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    • 1. 发明授权
    • Aqueous acidic solutions for the electrodeposition of tin and lead/tin
alloys
    • 用于电沉积锡和铅/锡合金的酸性水溶液
    • US5021130A
    • 1991-06-04
    • US469066
    • 1990-01-23
    • Willi MetzgerManfred SchmitzKarl-Jurgen Schmidt
    • Willi MetzgerManfred SchmitzKarl-Jurgen Schmidt
    • C25D3/32C25D3/56C25D3/60
    • C25D3/32C25D3/56C25D3/60
    • Described are aqueous acidic solutions for the electrodeposition of tin and lead/tin alloys for improving electro- deposition in the high current density range and for providing a uniform luster distribution of metals deposited in the low current density range. The solutions contain a mixture of metal salts, free alkanesulfonic acid, a non-ionic wetting agent and optionally aromatic short-chain aldehydes and/or optionally aromatic ketones and/or optionally short-chain unsaturated carboxylic acids. In the solutions, tin and/or lead salts of the alkanesulfonic acid are employed as the metal salt(s), the alkyl moiety of the alkanesulfonic acid consisting of from 1 to 5 carbon atoms, the free alkanesulfonic acid having alkyl moieties with from 1 to 5 carbon atoms. They contain, as a further brightener, a mixture comprising a reaction product of acetaldehyde and/or its aidol condensation product with ammonia and/or acyclic ketones and/or aliphatic amines, amides, amino acids and or hydrazine compounds.
    • 描述了用于电沉积锡和铅/锡合金的酸性水溶液,用于改善在高电流密度范围内的电沉积,并提供在低电流密度范围内沉积的金属的均匀光泽分布。 溶液含有金属盐,游离烷基磺酸,非离子润湿剂和任选的芳族短链醛和/或任选的芳族酮和/或任选的短链不饱和羧酸的混合物。 在该溶液中,使用烷基磺酸的锡和/或铅盐作为金属盐,由1至5个碳原子组成的烷基磺酸的烷基部分,具有烷基部分的游离烷基磺酸具有1 至5个碳原子。 它们作为另外的增白剂包含包含乙醛和/或其辅助缩合产物与氨和/或无环酮和/或脂族胺,酰胺,氨基酸和/或肼化合物的反应产物的混合物。