, aluminum hydroxide, aluminum alkoxides, and combinations thereof, in amounts sufficient to result in an AlPO.sub.4 content of about 3 to 12 percent by weight in the phosphate-Al.sub.2 O.sub.3, drying and heat-treating the precursor material at a temperature and for a time sufficient to form the phosphate- Al.sub.2 O.sub.3. The material is used as a support for catalyst metals.

8. 发明申请

US20080152577A1 Ordered mesoporous carbons and method for manufacturing same 审中-公开
标题翻译：有序介孔碳及其制造方法
公开(公告)号：US20080152577A1
公开(公告)日：2008-06-26
申请号：US11899002
申请日：2007-08-31
申请人： William P. Addiego , Adra S. Baca , Steven B. Dawes , Wageesha Senaratne
发明人： William P. Addiego , Adra S. Baca , Steven B. Dawes , Wageesha Senaratne
IPC分类号： C01B31/08
CPC分类号： C01B32/00 , C01B32/30 , C01B32/336
摘要： The present invention relates to an ordered mesoporous carbon and method for manufacturing the ordered mesoporous carbon which is made from a surfactant, a carbon precursor, water (possibly mixed with an acid) and a water immiscible oil. In addition, the present invention relates to a method of formulating a composition which is used to manufacture the ordered mesoporous carbon. Moreover, the present invention relates to an activated carbon which is made by partially oxidizing an ordered mesoporous carbon.
摘要翻译：本发明涉及有序介孔碳及由表面活性剂，碳前体，水（可能与酸混合）和水不混溶油制成的有序中孔碳的方法。此外，本发明涉及一种配制用于制造有序介孔碳的组合物的方法。此外，本发明涉及通过部分氧化有序介孔碳制成的活性炭。

9. 发明授权

US07304013B2 Metal oxide catalysts 有权
标题翻译：金属氧化物催化剂
公开(公告)号：US07304013B2
公开(公告)日：2007-12-04
申请号：US10611508
申请日：2003-06-30
申请人： William P. Addiego , Charles M. Sorensen, Jr.
发明人： William P. Addiego , Charles M. Sorensen, Jr.
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J23/745 , B01J37/0009 , B01J37/0221
摘要： Bulk and supported catalysts are prepared from an aqueous slurry containing a catalytically active material and a binder. The slurry is either coated onto a support and dried to form a porous, high surface area phase containing the catalytically active material, or reduced to a paste-like consistency, molded and dried to form a bulk catalyst. The processes and catalysts may be employed in various catalytic chemical processes to achieve high effectiveness factor of the catalytically active material while achieving a lower pressure drop.
摘要翻译：由含有催化活性材料和粘合剂的含水浆料制备主体和负载型催化剂。将浆料涂布到载体上并干燥以形成含有催化活性材料的多孔的高表面积相，或者还原成糊状稠度，模塑并干燥以形成本体催化剂。该方法和催化剂可用于各种催化化学方法中以实现催化活性材料的高效率因子，同时实现较低的压降。

10. 发明授权

US06964756B2 Method for treating alumina honeycomb monoliths 失效
标题翻译：氧化铝蜂窝状整料的处理方法
公开(公告)号：US06964756B2
公开(公告)日：2005-11-15
申请号：US10315825
申请日：2002-12-10
申请人： William P. Addiego , Kevin R. Brundage , Christopher R. Glose , Jennifer M. Torns
发明人： William P. Addiego , Kevin R. Brundage , Christopher R. Glose , Jennifer M. Torns
IPC分类号： B01J27/19 , B01J35/04 , B01J37/02 , B01J21/04 , B01J33/00
CPC分类号： B01J27/19 , B01J35/04 , B01J37/0207
摘要： High-surface-area alumina honeycombs are subjected to a water vapor pre-treatment to obtain protection from cracking damage on subsequent exposure to aqueous media e.g., aqueous solutions for depositing catalysts on the honeycombs.
摘要翻译：对高表面积氧化铝蜂窝进行水蒸气预处理，以获得防止随后暴露于水性介质例如用于在蜂窝上沉积催化剂的水溶液的破裂损伤。

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