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    • 9. 发明授权
    • Electrochemical cells with end-of-life indicator
    • 具有寿命终止指示剂的电化学电池
    • US4619874A
    • 1986-10-28
    • US641684
    • 1984-08-17
    • Paul M. SkarstadThomas G. Hayes
    • Paul M. SkarstadThomas G. Hayes
    • H01M4/36H01M6/50H01M10/48
    • H01M6/5055H01M4/36
    • Electrochemical cells having an oxidizable active anode material, a solid, non-reactive electronically conductive cathode current collector, and an electrolytic solution between and in contact with the anode and the cathode current collector, the electrolytic solution comprising a solvent cathode component which is a liquid oxyhalide or thiohalide. And anode ion transporting solute component dissolved therein for rendering the electrolytic solution conductive of anode metal ions, the electrolytic solution having an end-of-life (EOL) component associated therewith, the EOL component being selected from the group consisting of the Main Group V halides preferably arsenic tribromide (AsBr.sub.3), arsenic trichloride (AsCl.sub.3), arsenic trifluoride (AsF.sub.3), vanadium halides, transition metal sulfides, oxides, except for the actinide series and technetium, and mixtures thereof to provide end-of-life indication. The EOL component selected in any specific instance has an electropotential which is lower than that of the specific solvent cathode component used i.e., the primary cathode material in the electrolytic solution.
    • 具有可氧化活性阳极材料,固体,非反应性电子导电阴极集电器和在阳极和阴极集电器之间并与之接触的电解液的电化学电池,所述电解质溶液包含溶剂阴极组分,其为液体 卤氧化物或硫代卤化物。 并且阳极离子迁移溶质组分溶解在其中以使电解液导电阳极金属离子,所述电解质溶液具有与其结合的寿命终止(EOL)组分,所述EOL组分选自主组V 卤化物优选三溴化砷(AsBr 3),三氯化砷(AsCl 3),三氟化砷(AsF 3),卤化钒,过渡金属硫化物,除了锕系和锝以外的氧化物,以及它们的混合物,以提供寿命终止指示。 在任何具体情况下选择的EOL组分具有低于所使用的特定溶剂阴极组分的电位,即电解溶液中的主要阴极材料。