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    • 7. 发明授权
    • Preparation of components for transportation fuels
    • 运输燃料组分的制备
    • US06881325B2
    • 2005-04-19
    • US09779287
    • 2001-02-08
    • George Ernest MorrisAndrew Richard LucyWilliam H. GongMonica Cristina RegalbutoGeorge A. Huff, Jr.
    • George Ernest MorrisAndrew Richard LucyWilliam H. GongMonica Cristina RegalbutoGeorge A. Huff, Jr.
    • C10G67/12C10G27/04
    • C10G67/12
    • Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons, sulfur-containing and nitrogen-containing organic compounds. Oxidation feedstock is contacted with a soluble quaternary ammonium salt containing halogen, sulfate, or bisulfate anion, and an immiscible aqueous phase comprising a source of hydrogen peroxide, and at least one member of the group consisting of phosphomolybdic acid and phosphotungstic acid, in a liquid reaction mixture under conditions suitable for reaction of one or more of the sulfur-containing and/or nitrogen-containing organic compounds. Blending components containing less sulfur and/or less nitrogen than the oxidation feedstock are recovered from the reaction mixture. Advantageously, at least a portion of the immiscible acid-containing phase is recycled to the oxidation.
    • 公开了经济方法,用于通过选择性氧化包含烃,含硫和含氮有机化合物的混合物的原料来生产用于运输燃料的炼油厂混合的组分。 氧化原料与含有卤素,硫酸盐或硫酸氢盐阴离子的可溶性季铵盐和包含过氧化氢源的不混溶水相和至少一种由磷钼酸和磷钨酸组成的组中的一种在液体中接触 反应混合物在适于一种或多种含硫和/或含氮有机化合物的反应条件下进行。 从反应混合物中回收含有比氧化原料少的硫和/或更少的氮的混合组分。 有利地,至少一部分不混溶的含酸相被再循环至氧化。