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1. 再颁专利

USRE33452E Method for making alkylhalosilanes 失效
标题翻译：制备烷基卤硅烷的方法
公开(公告)号：USRE33452E
公开(公告)日：1990-11-20
申请号：US911614
申请日：1986-09-25
申请人： William J. Ward, III , Alan Ritzer , Kenneth M. Carroll , John W. Flock
发明人： William J. Ward, III , Alan Ritzer , Kenneth M. Carroll , John W. Flock
IPC分类号： B01J23/835 , C07F7/16
CPC分类号： B01J23/835 , C07F7/16
摘要： A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst. Significant improvements in reaction rate and product selectivity are achieved when copper is employed at a critical weight percent relative to silicon and critical weight ratios of tin and zinc are employed relative to copper.

2. 发明授权

US4500724A Method for making alkylhalosilanes 失效
标题翻译：制备烷基卤硅烷的方法
公开(公告)号：US4500724A
公开(公告)日：1985-02-19
申请号：US518236
申请日：1983-07-28
申请人： William J. Ward, III , Alan Ritzer , Kenneth M. Carroll , John W. Flock
发明人： William J. Ward, III , Alan Ritzer , Kenneth M. Carroll , John W. Flock
IPC分类号： B01J23/835 , B01J23/00 , B01J23/825 , B01J37/08 , C01B33/107 , C07B61/00 , C07F7/12 , C07F7/16
CPC分类号： B01J23/835 , C07F7/16
摘要： A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst. Significant improvements in reaction rate and product selectivity are achieved when copper is employed at a critical weight percent relative to silicon and critical weight ratios of tin and zinc are employed relative to copper.
摘要翻译：提供了通过在铜 - 锌 - 锡催化剂存在下，通过在烷基卤化物如甲基氯和粉末状硅之间进行反应来制备烷基卤代硅烷的方法。当以相对于硅的临界重量百分比使用铜时，实现反应速率和产物选择性的显着改善，并且相对于铜使用锡和锌的临界重量比。

3. 发明授权

US4487950A Method for making methylchlorosilanes 失效
标题翻译：制备甲基氯硅烷的方法
公开(公告)号：US4487950A
公开(公告)日：1984-12-11
申请号：US456470
申请日：1983-01-07
申请人： William J. Ward, III , George L. Gaines, Jr. , Alan Ritzer
发明人： William J. Ward, III , George L. Gaines, Jr. , Alan Ritzer
IPC分类号： C07F7/16
CPC分类号： C07F7/16
摘要： A process is provided for making methylchlorosilanes based on the reaction of methylchloride and particulated silicon, which has been contacted with a mixture of partially oxidized copper catalyst and copper formate. A reduction is achieved in the percent by weight of residue which are the silicon products in the methylchlorosilane crude having boiling points exceeding 70.degree. C. at atmospheric pressure, while the weight percent of disilane in such residue cleavable to useful chlorosilane monomer is not adversely affected.
摘要翻译：提供了基于与部分氧化的铜催化剂和甲酸铜的混合物接触的甲基氯和微粒硅的反应制备甲基氯硅烷的方法。在大气压下，沸点高于70℃的甲基氯硅烷粗品中的硅产物残留物的重量百分比达到减少，同时可残留于有用的氯硅烷单体的残留物中乙硅烷的重量百分比不会受到不利影响。

4. 发明授权

US4554370A Method for making alkylhalosilanes 失效
标题翻译：制备烷基卤硅烷的方法
公开(公告)号：US4554370A
公开(公告)日：1985-11-19
申请号：US665878
申请日：1984-10-29
申请人： William J. Ward, III , Alan Ritzer , Heine Lapidot
发明人： William J. Ward, III , Alan Ritzer , Heine Lapidot
IPC分类号： C07F7/12 , C07F7/16
CPC分类号： C07F7/16
摘要： The use of fumed silica in a mixture of powdered silicon and cuprous chloride has been found to reduce agglomeration in a fluid bed reactor during the production of alkylhalosilane under continuous conditions.
摘要翻译：发现在粉末状硅和氯化亚铜的混合物中使用热解法二氧化硅在连续条件下生产烷基卤硅烷期间减少流化床反应器中的团聚。

5. 发明授权

US5126203A Deactivation of spent silicon powder 失效
标题翻译：废硅粉末的停用
公开(公告)号：US5126203A
公开(公告)日：1992-06-30
申请号：US754144
申请日：1991-09-03
申请人： Alan Ritzer , George P. Moloney, Jr. , Jack C. Leunig
发明人： Alan Ritzer , George P. Moloney, Jr. , Jack C. Leunig
IPC分类号： C01B33/107 , C08K11/00
CPC分类号： C08K11/005 , C01B33/10742 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： Residual silicone from direct process manufacture of chlorosilanes is stabilized for transportation and disposal by pelletizing finely divided particles of finely divided residual silicon powder contaminated with chlorine, hydrogen, and oxygen and highly reactive and exothermic upon exposure to moisture, and impregnating the pellets with an organic binder.
摘要翻译：通过将受氯，氢和氧污染的精细分散的残留硅粉碎成细碎的颗粒，经过暴露于水分后具有高反应性和放热性，并且用有机物浸渍颗粒，稳定了氯硅烷直接工艺制造的残留硅氧烷用于运输和处理粘合剂

6. 发明授权

US4390510A Process for treating spent silicon-containing reaction masses to produce halosilanes 失效
标题翻译：用于处理含有废硅的反应物质以制备卤代硅烷的方法
公开(公告)号：US4390510A
公开(公告)日：1983-06-28
申请号：US349139
申请日：1982-02-16
申请人： Alan Ritzer , Bakulesh Shah , Daniel E. Sliva
发明人： Alan Ritzer , Bakulesh Shah , Daniel E. Sliva
IPC分类号： C01B33/107 , C07F7/16 , C01B33/08
CPC分类号： C07F7/16 , C01B33/107 , C01B33/1071
摘要： Improved yields of monohydrogentrihalosilanes are achieved by contacting the residual silicon obtained from the preparation of organohalosilanes by a metal-catalyzed direct process by contacting the residual silicon simultaneously with gaseous hydrogen halide and with gaseous alkyl halide to form a residual silicon contact mass; selecting a temperature between about 200.degree. C. and about 350.degree. C. at which alkylation of the silicon contact mass in inhibited and at which hydrohalogenation of the silicon contact mass occurs; and heating the silicon contact mass at the selected temperature. The silicon reacts with the gaseous alkyl halide and the gaseous hydrogen halide at the selected temperature to produce improved yields of the monohydrogentrihalosilane. In preferred embodiments, monohydrogentrichlorosilane is produced by reacting residual silicon with hydrogen chloride and methyl chloride at a temperature less than the temperature at which a predominantly alkylation reaction occurs with the residual contact mass so that there is sufficient hydrohalogenation to form the monohydrogentrichlorosilane.
摘要翻译：单氢化三卤硅烷的提高产率是通过金属催化的直接方法使残留的硅与气态卤化氢和气态烷基卤接触而形成剩余的硅接触物质而使得到的由有机卤代硅烷制备得到的剩余硅与选择约200℃至约350℃的温度，其中硅接触物质的烷基化被抑制并发生硅接触质量的氢卤化; 并在所选择的温度下加热硅接触块。硅在所选择的温度下与气态烷基卤化物和气态卤化氢反应，以产生单氢化三卤硅烷的提高的产率。在优选的实施方案中，通过使残余硅与氯化氢和氯甲烷在低于与残余接触质量发生主要烷基化反应的温度的温度下反应而产生单氢化三氯硅烷，使得存在足够的氢卤化以形成单氢三氯硅烷。

7. 发明授权

US5312946A Siloxane fluid from methylchlorosilane residue waste 失效
标题翻译：甲基氯硅烷残留物的硅氧烷流失
公开(公告)号：US5312946A
公开(公告)日：1994-05-17
申请号：US867938
申请日：1992-04-13
申请人： Robert G. Stank , Luisito A. Tolentino , Alan Ritzer , Frank J. Traver
发明人： Robert G. Stank , Luisito A. Tolentino , Alan Ritzer , Frank J. Traver
IPC分类号： C08G77/48 , C08G77/50 , C07F7/08
CPC分类号： C08G77/50 , C08G77/48 , Y10S516/01 , Y10S516/07
摘要： Siloxane fluids containing novel siloxane polymers prepared from mixtures of disilanes, disiloxanes and silylmethylenes, and a method for recovering fully alkylated linear and cyclic siloxanes with disilane, disiloxane and silylmethylene bonds, such as from methylchlorosilane residue cleavage bottoms, are disclosed.
摘要翻译：公开了含有由二硅烷，二硅氧烷和甲硅烷基亚甲基的混合物制备的新型硅氧烷聚合物的硅氧烷流体，以及用乙硅烷，二硅氧烷和甲硅烷基亚甲基（例如甲基氯硅烷残基裂解底物）回收完全烷基化的直链和环状硅氧烷的方法。

8. 发明授权

US5243061A Method for making organohalosilanes 失效
标题翻译：制备有机卤代硅烷的方法
公开(公告)号：US5243061A
公开(公告)日：1993-09-07
申请号：US987872
申请日：1992-12-09
申请人： Steven W. Webb , Alan Ritzer , John D. Neely
发明人： Steven W. Webb , Alan Ritzer , John D. Neely
IPC分类号： B01J23/72 , C07B61/00 , C07F7/12 , C07F7/16
CPC分类号： C07F7/16
摘要： A method for making organohalosilanes is provided utilizing spent contact mass generated during the production of organohalosilanes by the direct method which has been treated in an oxygen containing atmosphere to render it non-pyrophoric in air.
摘要翻译：提供了制备有机卤代硅烷的方法，其利用在含氧气氛中处理以使其在空气中不发火的直接方法在生产有机卤代硅烷期间产生的废接触物质。

9. 发明授权

US5239102A Method for making organohalosilanes 失效
标题翻译：制备有机卤代硅烷的方法
公开(公告)号：US5239102A
公开(公告)日：1993-08-24
申请号：US867656
申请日：1992-04-13
申请人： Steven W. Webb , Alan Ritzer , John D. Neely
发明人： Steven W. Webb , Alan Ritzer , John D. Neely
IPC分类号： C07F7/16
CPC分类号： C07F7/16
摘要： A method for making organohalosilanes is provided utilizing a spent contact mass generated during the production of organohalosilanes by the direct method which has been thermally treated to render it non-reactive in air.
摘要翻译：提供了一种制备有机卤代硅烷的方法，该方法利用已经通过热处理使其在空气中无反应的直接方法在生产有机卤代硅烷期间产生的废接触物质。

10. 发明授权

US4393229A Redistribution of polysilanes in high boiling residues 失效
标题翻译：聚硅烷在高沸点残渣中的再分配
公开(公告)号：US4393229A
公开(公告)日：1983-07-12
申请号：US372601
申请日：1982-04-28
申请人： Alan Ritzer , Abraham L. Hajjar , Harry R. McEntee , Ray W. Shade
发明人： Alan Ritzer , Abraham L. Hajjar , Harry R. McEntee , Ray W. Shade
IPC分类号： B01J27/08 , B01J27/122 , B01J27/125 , B01J27/135 , B01J31/26 , C07B61/00 , C07F7/12 , C07F7/08
CPC分类号： C07F7/125
摘要： A process is described for converting the alkyl-rich disilanes in the residue obtained from the manufacture of alkylhalosilanes to halogen-rich polysilanes with alkyltrihalosilanes and simultaneously converting the alkyltrihalosilanes to dialkyldihalosilanes by reacting the alkyl-rich polysilanes in the residue and the alkyltrihalosilanes at an elevated temperature in the presence of a suitable catalyst and a catalytic amount of a hydrosilane reaction promoter. In a preferred embodiment, the residue containing alkyl-rich disilanes is treated with methyltrichlorosilane at a temperature of about 100.degree. C. to about 250.degree. C. in the presence of aluminum trichloride catalyst and a catalytic amount of methyldichlorosilane.
摘要翻译：描述了将烷基卤代硅烷制得的残余物中富含烷基的二硅烷转化为富烷基的聚硅烷与烷基三卤代硅烷同时通过烷基三卤硅烷在烷基三卤硅烷中的烷基三卤代硅烷转化为二烷基二卤代硅烷的方法，在合适的催化剂和催化量的氢化硅烷反应促进剂的存在下的温度。在优选的实施方案中，在三氯化铝催化剂和催化量的甲基二氯硅烷的存在下，在约100℃至约250℃的温度下，用甲基三氯硅烷处理含有富烷基二硅烷的残余物。

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