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1. 发明授权

US07220806B2 Process for increasing ethylene incorporation into random copolymers 有权
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US07220806B2
公开(公告)日：2007-05-22
申请号：US11119243
申请日：2005-04-29
申请人： William John Gauthier , Jun Tian , David John Rauscher , Constance Hayworth Patrick , Shady Nader Henry , Nathan Williams
发明人： William John Gauthier , Jun Tian , David John Rauscher , Constance Hayworth Patrick , Shady Nader Henry , Nathan Williams
IPC分类号： C08F4/76 , C08F4/52
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F4/65927
摘要： A process for preparing low melting copolymers comprising contacting a mixture of olefin monomers with a CpFlu-type metallocene catalyst under reaction conditions sufficient to form a copolymer. The copolymers thus prepared desirably display melt temperatures from about 100° C. to about 140° C. and may be produced with reduced amounts of ethylene. The copolymers may also exhibit reduced levels of undesirable xylene solubles, relatively narrow molecular weight distribution, and other improved optical and physical properties.
摘要翻译：一种制备低熔点共聚物的方法，包括使烯烃单体的混合物与CpFlu型金属茂催化剂在足以形成共聚物的反应条件下接触。如此制备的共聚物理想地显示约100℃至约140℃的熔融温度，并且可以用减少量的乙烯制备。共聚物也可以表现出不希望的二甲苯可溶物的水平降低，分子量分布相对窄，以及其他改进的光学和物理性能。

2. 发明授权

US06855783B2 Supported metallocene catalysts 有权
标题翻译：负载金属茂催化剂
公开(公告)号：US06855783B2
公开(公告)日：2005-02-15
申请号：US10412372
申请日：2003-04-11
申请人： William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
发明人： William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
IPC分类号： B01J31/00 , B01J37/00 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/02 , C08F4/42 , C08F4/44 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/18 , C08F2500/03 , C08F2500/12 , C08F2500/17 , C08F2500/15
摘要： Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C3+ ethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m2/g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). Alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Fl′)MQ2 in which Fl′ is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Fl′, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a Cl-C4 alkyl group.
摘要翻译：负载型金属茂催化剂和在C3 +烯属不饱和单体的全同立构聚合中使用这种催化剂的方法。载体催化剂包括颗粒二氧化硅载体，烷基铝氧烷组分和茂金属催化剂组分。载体的平均粒度为10-50微米，表面积为200-800平方米/克，孔体积为0.9-2.1毫升/克（毫升/克）。将Alumoxane加入到载体上以提供至少0.8:1的铝氧烷与二氧化硅的重量比。金属茂的存在量为二氧化硅和铝氧烷的至少1重量％，并且具有式B（CpRaRb）（F1'）MQ2，其中F1'是未取代的芴基或在该位置上对称取代的芴基 3和6位，B是Cp和Fl'之间的结构桥，Ra是远端位置的大体积取代基，Rb是靠近桥的较不庞大的取代基，而与远端取代基不相邻，M是IVB族过渡金属或钒，Q是卤素或C 1 -C 4烷基。

3. 发明申请

US20120010376A1 Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers 有权
公开(公告)号：US20120010376A1
公开(公告)日：2012-01-12
申请号：US12832237
申请日：2010-07-08
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/76 , C08F4/42
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.

4. 发明申请

US20060247395A1 Process for increasing ethylene incorporation into random copolymers 有权
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US20060247395A1
公开(公告)日：2006-11-02
申请号：US11119243
申请日：2005-04-29
申请人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
发明人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
IPC分类号： C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F4/65927
摘要： A process for preparing low melting copolymers comprising contacting a mixture of olefin monomers with a CpFlu-type metallocene catalyst under reaction conditions sufficient to form a copolymer. The copolymers thus prepared desirably display melt temperatures from about 100° C. to about 140° C. and may be produced with reduced amounts of ethylene. The copolymers may also exhibit reduced levels of undesirable xylene solubles, relatively narrow molecular weight distribution, and other improved optical and physical properties.
摘要翻译：一种制备低熔点共聚物的方法，包括使烯烃单体的混合物与CpFlu型金属茂催化剂在足以形成共聚物的反应条件下接触。如此制备的共聚物理想地显示约100℃至约140℃的熔融温度，并且可以用减少量的乙烯制备。共聚物也可以表现出不希望的二甲苯可溶物的水平降低，分子量分布相对窄，以及其他改进的光学和物理性能。

5. 发明申请

US20140051816A9 MULTI-COMPONENT CATALYST SYSTEMS FOR THE PRODUCTION OF REACTOR BLENDS OF POLYPROPYLENE 审中-公开
标题翻译：用于生产聚丙烯反应混合物的多组分催化剂体系
公开(公告)号：US20140051816A9
公开(公告)日：2014-02-20
申请号：US13476133
申请日：2012-05-21
申请人： Jun Tian , William J. Gauthier , David J. Rauscher , Nathan Williams
发明人： Jun Tian , William J. Gauthier , David J. Rauscher , Nathan Williams
IPC分类号： C08F4/76 , C08F210/06 , C08F110/06
CPC分类号： C08F110/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F4/65904 , C08F2500/03 , C08F2500/12 , C08F2500/18
摘要： Embodiments of the invention generally include multicomponent catalyst systems, polymerization processes and reactor blends formed by the processes. The multicomponent catalyst system generally includes a first catalyst component selected from an isotactic directing metallocene catalyst. The multicomponent catalyst system further includes a second syndiotactic directing metallocene catalyst component.
摘要翻译：本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和反应器共混物。多组分催化剂体系通常包括选自全同立构导向金属茂催化剂的第一催化剂组分。多组分催化剂体系还包括第二间同立构的茂金属催化剂组分。

6. 发明授权

US08461276B2 Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers 有权
标题翻译：多组分催化剂体系和用于形成宽分子量聚合物的聚合方法
公开(公告)号：US08461276B2
公开(公告)日：2013-06-11
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/6592 , C08F4/60 , C08F4/603 , C08F4/606 , C08F4/653
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译：本文描述了丙烯聚合方法，由其形成的聚合物和膜。丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括约2重量％％至约6wt。％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

7. 发明申请

US20060247394A1 Process for increasing ethylene incorporation into random copolymers 审中-公开
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US20060247394A1
公开(公告)日：2006-11-02
申请号：US11117872
申请日：2005-04-29
申请人： William Gauthier , Jun Tian , Shady Henry , Nathan Williams
发明人： William Gauthier , Jun Tian , Shady Henry , Nathan Williams
IPC分类号： C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F2500/03 , C08F2500/20
摘要： Random copolymers may be prepared using a process that includes polymerizing a mixture of monomers including at least propylene and ethylene monomer, in the presence of a catalyst system including a metallocene catalyst having the general structure: racemic-X(2-R1-4-R2-Ind)2MCl2 wherein M is a Group 4, 5 or 6 transition metal, or a lanthanide or actinide series metal; X is a structural bridge imparting stereorigidity; R1 is hydrogen or an alkyl, aryl or a substitution moiety; R2 is hydrogen, or a C1-C4 alkyl; and Ind is an indenyl group. The copolymers are prepared under reaction conditions suitable to form a copolymer, wherein the copolymer has a higher level of ethylene incorporation than a corresponding polymer formed under otherwise identical reaction conditions except that a different bisindeny metallocene catalyst having a 4-indenyl substitution larger than 4 carbons is used. The copolymers may have a lower melt temperature than the corresponding polymers. The resulting copolymers may be used to prepare articles of manufacture including, but not limited to films, fibers and injection molded articles.
摘要翻译：无规共聚物可以使用包括聚合包含至少丙烯和乙烯单体的单体的混合物在内的方法在包括具有以下通式结构的茂金属催化剂的催化剂体系存在下的方法来制备：线式“end =”lead“？>外消旋-X（2-R 1 - 4-R 2 -Ind）2 MCl 其中M是第4,5或6族过渡金属，或镧系元素或锕系元素系列金属 ; X是赋予立体感的结构桥梁; R1是氢或烷基，芳基或取代部分; R 2是氢或C 1 -C 4烷基; 而Ind是茚基。共聚物在适于形成共聚物的反应条件下制备，其中共聚物具有比在其他相同反应条件下形成的相应聚合物更高的乙烯掺入水平，不同之处在于使用具有4-茚基取代基大于4个碳原子的不同的双茚基茂金属催化剂用来。共聚物可以具有比相应聚合物更低的熔融温度。所得共聚物可用于制备制品，包括但不限于薄膜，纤维和注模制品。

8. 发明申请

US20080287619A1 Supported metallocene catalysts 审中-公开
标题翻译：负载金属茂催化剂
公开(公告)号：US20080287619A1
公开(公告)日：2008-11-20
申请号：US11804483
申请日：2007-05-18
申请人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： B01J31/14 , C08F4/46
CPC分类号： C08F210/16 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/06 , C08F4/65916 , C08F2500/15 , C08F2500/12
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m 2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6毫升/克，表面积为200-400平方米/克的粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特殊的茂金属的特征在于以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> B（CpRaRb）（FlR'2 > n （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>或通过公式：<？in-line-formula description =“在线公式 “end =”lead“？> B'（Cp'R'aR'b）（Fl'）M'Q'N'（2）<？in-line-formula description =”In 在式中，Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'是2和7位的取代基，Ra和R'a是桥的远端的取代基，Rb和R'b靠近桥。 M和M'是过渡金属，Q'是卤素或C 1 -C 4 -C 4烷基; 并且n'是0-4的整数。

9. 发明申请

US20120264894A1 Multi-Component Catalyst Systems and Polymerization Processes for Forming Broad Composition Distribution Polymers 有权
标题翻译：多组分催化剂体系和用于形成广泛组分分布聚合物的聚合方法
公开(公告)号：US20120264894A1
公开(公告)日：2012-10-18
申请号：US13525443
申请日：2012-06-18
申请人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
发明人： Tim Coffy , Kenneth Blackmon , Joseph Thorman , David Rauscher , Jun Tian , William Gauthier , Nathan Williams
IPC分类号： C08F4/76 , C08F210/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F2/00 , C08F210/16 , C08F2500/12 , C08F2500/26 , C08F4/65904
摘要： Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
摘要翻译：本文描述了丙烯聚合方法，由其形成的聚合物和膜。丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括约2重量％％至约6wt。％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

10. 发明申请

US20110112262A1 SUPPORTED METALLOCENE CATALYSTS 有权
标题翻译：支持的金属催化剂
公开(公告)号：US20110112262A1
公开(公告)日：2011-05-12
申请号：US12882268
申请日：2010-09-15
申请人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
发明人： William Gauthier , David Rauscher , Jun Tian , Nathan Williams
IPC分类号： C08F4/76 , B01J31/14
CPC分类号： C08F210/06 , B01J31/143 , B01J31/2295 , B01J2231/122 , B01J2531/48 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65916 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
摘要翻译：在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6ml / g，表面积为200-400m2 / g的颗粒状二氧化硅载体上的金属茂组分。在载体上加入烷基铝氧烷助催化剂组分。特异性金属茂的特征是：B（CpRaRb）（FlR'2）MQn（1）或式：B'（Cp'R'aR'b）（Fl'）M'Q'n'（2 ）式中Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'为2和7位的取代基，Ra和R'a是远离桥的取代基，Rb和R'b位于桥附近。 M和M'是过渡金属，Q'是卤素或C 1 -C 4烷基; 并且n'是0-4的整数。

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