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    • 3. 发明授权
    • Rigid polyurethanes based on allophanate-modified aliphatic and/or
cycloaliphatic polyisocyanurates
    • 基于脲基甲酸酯改性的脂族和/或脂环族聚异氰脲酸酯的刚性聚氨酯
    • US5614605A
    • 1997-03-25
    • US359213
    • 1994-12-19
    • Robson MafotiWilliam E. Slack
    • Robson MafotiWilliam E. Slack
    • C08G18/42C08G18/48C08G18/78C08G18/79C08G18/00
    • C08G18/482C08G18/4202C08G18/7837C08G18/792
    • This invention relates to rigid polyurethanes prepared by reaction, at an isocyanate index of 95 to 110, of(a) an allophanate-modified aliphatic and/or cycloaliphatic polyisocyanurate;(b) 20 to 100% by weight, relative to the total of components (b) and (c), of(i) one or more polyether and/or polyester polyols containing three or more isocyanate-reactive hydroxyl groups and having a molecular weight of 200 to 6000, and(ii) 0 to 30% by weight, relative to component (b)(i), of one or more isocyanate-reactive compounds other than a polyether or polyester of component (b)(i) and containing two or more isocyanate-reactive hydroxyl groups and having a molecular weight of about 400 to about 10,000,(c) 0 to 30% by weight, relative to the total of components (b) and (c), of a chain extender and/or crosslinker other than a polyether or polyester and having a molecular weight of from 32 to 399, wherein the amounts of components (b) and (c) total 100% by weight.
    • 本发明涉及通过在(a)脲基甲酸酯改性的脂族和/或脂环族聚异氰脲酸酯的异氰酸酯指数为95至110的反应中制备的刚性聚氨酯; (b)相对于组分(b)和(c)的总量为20至100重量%,(i)一种或多种含有三个或更多个异氰酸酯反应性羟基并具有分子量的聚醚和/或聚酯多元醇 相对于组分(b)(i),除了组分(b)(i)的聚醚或聚酯以外的一种或多种异氰酸酯反应性化合物和(ii)0至30重量% 含有两个或更多个异氰酸酯反应性羟基并且分子量为约400至约10,000,(c)0至30重量%,相对于增链剂组分(b)和(c)的总量,和 /或聚醚或聚酯以外的分子量为32〜399的交联剂,其中组分(b)和(c)的总量为100重量%。
    • 9. 发明授权
    • Preparation of cast elastomers using aminocrotonate-terminated polyether
chain extenders
    • 使用氨基巴豆酸酯封端的聚醚增链剂制备流延弹性体
    • US5516872A
    • 1996-05-14
    • US270605
    • 1994-07-05
    • Robson MafotiAlan D. Bushmire
    • Robson MafotiAlan D. Bushmire
    • C08G18/10C08G18/67
    • C08G18/6795C08G18/10
    • This invention relates to a process for preparing polyurethane elastomers comprising reacting in an open mold at an isocyanate index of about 90 to about 110(a) an isocyanate prepolymer having an isocyanate content of about 2 to about 15% by weight and a molecular weight of from about 500 to about 5000 prepared by reaction of(i) at least one organic polyisocyanate with(ii) at least one isocyanate-reactive compound having at least two isocyanate-reactive groups and a molecular weight of from about 250 to about 4000;with(b) certain aminocrotonate-terminated polyethers having a molecular weight of from about 500 to about 1500;(c) optional chain extenders and/or crosslinkers other than aminocrotonate-terminated polyether (b); and(d) optional auxiliaries and/or additives.
    • 本发明涉及一种制备聚氨酯弹性体的方法,包括在开模中以异氰酸酯指数为约90至约110(a)异氰酸酯含量为约2至约15重量%的异氰酸酯预聚物和分子量为 通过(i)至少一种有机多异氰酸酯与(ii)至少一种具有至少两个异氰酸酯反应性基团和分子量为约250至约4000的异氰酸酯反应性化合物的反应制备的约500至约5000; (b)某些氨基巴豆酸酯封端的聚醚,其分子量为约500至约1500; (c)除氨基巴豆酸酯封端的聚醚(b)之外的任选的增链剂和/或交联剂; 和(d)任选的助剂和/或添加剂。