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1. 发明授权

US5349082A Toluene diisocyanate residue 失效
标题翻译：甲苯二异氰酸酯残基
公开(公告)号：US5349082A
公开(公告)日：1994-09-20
申请号：US33935
申请日：1993-03-19
申请人： William E. Slack , Kenneth L. Dunlap , Larry W. Arndt , Louis Renbaum
发明人： William E. Slack , Kenneth L. Dunlap , Larry W. Arndt , Louis Renbaum
IPC分类号： C07C263/20
CPC分类号： C07C263/20
摘要： Disclosed herein is a process for recovering toluene diisocyanate (TDI) from a TDI residue solution, comprising mixing the residue solution with a polyisocyanate consisting essentially of methylenediphenyl diisocyanate (MDI) or MDI in combination with its higher ring oligomer, followed by heating the resulting mixture over a temperature range of 130.degree. to 250.degree. C. for a period of time sufficient to remove free TDI and thermally splittable TDI generated from equilibration of the TDI residue with MDI or the MDI oligomer by either a batch or continuous process.
摘要翻译：本文公开了一种从TDI残余物溶液中回收甲苯二异氰酸酯（TDI）的方法，包括将残余物溶液与基本上由亚甲基二苯基二异氰酸酯（MDI）或MDI组合的多异氰酸酯与其较高级的低聚物组合，然后加热得到的混合物在130-250℃的温度范围内，足以除去通过MDI或MDI低聚物通过间歇或连续方法平衡TDI残余物产生的游离TDI和热裂解TDI的时间。

2. 发明授权

US4810820A Process for the production of polyisocyanates containing allophanate groups 失效
标题翻译：用于生产含有脲基甲酸酯基团的多异氰酸酯的方法
公开(公告)号：US4810820A
公开(公告)日：1989-03-07
申请号：US84546
申请日：1987-08-12
申请人： William E. Slack , Terry A. Potter , Kenneth L. Dunlap
发明人： William E. Slack , Terry A. Potter , Kenneth L. Dunlap
IPC分类号： C08G18/73 , C07C67/00 , C07C241/00 , C07C263/16 , C07C265/00 , C07C265/04 , C07C273/18 , C07C275/60 , C08G18/78 , C09D175/00 , C07C127/22
CPC分类号： C07C265/10 , C07C265/00 , C07C273/1809 , C08G18/7837
摘要： Aliphatic and/or cycloaliphatic polyisocyanates containing allophanate groups are produced by reacting (a) a di- and/or polyisocyanate with aliphatic and/or cycloaliphatic isocyanate groups with (b) a hydroxy compound at a temperature of at least 150.degree. C. for no more than 90 minutes and then rapidly cooling the reaction mixture to a temperature of less than 100.degree. C. It is preferred that the reaction be carried out in the absence of oxygen. The products thus obtained are virtually colorless, have a relatively low viscosity and excellent storage stability.

3. 发明授权

US07378543B2 Stable liquid biuret modified and biuret allophanate modified toluene diisocyanates, prepolymers thereof, and processes for their preparation 失效
标题翻译：稳定的液体缩二脲改性和缩二脲脲基甲酸酯改性甲苯二异氰酸酯，其预聚物及其制备方法
公开(公告)号：US07378543B2
公开(公告)日：2008-05-27
申请号：US10626368
申请日：2003-07-24
申请人： William E. Slack , Rick L. Adkins , Hersel T. Kemp
发明人： William E. Slack , Rick L. Adkins , Hersel T. Kemp
IPC分类号： C07C263/00 , C07C273/00
CPC分类号： C08G18/10 , C08G18/089 , C08G18/7831 , C08G18/808
摘要： This invention relates to stable liquid biuret modified toluene diisocyanates, prepolymers thereof, stable liquid biuret allophanate modified toluene diisocyanates, prepolymers thereof, and to processes for the preparation of these compositions. The stable liquid biuret modified toluene diisocyanates comprise a secondary amine based biuret modified TDI having an NCO group content of about 12 to about 46% by weight.
摘要翻译：本发明涉及稳定的液体缩二脲改性甲苯二异氰酸酯，其预聚物，稳定的液体缩二脲脲基甲酸酯改性甲苯二异氰酸酯，其预聚物，以及这些组合物的制备方法。稳定的液体缩二脲改性甲苯二异氰酸酯包含NCO基含量为约12至约46重量％的仲胺基缩二脲改性TDI。

4. 发明申请

US20080114186A1 New liquid modified diphenylmetilane diisocyanates 失效
标题翻译：新的液体改性二苯基甲烷二异氰酸酯
公开(公告)号：US20080114186A1
公开(公告)日：2008-05-15
申请号：US11599135
申请日：2006-11-14
申请人： Rick L. Adkins , William E. Slack , Hersel Kemp , Lewis S. Newman
发明人： Rick L. Adkins , William E. Slack , Hersel Kemp , Lewis S. Newman
IPC分类号： C07C265/00
CPC分类号： C08G18/7671 , C08G18/3825
摘要： This invention relates to novel liquid, storage-stable diisocyanates and to a process for the preparation of these liquid, storage-stable diisocyanates. These comprise diphenylmethane diisocyanate and at least one compound which contains both an amide group and a hydroxyl group and which corresponds to one of two specified formulas.
摘要翻译：本发明涉及新的液体，储存稳定的二异氰酸酯和制备这些液体储存稳定的二异氰酸酯的方法。这些包括二苯基甲烷二异氰酸酯和至少一种含有酰胺基和羟基并且对应于两个特定式之一的化合物。

5. 发明授权

US06887399B2 Polymeric allophanates of diphenylmethane diisocyanate, prepolymers of these polymeric allophanates, and processes for the preparation of the polymeric allophanates and the prepolymers thereof 失效
标题翻译：二苯基甲烷二异氰酸酯的聚合型脲基甲酸酯，这些聚合型脲基甲酸酯的预聚物，以及聚合脲基甲酸酯及其预聚物的制备方法
公开(公告)号：US06887399B2
公开(公告)日：2005-05-03
申请号：US10238444
申请日：2002-09-09
申请人： William E. Slack , Hersel T. Kemp, II , William E. Miller
发明人： William E. Slack , Hersel T. Kemp, II , William E. Miller
IPC分类号： C08G18/09 , C08G18/10 , C08G18/76 , C08G18/78 , C07C275/60 , C07C269/02 , C07C271/66 , C07C273/00 , C07C275/62
CPC分类号： C08G18/7837
摘要： The present invention relates to a new high functionality MDI. In particular, this invention relates to polymeric allophanates based on diphenylmethane diisocyanate having an NCO group content of 12 to 30%, prepolymers thereof, and processes for the production of these compositions. The prepolymers are stable liquids having NCO group contents of about 10 to about 28%.
摘要翻译：本发明涉及一种新的高功能MDI。特别地，本发明涉及基于NCO基团含量为12-30％的二苯基甲烷二异氰酸酯的聚合物脲基甲酸酯，其预聚物，以及这些组合物的制备方法。预聚物是具有约10至约28％的NCO基团含量的稳定液体。

6. 发明授权

US6063891A Freeze stable allophanate-modified toluene diisocyanate trimers 失效
标题翻译：冷冻稳定的脲基甲酸酯改性甲苯二异氰酸酯三聚体
公开(公告)号：US6063891A
公开(公告)日：2000-05-16
申请号：US375842
申请日：1999-08-16
申请人： William E. Slack , Hersel T. Kemp, II
发明人： William E. Slack , Hersel T. Kemp, II
IPC分类号： C08G18/09 , C08G18/16 , C08G18/76 , C08G18/78 , C08G18/10
CPC分类号： C08G18/7837 , C08G18/092 , C08G18/161 , C08G18/7621
摘要： This invention relates to a novel freeze-stable allophanate modified toluene diisocyanurates, and to a process for producing these freeze-stable allophanate-modified toluene diisocyanurates which requires a catalyst which is capable of forming both trimer and allophanate groups, or a catalyst system comprising at least one catalyst capable of forming trimer groups and at least one catalyst capable of forming allophanate groups. This invention also relates to novel freeze-stable blends of the allophanate-modified toluene diisocyanurates with di- and/or polyisocyanates of the diphenylmethane series; and to freeze-stable urethane prepolymers of the allophanate-modified toluene diisocyanurates, or the blends of these with an isocyanate of the diphenylmethane series.
摘要翻译：本发明涉及一种新型的冷冻稳定的脲基甲酸酯改性的甲苯二异氰脲酸酯，以及制备这种冷冻稳定的脲基甲酸酯改性的甲苯二异氰酸酯的方法，其需要能够形成三聚体和脲基甲酸酯基团的催化剂，或者包含能够形成三聚体基团的至少一种催化剂和能够形成脲基甲酸酯基团的至少一种催化剂。本发明还涉及脲基甲酸酯改性的甲苯二异氰脲酸酯与二苯基甲烷系列的二 - 和/或多异氰酸酯的新型冷冻稳定共混物; 以及脲基甲酸酯改性的甲苯二异氰脲酸酯的冷冻稳定的氨基甲酸酯预聚物，或它们与二苯基甲烷系列的异氰酸酯的共混物。

7. 发明授权

US5905151A Trimer catalyst for aliphatic and aromatic isocyanates 失效
标题翻译：用于脂族和芳族异氰酸酯的三聚体催化剂
公开(公告)号：US5905151A
公开(公告)日：1999-05-18
申请号：US18830
申请日：1993-02-18
申请人： William E. Slack , Hersel T. Kemp, II
发明人： William E. Slack , Hersel T. Kemp, II
IPC分类号： C07D251/34 , C07D263/00 , C07D263/16
CPC分类号： C07D251/34 , C07D263/00 , C07D263/16
摘要： This invention relates to a process for trimerizing organic polyisocyanates in the presence of thermally active catalyst systems. The catalyst systems comprise (a) compounds selected from the group consisting of 1) lithium salts of aliphatic or aromatic carboxylic acids, 2) lithium salts of hydroxyl group containing compounds wherein the hydroxyl groups are directed attached to an aromatic ring, and 3) lithium hydroxide; used in conjunction with (b) an organic compound which contains at least one hydroxyl group.
摘要翻译：本发明涉及在热活性催化剂体系存在下使有机多异氰酸酯三聚的方法。催化剂体系包括（a）选自下组的化合物：1）脂肪族或芳族羧酸的锂盐，2）羟基指向与芳环连接的含羟基化合物的锂盐，和3）锂氢氧化物; 与（b）含有至少一个羟基的有机化合物结合使用。

8. 发明授权

US5753749A Dicyclohexylmethane diisocyanate residue-based compositions and the use of such compositions as fillers 失效
标题翻译：基于二环己基甲烷二异氰酸酯残基的组合物以及这种组合物作为填料的用途
公开(公告)号：US5753749A
公开(公告)日：1998-05-19
申请号：US777314
申请日：1996-12-27
申请人： William E. Slack
发明人： William E. Slack
IPC分类号： C08G18/28 , C08G18/40 , C08G18/72 , C08G18/75 , C08K5/04 , C08K5/205 , C07C269/02 , C08K5/06 , C08K5/10 , C08K5/29 , C08L75/04 , C08L75/06 , C08L75/08
CPC分类号： C08G18/758 , C08G18/282 , C08G18/283 , C08G18/409 , C08G18/725 , C08K5/04
摘要： Urethane-filled compositions are produced by reacting a dicyclohexylmethane diisocyanate residue or a dicyclohexylmethane diisocyanate residue containing mixture with a monofunctional alcohol containing at least one ether group in an amount such that the equivalent ratio isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The diisocyanate residue or residue-containing mixture must contain at least 20% by weight monomeric diisocyanate and have a total NCO content of at least 10%. The diisocyanate residue is produced by phosgenating dicyclohexylmethane diamine in which less than 20% polymeric diamine is present. The urethane filled compositions produced in this manner may then be dissolved in either a polyol or a polyisocyanate and subsequently used to produce polyurethanes in known manner.
摘要翻译：填充聚氨酯的组合物通过使二环己基甲烷二异氰酸酯残基或含二环己基甲烷二异氰酸酯残基的混合物与含有至少一个醚基团的单官能醇反应，使得异氰酸酯基与羟基的当量比为约0.9:1至约 1：0.9。二异氰酸酯残基或含残渣的混合物必须含有至少20重量％的单体二异氰酸酯，总NCO含量至少为10％。二异氰酸酯残基通过其中存在少于20％的聚合二胺的二环己基甲烷二胺光气化而产生。然后将以这种方式制备的聚氨酯填充的组合物溶解在多元醇或多异氰酸酯中，随后用于以已知方式制备聚氨酯。

9. 发明授权

US5646227A Low surface energy polyisocyanates and their use in one- or two-component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
公开(公告)号：US5646227A
公开(公告)日：1997-07-08
申请号：US593129
申请日：1996-02-01
申请人： William E. Slack , Edward P. Squiller , Philip E. Yeske
发明人： William E. Slack , Edward P. Squiller , Philip E. Yeske
IPC分类号： C08G18/70 , C08G18/61 , C08G18/77 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/04 , C08G77/04
CPC分类号： C08G18/61 , C08G18/7837 , C08G18/791 , C08G18/8054
摘要： The present invention is directed to a polyisocyanate mixturei) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate,ii) containing up to 25% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126),iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane and urea groups and such that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. andiv) containing siloxane groups (calculated as SiO, MW 44) in an amount of 0.002 to 50% by weight,wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing two or more isocyanate-reactive groups directly attached to carbon atoms and one or more siloxane groups. The present invention is also directed to a process for the production of this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
摘要翻译：本发明涉及NCO含量为5-35重量％并由有机二异氰酸酯制备的多异氰酸酯混合物，ii）含有至多25重量％的异氰脲酸酯基（以N 3，C 3，O 3， MW 126），iii）含有脲基甲酸酯基团，其量使得比氨基甲酸酯和脲基团具有更多当量的脲基甲酸酯基团，并且使得多异氰酸酯混合物在25℃保存3个月并保持稳定和均匀，以及iv）含硅氧烷基团（以SiO，MW 44计），其量为0.002至50重量％，其中前述百分比是基于多异氰酸酯混合物的固体含量，不包括任何未反应的有机二异氰酸酯，并且其中硅氧烷基团通过使异氰酸酯基团与含有直接连接到碳原子上的两个或多个异氰酸酯反应性基团和一个或多个硅氧烷基团的化合物反应。本发明还涉及在单组分或双组分涂料组合物中制备该多异氰酸酯混合物及其用途，任选为封闭形式的异氰酸酯组分的方法。

10. 发明授权

US5576411A Low surface energy polyisocyanates and their use in one-or two component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在一种或两种组分涂料组合物中的用途
公开(公告)号：US5576411A
公开(公告)日：1996-11-19
申请号：US306553
申请日：1994-09-14
申请人： Philip E. Yeske , Edward P. Squiller , William E. Slack
发明人： Philip E. Yeske , Edward P. Squiller , William E. Slack
IPC分类号： C08G18/77 , C07D251/34 , C08G18/50 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C08G18/28
CPC分类号： C08G18/8087 , C07D251/34 , C08G18/5015 , C08G18/7837 , C08G18/791 , C08G18/8054
摘要： The present invention is directed to a polyisocyanate mixturei) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate,ii) containing at least 1% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126),iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane groups andiv) containing fluorine (calculated as F, AW 19) in an amount of 0.001 to 50% by weight,wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane groups and converting a sufficient amount of these urethane groups to allophanate groups to satisfy the requirements of iii), provided that the polyisocyanate mixture contains sufficient allophanate groups to ensure that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. The present invention is also directed to a process for the production this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
摘要翻译：本发明涉及NCO含量为5至35重量％并由有机二异氰酸酯制备的多异氰酸酯混合物i），ii）含有至少1重量％的异氰脲酸酯基（以N 3，C 3，O 3， MW 126），iii）含有脲基甲酸酯基团，其量使得比氨基甲酸酯基团具有更多当量的脲基甲酸酯基，和iv）含有0.001至50重量％的氟（以F，AW 19计算），其中前述百分数是基于多异氰酸酯混合物的固体含量，不包括任何未反应的有机二异氰酸酯，并且其中氟通过使异氰酸酯基团与含有两个或更多个碳原子，一个或多个羟基和一个或多个氟原子的化合物反应而引入以形成氨基甲酸酯基团并将足够量的这些氨基甲酸酯基团转化为脲基甲酸酯基团以满足iii）的要求，条件是多异氰酸酯混合物包含足够的全部以确保多异氰酸酯混合物在25℃下储存3个月时保持稳定和均匀。本发明还涉及一种制备该多异氰酸酯混合物的方法及其用途，任选以封闭形式作为异氰酸酯组分在一种或两种组分的涂料组合物中。

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