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1. 发明申请

US20090253861A1 Method of emulsion polymerization 有权
标题翻译：乳液聚合方法
公开(公告)号：US20090253861A1
公开(公告)日：2009-10-08
申请号：US12384420
申请日：2009-04-02
申请人： William Douglas Rohrbach , David Lewis Zimmerman, JR.
发明人： William Douglas Rohrbach , David Lewis Zimmerman, JR.
IPC分类号： C08F2/32
CPC分类号： C08F2/24 , B01J19/1881 , B01J2219/0011 , B01J2219/00114 , B01J2219/00254 , C08F2/01 , F28D9/00
摘要： There is provided a process of emulsion polymerization comprising (a) adding a reactive mixture to a reaction vessel, said reactive mixture comprising water, one or more emulsifier, one or more monomer, and one or more initiator, (b) providing conditions in which said reactive mixture undergoes emulsion polymerization, and (c) passing some of the contents of said reaction vessel through a recirculating loop comprising a low-shear pump and a plate and frame heat exchanger having gap width of 6 to 18 mm, wherein more than 50% of the heat produced by said emulsion polymerization is removed from the contents of said reaction vessel by said plate and frame heat exchanger.
摘要翻译：提供了一种乳液聚合方法，其包括（a）向反应容器中加入反应性混合物，所述反应混合物包含水，一种或多种乳化剂，一种或多种单体和一种或多种引发剂，（b）提供其中所述反应性混合物经历乳液聚合，和（c）使所述反应容器的一些内容物通过包括低剪切泵和间隙宽度为6至18mm的板框式热交换器的再循环回路，其中多于50 通过所述板框式热交换器从所述反应容器的内容物中除去所述乳液聚合产生的热量的％。

2. 发明申请

US20100130643A1 Polymer compositions containing phosphates 有权
标题翻译：含磷酸盐的聚合物组合物
公开(公告)号：US20100130643A1
公开(公告)日：2010-05-27
申请号：US12592181
申请日：2009-11-20
申请人： William Douglas Rohrbach
发明人： William Douglas Rohrbach
IPC分类号： C08K3/32 , C08C1/08
CPC分类号： C08L51/003 , C08F2/001 , C08F257/02 , C08F265/04 , C08F279/02 , C08K3/32 , C08L51/00 , C08L51/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02
摘要： In a first aspect of the present invention, there is provided a polymer composition comprising (i) one or more multistage polymer comprising (a) a first stage polymer having Tg of 0° C. or lower, (b) a subsequent stage polymer having Tg of 20° C. or higher, (ii) one or more phosphate salt of a multivalent cation, and (iii) one or more alkaline phosphate, in the amount of 100 ppm or more, measured as the weight of phosphorous, based on the dry weight of said multistage polymer. In a second aspect of the present invention, there is provided a mixture comprising the polymer composition of the first aspect described above and one or more matrix resin.In a third aspect of the present invention, there is provided a process for making a polymer composition comprising the steps of providing a multistage polymer latex, coagulating said multistage polymer latex, mixing said multistage polymer with an aqueous solution of an alkaline phosphate, and drying said multistage polymer to a water content of less than 1% by weight of water based on the dry weight of said multistage polymer, wherein said dried multistage polymer comprises 100 ppm or more, based on the dry weight of said multistage polymer, of phosphorous that is in the form of an alkaline phosphate.
摘要翻译：在本发明的第一方面，提供一种聚合物组合物，其包含（i）一种或多种多段聚合物，其包含（a）Tg为0℃或更低的第一阶段聚合物，（b）后续聚合物具有 Tg为20℃或更高，（ii）多价阳离子的一种或多种磷酸盐，和（iii）一种或多种碱金属磷酸盐，其用量以磷的重量计为100ppm或更多，基于所述多级聚合物的干重。在本发明的第二方面，提供了包含上述第一方面的聚合物组合物和一种或多种基质树脂的混合物。在本发明的第三方面，提供了一种制备聚合物组合物的方法，包括以下步骤：提供多级聚合物胶乳，凝结所述多级聚合物胶乳，将所述多级聚合物与碱性磷酸盐的水溶液混合，并干燥基于所述多级聚合物的干重，所述多级聚合物的含水量小于1重量％的水，其中所述干燥多段聚合物包含基于所述多段聚合物的干重为100ppm或更多的磷，所述磷是碱性磷酸盐的形式。

3. 发明授权

US08008396B2 Method of emulsion polymerization 有权
标题翻译：乳液聚合方法
公开(公告)号：US08008396B2
公开(公告)日：2011-08-30
申请号：US12384420
申请日：2009-04-02
申请人： William Douglas Rohrbach , David Lewis Zimmerman, Jr.
发明人： William Douglas Rohrbach , David Lewis Zimmerman, Jr.
IPC分类号： C08F2/32 , C08F283/00 , C08K3/20 , C08L31/00
CPC分类号： C08F2/24 , B01J19/1881 , B01J2219/0011 , B01J2219/00114 , B01J2219/00254 , C08F2/01 , F28D9/00
摘要： There is provided a process of emulsion polymerization comprising (a) adding a reactive mixture to a reaction vessel, said reactive mixture comprising water, one or more emulsifier, one or more monomer, and one or more initiator, (b) providing conditions in which said reactive mixture undergoes emulsion polymerization, and (c) passing some of the contents of said reaction vessel through a recirculating loop comprising a low-shear pump and a plate and frame heat exchanger having gap width of 6 to 18 mm, wherein more than 50% of the heat produced by said emulsion polymerization is removed from the contents of said reaction vessel by said plate and frame heat exchanger.
摘要翻译：提供了一种乳液聚合方法，其包括（a）向反应容器中加入反应性混合物，所述反应混合物包含水，一种或多种乳化剂，一种或多种单体和一种或多种引发剂，（b）提供其中所述反应性混合物经历乳液聚合，和（c）使所述反应容器的一些内容物通过包括低剪切泵和间隙宽度为6至18mm的板框式热交换器的再循环回路，其中多于50 通过所述板框式热交换器从所述反应容器的内容物中除去所述乳液聚合产生的热量的％。

4. 发明授权

US08008372B2 Polymer compositions containing phosphates 有权
标题翻译：含磷酸盐的聚合物组合物
公开(公告)号：US08008372B2
公开(公告)日：2011-08-30
申请号：US12592181
申请日：2009-11-20
申请人： William Douglas Rohrbach
发明人： William Douglas Rohrbach
IPC分类号： C08C1/08
CPC分类号： C08L51/003 , C08F2/001 , C08F257/02 , C08F265/04 , C08F279/02 , C08K3/32 , C08L51/00 , C08L51/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02
摘要： In a first aspect of the present invention, there is provided a polymer composition comprising (i) one or more multistage polymer comprising (a) a first stage polymer having Tg of 0° C. or lower, (b) a subsequent stage polymer having Tg of 20° C. or higher, (ii) one or more phosphate salt of a multivalent cation, and (iii) one or more alkaline phosphate, in the amount of 100 ppm or more, measured as the weight of phosphorous, based on the dry weight of said multistage polymer. In a second aspect of the present invention, there is provided a mixture comprising the polymer composition of the first aspect described above and one or more matrix resin.In a third aspect of the present invention, there is provided a process for making a polymer composition comprising the steps of providing a multistage polymer latex, coagulating said multistage polymer latex, mixing said multistage polymer with an aqueous solution of an alkaline phosphate, and drying said multistage polymer to a water content of less than 1% by weight of water based on the dry weight of said multistage polymer, wherein said dried multistage polymer comprises 100 ppm or more, based on the dry weight of said multistage polymer, of phosphorous that is in the form of an alkaline phosphate.
摘要翻译：在本发明的第一方面，提供一种聚合物组合物，其包含（i）一种或多种多段聚合物，其包含（a）Tg为0℃或更低的第一阶段聚合物，（b）后续聚合物具有 Tg为20℃或更高，（ii）多价阳离子的一种或多种磷酸盐，和（iii）一种或多种碱金属磷酸盐，其用量以磷的重量计为100ppm或更多，基于所述多级聚合物的干重。在本发明的第二方面，提供了包含上述第一方面的聚合物组合物和一种或多种基质树脂的混合物。在本发明的第三方面，提供了一种制备聚合物组合物的方法，包括以下步骤：提供多级聚合物胶乳，凝结所述多级聚合物胶乳，将所述多级聚合物与碱性磷酸盐的水溶液混合，并干燥基于所述多级聚合物的干重，所述多级聚合物的含水量小于1重量％的水，其中所述干燥多段聚合物包含基于所述多段聚合物的干重为100ppm或更多的磷，所述磷是碱性磷酸盐的形式。

5. 发明授权

US08877852B2 Phosphorous-containing organic polymer and compositions and processes including same 有权
标题翻译：含磷有机聚合物及其组合物及方法
公开(公告)号：US08877852B2
公开(公告)日：2014-11-04
申请号：US11998911
申请日：2007-12-03
申请人： James Charles Bohling , Matthew Stewart Gebhard , Thomas Glenn Madle , Alvin Michael Maurice , Robert Joseph Pafford, IV , William Douglas Rohrbach
发明人： James Charles Bohling , Matthew Stewart Gebhard , Thomas Glenn Madle , Alvin Michael Maurice , Robert Joseph Pafford, IV , William Douglas Rohrbach
IPC分类号： C08L43/02 , C08K9/00 , C08F2/22 , C08F230/02 , C08F220/14 , C08F220/18 , C08F220/06
CPC分类号： C08F2/22 , C08F220/06 , C08F220/14 , C08F220/18 , C08F230/02
摘要： An organic polymer including internal pendant phosphorous acid groups at a level of >0.25% phosphorus by weight based on the weight of said organic polymer, the phosphorus acid groups being separated from the backbone of the organic polymer by no more than 2 alkylene glycol units, the organic polymer having an acid number of from 100 to 1,000, and a Mw of from 1,000 to 75,000, wherein the organic polymer has been formed by emulsion polymerization from at least one ethylenically unsaturated monomer is provided. Compositions further including an emulsion polymer including from 0.05% to 2% phosphorous, present as pendant phosphorous acid groups, by weight based on the weight of the emulsion polymer, and, optionally, an inorganic particle are also provided as are processes related to the compositions.
摘要翻译：一种有机聚合物，包括基于所述有机聚合物的重量，重量百分比> 0.25重量％的内侧亚磷酸基团，磷酸基与有机聚合物的主链分开不超过2个亚烷基二醇单元，提供酸值为100至1,000，Mw为1,000至75,000的有机聚合物，其中通过至少一种烯键式不饱和单体的乳液聚合形成有机聚合物。还包括基于乳液聚合物的重量，以及任选的无机颗粒，包含以重量计，作为侧基亚磷酸基团存在的0.05％至2％的磷的乳液聚合物，以及任选的无机颗粒，。

6. 发明申请

US20080146724A1 Phosphorous-containing organic polymer and compositions and processes including same 有权
标题翻译：含磷有机聚合物及其组合物及方法
公开(公告)号：US20080146724A1
公开(公告)日：2008-06-19
申请号：US11998911
申请日：2007-12-03
申请人： James Charles Bohling , Matthew Stewart Gebhard , Thomas Glenn Madle , Alvin Michael Maurice , Robert Joseph Pafford , William Douglas Rohrbach
发明人： James Charles Bohling , Matthew Stewart Gebhard , Thomas Glenn Madle , Alvin Michael Maurice , Robert Joseph Pafford , William Douglas Rohrbach
IPC分类号： C08L43/02
CPC分类号： C08F2/22 , C08F220/06 , C08F220/14 , C08F220/18 , C08F230/02
摘要： An organic polymer including internal pendant phosphorous acid groups at a level of >0.25% phosphorus by weight based on the weight of said organic polymer, the phosphorus acid groups being separated from the backbone of the organic polymer by no more than 2 alkylene glycol units, the organic polymer having an acid number of from 100 to 1,000, and a Mw of from 1,000 to 75,000, wherein the organic polymer has been formed by emulsion polymerization from at least one ethylenically unsaturated monomer is provided. Compositions further including an emulsion polymer including from 0.05% to 2% phosphorous, present as pendant phosphorous acid groups, by weight based on the weight of the emulsion polymer, and, optionally, an inorganic particle are also provided as are processes related to the compositions.
摘要翻译：一种有机聚合物，包括基于所述有机聚合物的重量，重量百分比> 0.25重量％的内侧亚磷酸基团，磷酸基与有机聚合物的主链分开不超过2个亚烷基二醇单元，提供酸值为100至1,000，Mw为1,000至75,000的有机聚合物，其中通过至少一种烯键式不饱和单体的乳液聚合形成有机聚合物。还包括基于乳液聚合物的重量，以及任选的无机颗粒，包含以重量计，作为侧基亚磷酸基团存在的0.05％至2％的磷的乳液聚合物，以及任选的无机颗粒，。

7. 发明授权

US06784213B2 Method for preparation of strong acid cation exchange resins 有权
标题翻译：强酸阳离子交换树脂的制备方法
公开(公告)号：US06784213B2
公开(公告)日：2004-08-31
申请号：US10158664
申请日：2002-05-30
申请人： William Douglas Rohrbach , Bruce Maurice Rosenbaum
发明人： William Douglas Rohrbach , Bruce Maurice Rosenbaum
IPC分类号： C08F834
CPC分类号： B01J39/20 , C02F2001/427 , C02F2101/101 , C08F8/36 , C08J5/20 , C08F212/08 , C08F212/36
摘要： An improved process for preparing strong acid cation exchange resins by sulfonation of wet crosslinked copolymer in the absence of organic swelling solvents is disclosed. This process involves dewatering a crosslinked poly(vinylaromatic) copolymer to selected residual moisture levels of 3 to 35%, followed by non-solvent sulfonation, to provide strong acid cation exchange resins having enhanced physical stability and that are free of chlorinated-solvent contaminants.
摘要翻译：公开了通过在不存在有机溶胀溶剂的情况下磺化湿交联共聚物制备强酸阳离子交换树脂的改进方法。该方法包括将交联的聚（乙烯基芳族化合物）共聚物脱水至3至35％的选定残余水分含量，然后进行非溶剂磺化，以提供具有增强的物理稳定性且不含氯化溶剂污染物的强酸阳离子交换树脂。

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