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1. 发明申请

US20060247394A1 Process for increasing ethylene incorporation into random copolymers 审中-公开
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US20060247394A1
公开(公告)日：2006-11-02
申请号：US11117872
申请日：2005-04-29
申请人： William Gauthier , Jun Tian , Shady Henry , Nathan Williams
发明人： William Gauthier , Jun Tian , Shady Henry , Nathan Williams
IPC分类号： C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F2500/03 , C08F2500/20
摘要： Random copolymers may be prepared using a process that includes polymerizing a mixture of monomers including at least propylene and ethylene monomer, in the presence of a catalyst system including a metallocene catalyst having the general structure: racemic-X(2-R1-4-R2-Ind)2MCl2 wherein M is a Group 4, 5 or 6 transition metal, or a lanthanide or actinide series metal; X is a structural bridge imparting stereorigidity; R1 is hydrogen or an alkyl, aryl or a substitution moiety; R2 is hydrogen, or a C1-C4 alkyl; and Ind is an indenyl group. The copolymers are prepared under reaction conditions suitable to form a copolymer, wherein the copolymer has a higher level of ethylene incorporation than a corresponding polymer formed under otherwise identical reaction conditions except that a different bisindeny metallocene catalyst having a 4-indenyl substitution larger than 4 carbons is used. The copolymers may have a lower melt temperature than the corresponding polymers. The resulting copolymers may be used to prepare articles of manufacture including, but not limited to films, fibers and injection molded articles.
摘要翻译：无规共聚物可以使用包括聚合包含至少丙烯和乙烯单体的单体的混合物在内的方法在包括具有以下通式结构的茂金属催化剂的催化剂体系存在下的方法来制备：线式“end =”lead“？>外消旋-X（2-R 1 - 4-R 2 -Ind）2 MCl 其中M是第4,5或6族过渡金属，或镧系元素或锕系元素系列金属 ; X是赋予立体感的结构桥梁; R1是氢或烷基，芳基或取代部分; R 2是氢或C 1 -C 4烷基; 而Ind是茚基。共聚物在适于形成共聚物的反应条件下制备，其中共聚物具有比在其他相同反应条件下形成的相应聚合物更高的乙烯掺入水平，不同之处在于使用具有4-茚基取代基大于4个碳原子的不同的双茚基茂金属催化剂用来。共聚物可以具有比相应聚合物更低的熔融温度。所得共聚物可用于制备制品，包括但不限于薄膜，纤维和注模制品。

2. 发明申请

US20060247395A1 Process for increasing ethylene incorporation into random copolymers 有权
标题翻译：增加乙烯掺入无规共聚物的方法
公开(公告)号：US20060247395A1
公开(公告)日：2006-11-02
申请号：US11119243
申请日：2005-04-29
申请人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
发明人： William Gauthier , Jun Tian , David Rauscher , Constance Patrick , Shady Henry , Nathan Williams
IPC分类号： C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F4/65927
摘要： A process for preparing low melting copolymers comprising contacting a mixture of olefin monomers with a CpFlu-type metallocene catalyst under reaction conditions sufficient to form a copolymer. The copolymers thus prepared desirably display melt temperatures from about 100° C. to about 140° C. and may be produced with reduced amounts of ethylene. The copolymers may also exhibit reduced levels of undesirable xylene solubles, relatively narrow molecular weight distribution, and other improved optical and physical properties.
摘要翻译：一种制备低熔点共聚物的方法，包括使烯烃单体的混合物与CpFlu型金属茂催化剂在足以形成共聚物的反应条件下接触。如此制备的共聚物理想地显示约100℃至约140℃的熔融温度，并且可以用减少量的乙烯制备。共聚物也可以表现出不希望的二甲苯可溶物的水平降低，分子量分布相对窄，以及其他改进的光学和物理性能。

3. 发明授权

US07973113B2 Transition metal catalyst systems and formation thereof 有权
标题翻译：过渡金属催化剂体系及其形成
公开(公告)号：US07973113B2
公开(公告)日：2011-07-05
申请号：US12642896
申请日：2009-12-21
申请人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
发明人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
IPC分类号： C08F4/642 , C08F4/6592 , B01J31/14 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.
摘要翻译：本文描述了形成催化剂体系的催化剂体系和方法。所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

4. 发明授权

US08436112B2 Polyolefin production with a high performance support for a metallocene catalyst system 有权
标题翻译：聚烯烃生产具有高性能支持的茂金属催化剂体系
公开(公告)号：US08436112B2
公开(公告)日：2013-05-07
申请号：US12013774
申请日：2008-01-14
申请人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
发明人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76
CPC分类号： C08F4/76 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10T428/2982 , C08F4/65916 , C08F110/06 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/15
摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.
摘要翻译：本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属在整个支撑体上大体上被束缚。将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

5. 发明申请

US20080194399A1 Polyolefin Production with a High Performance Support for a Metallocene Catalyst System 有权
标题翻译：具有高性能支撑金属茂催化剂体系的聚烯烃生产
公开(公告)号：US20080194399A1
公开(公告)日：2008-08-14
申请号：US12013774
申请日：2008-01-14
申请人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
发明人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
IPC分类号： B01J31/00
CPC分类号： C08F4/76 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10T428/2982 , C08F4/65916 , C08F110/06 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/15
摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.
摘要翻译：本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属在整个支撑体上大体上被束缚。将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

6. 发明申请

US20100099834A1 Transition Metal Catalyst Systems and Formation Thereof 有权
标题翻译：过渡金属催化剂体系及其形成
公开(公告)号：US20100099834A1
公开(公告)日：2010-04-22
申请号：US12642896
申请日：2009-12-21
申请人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
发明人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
IPC分类号： C08F4/52 , C08F4/76
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.
摘要翻译：本文描述了形成催化剂体系的催化剂体系和方法。所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

7. 发明申请

US20050233892A1 Polyolefin production with a high performance support for a metallocene catalyst system 审中-公开
标题翻译：聚烯烃生产具有高性能支持的茂金属催化剂体系
公开(公告)号：US20050233892A1
公开(公告)日：2005-10-20
申请号：US11136136
申请日：2005-05-24
申请人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
发明人： Jun Tian , William Gauthier , David Rauscher , Shady Henry
IPC分类号： C08F4/642 , C08F2/00 , C08F4/00 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00
CPC分类号： C08F4/76 , C08F4/65912 , C08F4/65927 , C08F10/00 , Y10T428/2982 , C08F4/65916 , C08F110/06 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F2500/15
摘要： The invention is directed to a metallocene catalyst system and a process for preparing the system. The metallocene catalyst system comprises a support and metallocene bound substantially throughout the support. The selection of certain supports facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized.
摘要翻译：本发明涉及金属茂催化剂体系和制备该方法。茂金属催化剂体系包含基本上在整个载体上结合的载体和茂金属。某些载体的选择有助于生产具有比先前认识到的催化活性更高的茂金属催化剂体系。

8. 发明授权

US07683002B2 Transition metal catalyst and formation thereof 有权
标题翻译：过渡金属催化剂及其形成
公开(公告)号：US07683002B2
公开(公告)日：2010-03-23
申请号：US11492351
申请日：2006-07-25
申请人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
发明人： Jun Tian , William Gauthier , Joseph Thorman , Shady Henry
IPC分类号： C08F4/642 , C08F4/6592 , B01J31/14 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65916 , C08F2500/18 , C08F2500/03
摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.
摘要翻译：本文描述了形成催化剂体系的催化剂体系和方法。所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

9. 发明授权

US06855783B2 Supported metallocene catalysts 有权
标题翻译：负载金属茂催化剂
公开(公告)号：US06855783B2
公开(公告)日：2005-02-15
申请号：US10412372
申请日：2003-04-11
申请人： William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
发明人： William J. Gauthier , Margaret Kerr , Jun Tian , David J. Rauscher , Constance Hayworth Patrick , Shady Henry
IPC分类号： B01J31/00 , B01J37/00 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/02 , C08F4/42 , C08F4/44 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/18 , C08F2500/03 , C08F2500/12 , C08F2500/17 , C08F2500/15
摘要： Supported metallocene catalysts and processes for the use of such catalysts in isotactic polymerization of a C3+ ethylenically unsaturated monomer. The supported catalysts comprise a particulate silica support, an alkyl alumoxane component, and a metallocene catalyst component. The support has an average particle size of 10-50 microns, a surface area of 200-800 m2/g and a pore volume of 0.9-2.1 milliliters per gram (ml/g). Alumoxane is incorporated onto the support to provide a weight ratio of alumoxane to silica of at least 0.8:1. The metallocene is present in an amount of at least 1 weight percent of the silica and the alumoxane and is of the formula B(CpRaRb)(Fl′)MQ2 in which Fl′ is an unsubstituted fluorenyl group or a fluorenyl group symmetrically substituted at the 3 and 6 positions, B is a structural bridge between Cp and Fl′, Ra is a bulky substituent in a distal position, Rb is a less bulky substituent proximal to the bridge and non-vicinal to the distal substituent, M is a Group IVB transition metal or vanadium, and Q is a halogen or a Cl-C4 alkyl group.
摘要翻译：负载型金属茂催化剂和在C3 +烯属不饱和单体的全同立构聚合中使用这种催化剂的方法。载体催化剂包括颗粒二氧化硅载体，烷基铝氧烷组分和茂金属催化剂组分。载体的平均粒度为10-50微米，表面积为200-800平方米/克，孔体积为0.9-2.1毫升/克（毫升/克）。将Alumoxane加入到载体上以提供至少0.8:1的铝氧烷与二氧化硅的重量比。金属茂的存在量为二氧化硅和铝氧烷的至少1重量％，并且具有式B（CpRaRb）（F1'）MQ2，其中F1'是未取代的芴基或在该位置上对称取代的芴基 3和6位，B是Cp和Fl'之间的结构桥，Ra是远端位置的大体积取代基，Rb是靠近桥的较不庞大的取代基，而与远端取代基不相邻，M是IVB族过渡金属或钒，Q是卤素或C 1 -C 4烷基。

10. 发明申请

US20050171307A1 Polyamide supported metallocene catalysts 失效
公开(公告)号：US20050171307A1
公开(公告)日：2005-08-04
申请号：US11094681
申请日：2005-03-29
申请人： David Rauscher , William Gauthier , Shady Henry , Kai Hortmann
发明人： David Rauscher , William Gauthier , Shady Henry , Kai Hortmann
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F4/44
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/06 , Y02P20/52 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F2500/16 , C08F2500/15 , C08F2500/12 , C08F2500/18
摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene or two or more co-supported metallocenes.

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