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1. 发明申请

US20080200525A1 PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES 失效
公开(公告)号：US20080200525A1
公开(公告)日：2008-08-21
申请号：US12098594
申请日：2008-04-07
申请人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
发明人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
IPC分类号： A01N43/40 , C07C233/02 , C07C259/00 , A01N37/18 , A01N33/24 , A01N43/80 , C07D261/02 , A01P17/00 , C07D211/82
CPC分类号： C07D333/58 , A01N33/24 , A01N35/10 , A01N37/52 , A01N41/06 , A01N43/10 , A01N43/40 , A01N43/78 , A01N43/80 , C07C49/753 , C07C49/755 , C07C49/84 , C07C235/84 , C07C251/44 , C07C251/48 , C07C251/54 , C07C251/58 , C07C311/04 , C07C311/05 , C07C311/09 , C07C323/47 , C07D213/50 , C07D213/53 , C07D213/61 , C07D213/64 , C07D261/08 , C07D277/24 , C07D277/28 , C07D307/52 , C07D307/81 , C07D333/22
摘要： Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.

2. 发明申请

US20100016383A1 4-(3,3-DIHALO-ALLYLOXY)PHENOL DERIVATIVES HAVING PESTICIDAL PROPERTIES 审中-公开
标题翻译：具有农药性质的4-（3,3-DIHALO-ALLYLOXY）苯酚衍生物
公开(公告)号：US20100016383A1
公开(公告)日：2010-01-21
申请号：US12564995
申请日：2009-09-23
申请人： Werner Zambach , Arthur Steiger , Peter Renold , Stephan Trah , Roger Graham Hall
发明人： Werner Zambach , Arthur Steiger , Peter Renold , Stephan Trah , Roger Graham Hall
IPC分类号： A01N43/836 , C07D207/30 , A01N43/36 , C07D257/04 , A01N43/713 , C07D271/06 , C07D261/06 , A01N43/80 , C07D277/20 , A01N43/78 , C07D249/08 , A01N43/653 , A01P15/00
CPC分类号： C07D207/325 , A01N43/36 , A01N43/56 , A01N43/653 , A01N43/713 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/82 , A01N43/90 , A01N47/18 , A01N47/20 , C07D207/333 , C07D207/34 , C07D231/12 , C07D231/22 , C07D231/38 , C07D249/08 , C07D249/10 , C07D257/04 , C07D261/08 , C07D261/10 , C07D261/18 , C07D263/32 , C07D263/34 , C07D271/06 , C07D271/07 , C07D277/24 , C07D277/30 , C07D277/40 , C07D277/48 , C07D277/56 , C07D285/08 , C07D285/12 , C07D333/16 , C07D333/38 , C07D471/04
摘要： Compounds of formula wherein A0 is a bond or a C1-C6alkylene bridge; A1, A2 and A3 are a C1-C6alkylene bridge; D is CH or N; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is a bond or, for example, O, NH, S, SO or SR2; Q is, for example, O, S, SO or SO2; Y is, for example, O, S, SO or SO2; X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN or nitro; R4 is, for example, H, halogen, OH, SH, CN, nitro or C1-C6alkyl; R5 is, for example, H, CN, OH, C1-C6alkyl or C3-C8cycloalkyl; k is 1, 2 or 3 when D is nitrogen; or is 1, 2, 3 or 4 when D is CH; m is 1 or 2; E is heteroaryl which is unsubstituted or substituted—depending upon the substitutions possible on the ring—by from one to four identical or different substituents selected from R10; and R10 is, for example, halogen, CN, NO2, OH, SH or C1-C6alkyl; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
摘要翻译：式中的化合物其中A 0是一个键或一个C 1 -C 6亚烷基桥; A1，A2和A3是C1-C6亚烷基桥; D是CH或N; W是例如O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; T是键或例如O，NH，S，SO或SR2; Q是例如O，S，SO或SO 2; Y是例如O，S，SO或SO 2; X1和X2各自独立地为氟，氯或溴; R1，R2和R3是例如H，卤素，OH，SH，CN或硝基; R4是例如H，卤素，OH，SH，CN，硝基或C1-C6烷基; R5是例如H，CN，OH，C1-C6烷基或C3-C8环烷基; 当D为氮时，k为1,2或3; 或当D为CH时为1,2,3或4; m为1或2; E是未被取代或被取代的杂芳基，这取决于环上通过1-4个相同或不同的选自R 10的取代基取代的取代基; R 10为例如卤素，CN，NO 2，OH，SH或C 1 -C 6烷基; 在适用情况下，它们可能的E / Z异构体，E / Z异构体混合物和/或互变异构体，在每种情况下为游离形式或盐形式，制备这些化合物及其用途的方法，其中从这些化合物或其农业化学上可接受的盐中选择活性成分，制备这些组合物的方法及其用途，用这些组合物处理的植物繁殖材料以及防治害虫的方法。

3. 发明申请

US20090298898A1 PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES 审中-公开
标题翻译：杀虫活性酮和氧化衍生物
公开(公告)号：US20090298898A1
公开(公告)日：2009-12-03
申请号：US12533302
申请日：2009-07-31
申请人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
发明人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
IPC分类号： A01N43/80 , C07C233/02 , C07C249/02 , C07D261/06 , A01N37/18 , A01N33/02 , A01P7/00
CPC分类号： C07D333/58 , A01N33/24 , A01N35/10 , A01N37/52 , A01N41/06 , A01N43/10 , A01N43/40 , A01N43/78 , A01N43/80 , C07C49/753 , C07C49/755 , C07C49/84 , C07C235/84 , C07C251/44 , C07C251/48 , C07C251/54 , C07C251/58 , C07C311/04 , C07C311/05 , C07C311/09 , C07C323/47 , C07D213/50 , C07D213/53 , C07D213/61 , C07D213/64 , C07D261/08 , C07D277/24 , C07D277/28 , C07D307/52 , C07D307/81 , C07D333/22
摘要： Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
摘要翻译：下式化合物其中A0，A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥，其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O，S，SO或SO 2; M为O或NOR6，X1和X2各自独立地为氟，氯或溴; R1，R2和R3是例如H，卤素，OH，SH，CN，硝基，C1-C6烷基，C1-C6卤代烷基，C1-C6烷基羰基，C2-C6链烯基，C2-C6卤代烯基或C2-C6炔基; Q是例如O，S，SO或SO 2; W是例如O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; T是例如键O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; D是CH或N; R4是例如H，卤素，OH，SH，CN，硝基，C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基，C3-C8环烷基或-N（R7）2; R 7是H，C 1 -C 6烷基，C 1 -C 3卤代烷基，C 1 -C 6烷基羰基，C 1 -C 3卤代烷基羰基，C 1 -C 6烷氧基羰基，C 3 -C 8环烷基，C 3 -C 8环烷基羰基或甲酰基; k为0，1，2，3或4; m为1或2; q为0,1或2; 在适用情况下，它们可能的E / Z异构体，E / Z异构体混合物和/或互变异构体，在每种情况下为游离形式或盐形式，制备这些化合物及其用途的方法，其中已经从这些化合物和农业化学上可接受的盐中选择活性成分，以及这些组合物的制备方法及其用途，用这些组合物处理的繁殖材料以及控制害虫的方法。

4. 发明授权

US07569727B2 Pesticidally active ketone and oxime derivatives 失效
标题翻译：杀虫活性酮和肟衍生物
公开(公告)号：US07569727B2
公开(公告)日：2009-08-04
申请号：US12098594
申请日：2008-04-07
申请人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
发明人： Werner Zambach , Roger Graham Hall , Peter Renold , Stephan Trah
IPC分类号： C07C251/32 , C07D213/24 , A01N33/24 , A01N43/40
CPC分类号： C07D333/58 , A01N33/24 , A01N35/10 , A01N37/52 , A01N41/06 , A01N43/10 , A01N43/40 , A01N43/78 , A01N43/80 , C07C49/753 , C07C49/755 , C07C49/84 , C07C235/84 , C07C251/44 , C07C251/48 , C07C251/54 , C07C251/58 , C07C311/04 , C07C311/05 , C07C311/09 , C07C323/47 , C07D213/50 , C07D213/53 , C07D213/61 , C07D213/64 , C07D261/08 , C07D277/24 , C07D277/28 , C07D307/52 , C07D307/81 , C07D333/22
摘要： Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.
摘要翻译：下式化合物其中A0，A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥，其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O，S，SO或SO 2; M为O或NOR6，X1和X2各自独立地为氟，氯或溴; R1，R2和R3是例如H，卤素，OH，SH，CN，硝基，C1-C6烷基，C1-C6卤代烷基，C1-C6烷基羰基，C2-C6链烯基，C2-C6卤代烯基或C2-C6炔基; Q是例如O，S，SO或SO 2; W是例如O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; T是例如键O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; D是CH或N; R4是例如H，卤素，OH，SH，CN，硝基，C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基，C3-C8环烷基或-N（R7）2; R 7是H，C 1 -C 6烷基，C 1 -C 3卤代烷基，C 1 -C 6烷基羰基，C 1 -C 3卤代烷基羰基，C 1 -C 6烷氧基羰基，C 3 -C 8环烷基，C 3 -C 8环烷基羰基或甲酰基; k为0，1，2，3或4; m为1或2; q为0,1或2; 在适用情况下，它们可能的E / Z异构体，E / Z异构体混合物和/或互变异构体，在每种情况下为游离形式或盐形式，制备这些化合物及其用途的方法，其中已经从这些化合物和农业化学上可接受的盐中选择活性成分，以及这些组合物的制备方法及其用途，用这些组合物处理的繁殖材料以及控制害虫的方法。

5. 发明授权

US07414064B2 4-(3,3-dihalo-allyloxy) phenoxy alkyl derivatives 失效
公开(公告)号：US07414064B2
公开(公告)日：2008-08-19
申请号：US11675149
申请日：2007-02-15
申请人： Werner Zambach , Peter Renold , Arthur Steiger , Stephan Trah , Roger Graham Hall
发明人： Werner Zambach , Peter Renold , Arthur Steiger , Stephan Trah , Roger Graham Hall
IPC分类号： A61K31/44 , A61K31/4427 , C07D401/12 , C07D403/12 , C07D213/60
CPC分类号： C07D207/27 , C07C217/84 , C07C233/25 , C07C233/29 , C07C233/75 , C07C271/28 , C07D207/325 , C07D207/444 , C07D207/452 , C07D263/22 , C07D307/68 , C07D333/38
摘要： Compounds of formula wherein A1, A2 and A3 are each independently of the others a bond or a C1-C6alkylene bridge; A4 is a C1-C6alkylene bridge; D is CH or N; W is, for example, O, NR7 or S; T is, for example, a bond, O, NH or NR7; Q is O, NR7, S, SO or SO2; Y is O, NR7, S, SO or SO2; X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl or C2-C6alkenyl; R4 is, for example, H, halogen, CN, nitro or C1-C6alkyl; R5 and R6 are, for example, H, CN, OH, C1-C6alkyl, C3-C8cycloalkyl, C3-C8cycloalkyl-C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy or C1-C6haloalkoxy; R7 is H, C1-C6alkyl, C1-C6alkoxyalkyl or C1-C6alkylcarbonyl; k, when D is nitrogen, is 1, 2 or 3; or, when D is CH, is 1, 2, 3 or 4; and m is 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.

6. 发明授权

US07192965B2 4-(3,3-dihalo-allyloxy)phenoxy alkyl derivatives 失效
公开(公告)号：US07192965B2
公开(公告)日：2007-03-20
申请号：US10518888
申请日：2003-06-27
申请人： Werner Zambach , Peter Renold , Arthur Steiger , Stephan Trah , Roger Graham Hall
发明人： Werner Zambach , Peter Renold , Arthur Steiger , Stephan Trah , Roger Graham Hall
IPC分类号： A01N33/02 , C07C333/00 , C07C69/76 , C07C327/00 , C07C325/00 , C07C49/23 , C07D319/02
CPC分类号： C07D207/27 , C07C217/84 , C07C233/25 , C07C233/29 , C07C233/75 , C07C271/28 , C07D207/325 , C07D207/444 , C07D207/452 , C07D263/22 , C07D307/68 , C07D333/38
摘要： Compounds of formula wherein A1, A2 and A3 are each independently of the others a bond or a C1–C6alkylene bridge; A4 is a C1–C6alkylene bridge; D is CH or N; W is, for example, O, NR7 or S; T is, for example, a bond, O, NH or NR7; Q is O, NR7, S, SO or SO2; Y is O, NR7, S, SO or SO2; X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, CN, nitro, C1–C6alkyl, C1–C6haloalkyl, C1–C6alkylcarbonyl or C2–C6alkenyl; R4 is, for example, H, halogen, CN, nitro or C1–C6alkyl; R5 and R6 are, for example, H, CN, OH, C1–C6alkyl, C3–C8cycloalkyl, C3–C8cycloalkyl-C1–C6alkyl, C1–C6haloalkyl, C1–C6alkoxy or C1–C6haloalkoxy; R7 is H, C1–C6alkyl, C1–C6alkoxyalkyl or C1–C6alkylcarbonyl; k, when D is nitrogen, is 1, 2 or 3; or, when D is CH, is 1, 2, 3 or 4; and m is 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.

7. 发明授权

US07812170B2 Insecticides 有权
标题翻译：杀虫剂
公开(公告)号：US07812170B2
公开(公告)日：2010-10-12
申请号：US10598041
申请日：2005-03-02
申请人： David John Hughes , James Edward Peace , Suzanna Riley , Sally Russell , Joseph John Swanborough , Roger Graham Hall , André Jeanguenat , Olivier Loiseleur , Peter Renold , Stephan Trah , Jean Wenger
发明人： David John Hughes , James Edward Peace , Suzanna Riley , Sally Russell , Joseph John Swanborough , Roger Graham Hall , André Jeanguenat , Olivier Loiseleur , Peter Renold , Stephan Trah , Jean Wenger
IPC分类号： C07D401/00
CPC分类号： C07D401/04 , A01N37/46 , A01N43/40 , A01N43/56 , C07D401/14 , C07D405/14 , C07D409/14 , C07D413/14 , C07D417/14 , C07D491/04 , C07D493/08 , C07D495/04 , C07D513/04
摘要： Compounds of the formula (I) in which Z, is an oxygen atom; or a sulfur atom; Z2 is an oxygen atom; or a sulfur atom; R, is an aryl or heteroaryl group, which is unsubstituted or substituted; R2 is hydrogen; or an organic substituent; R3 is hydrogen; or an organic substituent; R4 is hydrogen; or an organic substituent; or R3 and R4, taken together, form, together with the nitrogen atom, to which they are attached, a ring, which is unsubstituted or substituted; R5 is hydrogen; or an unsubstituted or substituted alkyl group; or forms, taken together with R8 or with a monovalent substituent attached to that atom of R6, via which atom R6 is directly connected with the carbon atom, shown in the formula I, which carries R5, one additional bond; R6 and R7, taken together, form, together with the two carbon atoms, shown in the formula I, to which atoms they are attached, a bicyclic ring system, which ring system is carbocyclic or heterocyclic, which ring system is substituted, in the manner shown in the formula I, by the four substituents —N(R2)-C(═Z1)-R, —C(═Z2)-N(R3)-R4, R5 and R8, and which ring system is optionally further substituted; and R8 is hydrogen; or an unsubstituted or substituted alkyl group; or forms, taken together with R5 or with a monovalent substituent attached to that atom of R7, via which atom R7 is directly connected with the carbon atom, shown in the formula I, which carries R8, one additional bond, and, where appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中Z为氧原子的式（I）化合物; 或硫原子; Z2是氧原子; 或硫原子; R 1是未取代或取代的芳基或杂芳基; R2是氢; 或有机取代基; R3是氢; 或有机取代基; R4是氢; 或有机取代基; 或者R 3和R 4一起与它们所连接的氮原子一起形成未被取代或被取代的环， R5是氢; 或未取代或取代的烷基; 或其形式，与R8一起或与R6的该原子连接的一价取代基，其中原子R6直接与碳原子连接，如式I所示，其携带R5，另外一个键; R6和R7一起与式I中所示的两个碳原子一起形成，其中它们连接的原子是双环系统，该环系是碳环或杂环的，该环系被取代，在式（I）所示的四种取代基-N（R 2）-C（= Z 1）-R，-C（= Z 2）-N（R 3）-R 4，R 5和R 8，取代 R8是氢; 或未取代或取代的烷基; 或其形式与R5一起或与R7的原子连接的一价取代基，其中原子R7与碳原子直接连接，如式I所示，其携带R8，一个附加键，并且在适当的情况下，互变异构体，以游离形式或盐形式，可以用作农业化学活性成分，并且可以以本身已知的方式制备。

8. 发明授权

US07608631B2 4-(3,3-dihalo-allyloxy) phenol derivatives having pesticidal properties 失效
标题翻译：具有杀虫特性的4-（3,3-二卤代烯丙氧基）苯酚衍生物
公开(公告)号：US07608631B2
公开(公告)日：2009-10-27
申请号：US10525891
申请日：2003-08-29
申请人： Wemer Zambach , Arthur Steiger , Peter Renold , Stephan Trah , Roger Graham Hall
发明人： Wemer Zambach , Arthur Steiger , Peter Renold , Stephan Trah , Roger Graham Hall
IPC分类号： A01N43/40
CPC分类号： C07D207/325 , A01N43/36 , A01N43/56 , A01N43/653 , A01N43/713 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/82 , A01N43/90 , A01N47/18 , A01N47/20 , C07D207/333 , C07D207/34 , C07D231/12 , C07D231/22 , C07D231/38 , C07D249/08 , C07D249/10 , C07D257/04 , C07D261/08 , C07D261/10 , C07D261/18 , C07D263/32 , C07D263/34 , C07D271/06 , C07D271/07 , C07D277/24 , C07D277/30 , C07D277/40 , C07D277/48 , C07D277/56 , C07D285/08 , C07D285/12 , C07D333/16 , C07D333/38 , C07D471/04
摘要： Compounds of formula (I) wherein Ao is a bond or a C1-C6alkylene bridge; A1, A2 and A3 are a C1-C6alkylene bridge; D is CH or N; W is, for example, O, S, SO, S02, —C(═O)—O— or —O—C(═O)—; T is a bond or, for example, O, NH, S, SO or SR2; Q is, for example, O, S, SO or SO2; Y is, for example, O, S, SO or SO2; X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN or nitro; R4 is, for example, H, halogen, OH, SH, CN, nitro or C1-C6alkyl; R5 is, for example, H, CN, OH, C1-C6alkyl or C3-C8cycloalkyl; k is 1, 2 or 3 when D is nitrogen; or is 1, 2, 3 or 4 when D is CH; m is 1 or 2; E is heteroaryl which is unsubstituted or substituted—depending upon the substitutions possible on the ring—by from one to four identical or different substituents selected from R10; and R10 is, for example, halogen, CN, NO2, OH, SH or C1-C6alkyl; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof, a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
摘要翻译：式（I）的化合物，其中Ao是一个键或C1-C6亚烷基桥; A1，A2和A3是C1-C6亚烷基桥; D是CH或N; W是例如O，S，SO，SO 2，-C（-O）-O-或-O-C（-O） - ; T是键或例如O，NH，S，SO或SR2; Q是例如O，S，SO或SO 2; Y是例如O，S，SO或SO 2; X1和X2各自独立地为氟，氯或溴; R1，R2和R3是例如H，卤素，OH，SH，CN或硝基; R4是例如H，卤素，OH，SH，CN，硝基或C1-C6烷基; R5是例如H，CN，OH，C1-C6烷基或C3-C8环烷基; 当D为氮时，k为1,2或3; 或D为CH时为1,2,3或4; m为1或2; E是未被取代或被取代的杂芳基，这取决于环上通过1-4个相同或不同的选自R 10的取代基取代的取代基; R 10为例如卤素，CN，NO 2，OH，SH或C 1 -C 6烷基; 在适用情况下，它们可能的E / Z异构体，E / Z异构体混合物和/或互变异构体，在每种情况下为游离形式或盐形式，制备这些化合物及其用途的方法，其中从这些化合物或其农业化学上可接受的盐中选择活性成分，制备这些组合物的方法及其用途，用这些组合物处理的植物繁殖材料以及控制害虫的方法。

9. 发明申请

US20060128670A1 Pesticidally active ketone and oxime derivatives 审中-公开
公开(公告)号：US20060128670A1
公开(公告)日：2006-06-15
申请号：US10560292
申请日：2004-06-22
申请人： Werner Zambach , Roger Hall , Peter Renold , Stephan Trah
发明人： Werner Zambach , Roger Hall , Peter Renold , Stephan Trah
IPC分类号： C07F9/06 , A01N57/00 , A01N37/28 , C07F9/28
CPC分类号： C07D333/58 , A01N33/24 , A01N35/10 , A01N37/52 , A01N41/06 , A01N43/10 , A01N43/40 , A01N43/78 , A01N43/80 , C07C49/753 , C07C49/755 , C07C49/84 , C07C235/84 , C07C251/44 , C07C251/48 , C07C251/54 , C07C251/58 , C07C311/04 , C07C311/05 , C07C311/09 , C07C323/47 , C07D213/50 , C07D213/53 , C07D213/61 , C07D213/64 , C07D261/08 , C07D277/24 , C07D277/28 , C07D307/52 , C07D307/81 , C07D333/22
摘要： Compounds of formula (I), wherein A0, A1, and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, 0, S, SO or S02; M is 0 or NOR6, X1, and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6halealkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, 0, S, SO, SO2, —C(═O)—O— or -0—C(═O)—; T is, for example, a bond, 0, S, SO, S02, —C(═O)—O or -0-C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8Cycloalkyl, C3-C8 cycloalkyl-carbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.

10. 发明申请

US20060014806A1 Dihalo-allyloxy-phenol derivatives having pesticidal activity 审中-公开
公开(公告)号：US20060014806A1
公开(公告)日：2006-01-19
申请号：US10537444
申请日：2003-12-10
申请人： Werner Zambach , Peter Renold , Stephan Trah , Poger Hall
发明人： Werner Zambach , Peter Renold , Stephan Trah , Poger Hall
IPC分类号： C07D213/42
CPC分类号： A01N37/34 , C07C43/225 , C07C43/23 , C07C43/315 , C07C45/29 , C07C45/71 , C07C49/255 , C07C69/76 , C07C205/32 , C07C251/40 , C07C255/37 , C07C255/41 , C07C271/16 , C07C2601/02 , C07D213/57 , C07D261/08 , C07D307/54 , C07D307/81 , C07D333/24 , C07C49/84
摘要： Compounds of formula (I), wherein A1 and A2 are each independently of the other a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge; X1 and X2 are each independently of the other fluorine, chlorine or bromine; Y is O, NR7, S, SO or SO2; R1, R2 and R3 are each independently of the others, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl or C2-C6alkenyl; Q is O, NR5, S, SO or SO2; W is, for example, O, NR5 or SO; T is for example, a bond, O or NR5; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN or nitro; R5 and R7 are, for example, H, C1-C6alkyl or C1-C3haloalkyl; k is 1, 2, 3 or 4; m is 1 or 2; R10 is a radical which contains 0, N or S; R11 is, for example, H, C1-C12alkyl or a radical which contains from one to three hetero atoms selected from O, N and S; or R11 together with R12 is a bond; R12 is, for example, H, C1-C6alkyl, halo-C1-C6alkyl or C1-C6alkoxy-C1-C6-alkyl; and, where applicable, their possible E/Z isomeric mixtures isomers, EQ isomeric mixtures and/or tautomers, in each case in free from or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof; a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.

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