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    • 9. 发明授权
    • Pesticidal triazine-derivatives
    • 杀虫三嗪衍生物
    • US06723720B2
    • 2004-04-20
    • US10006954
    • 2001-11-05
    • Arthur SteigerWerner ZambachAndré JeanguenatMartin EberleStephan TrahSaleem Farooq
    • Arthur SteigerWerner ZambachAndré JeanguenatMartin EberleStephan TrahSaleem Farooq
    • C07D253065
    • A01N57/22A01N43/707C07D253/07
    • A compound of formula wherein R1 is unsubstituted or substituted aryl or heteroaryl, the substituents of the aryl and heteroaryl rings being selected, for example, from the group consisting of OH, halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6alkyl-C3-C8cycloalkyl, C3-C8cycloalkyl-C1-C6alkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy and phenyl; phenoxy; phenylthio; phenylamino; and phenyl-(C1-C6alkyl)-amino; the substituents of the phenoxy, phenylthio, phenylamino and phenyl-(C1-C6alkyl)-amino groups being selected from the group consisting of halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy, C3-C8cycloalkoxy, C1-C6alkylthio, C3-C8cycloalkylthio, C1-C6haloalkylthio and C3-C8halocycloalkylthio; R2 is, for example, H, OH, halogen, CN, NO2, C1-C6alkyl or C1-C6alkoxy; A is, for example, a single bond, C1-C12alkylene, O or O(C1-C12alkylene); R4 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C1-C6alkoxy, N(R5)2 or C1-C6alkoxy-C2-C6alkyl; R5 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl or aryl-C1-C6alkyl; X1 is R10; X2 and X3 are each independently of the other H or R10; R10 is, for example, halogen, CN, NO2, C1-C6alkyl or C3-C8cycloalkyl; and n is 0, 1 or 2, and to their physiologically tolerable and agrochemically acceptable addition compounds, and where appropriate to E/Z isomers, to mixtures of E/Z isomers and/or to tautomers, in each case in free form or in salt form. The compounds, in free form or in agrochemically acceptable salt form, exhibit advantageous pesticidal properties. They are suitable especially in the control of pests in agriculture and stored goods and also in the keeping of domestic animals.
    • 化合物R1是未取代或取代的芳基或杂芳基,芳基和杂芳基环的取代基选自例如由OH,卤素,CN,NO 2,C 1 -C 6烷基,C 3 -C 8环烷基,C 1 -C 6烷基 - C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基,C 3 -C 8卤代环烷基,C 1 -C 6烷氧基和苯基; 苯氧基 苯硫基 苯基氨基; 苯基 - (C 1 -C 6烷基) - 氨基;苯氧基,苯硫基,苯基氨基和苯基 - (C 1 -C 6烷基) - 氨基的取代基选自卤素,CN,NO 2,C 1 -C 6烷基, C 3 -C 8卤代烷基,C 1 -C 6卤代烷基,C 3 -C 8卤代环烷基,C 1 -C 6烷氧基,C 3 -C 8环烷氧基,C 1 -C 6烷硫基,C 3 -C 8环烷硫基,C 1 -C 6卤代烷硫基和C 3 -C 8卤代环烷硫基; R 2为例如H,OH,卤素,CN, C1-C6烷基或C1-C6烷氧基; A是例如单键,C1-C12亚烷基,O或O(C1-C12亚烷基); R4是H,C1-C6烷基,C3-C8环烷基,C1-C6卤代烷基,C1-C6烷氧基 ,N(R 5)2或C 1 -C 6烷氧基-C 2 -C 6烷基; R 5是H,C 1 -C 6烷基,C 3 -C 8环烷基,C 1 -C 6卤代烷基或芳基-C 1 -C 6烷基; X 1是R 10; X 2和X 3各自独立地为H或R 10; R 10为例如卤素,CN,NO 2,C 1 -C 6烷基或C 3 -C 8环烷基; 和n为0,1或2,以及其生理上可耐受和农业化学上可接受的加成化合物,以及适用于E / Z异构体的E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 游离形式或农业化学上可接受的盐形式的化合物表现出有利的杀虫性质。 它们特别适用于控制农业和储存物中的害虫以及保存家畜。
    • 10. 发明授权
    • Pesticidal pyrimidine-derivatives
    • 杀虫嘧啶衍生物
    • US06686469B2
    • 2004-02-03
    • US10011012
    • 2001-11-05
    • Martin EberleAndré JeanguenatWerner ZambachArthur SteigerSaleem Farooq
    • Martin EberleAndré JeanguenatWerner ZambachArthur SteigerSaleem Farooq
    • C07D2412
    • C07D239/26A01N43/54C07D239/28C07D239/34C07D239/36C07D239/42C07D239/54
    • The invention relates to compounds of the general formula wherein R1 is unsubstituted or mono- to penta-substituted aryl, whereby the substituents are selected from the group consisting for instance of OH, Halogen, CN, C1-C6-alkyl, optionally substituted C3-C8-cycloalkyl and optionally substituted C3-C8-cycloalkenyl; A is for instance a single bond, C1-C12-alkylene or O; X1 and X2, independently of one another, are R10; X3 is H or R10; R10 is for instance halogen, CN, NO2, C1-C6-alkyl, C3-C8-cycloalkyl or C1-C6-haloalkyl; R21 and R22, independently of one another are for instance H, halogen, CN, NO2, OH, SH, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-alkyl-C3-C8-cycloalkyl or C3-C8-cycloalkyl-C1-C6-alkyl; R23 and R24, independently of one another, are for instance H, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C6-alkyl, C1-C6-haloalkyl or C3-C8-halocycloalkyl; m is 1, 2, 3 or 4; and n is 0, 1 or 2; as well as the physiologically acceptable addition compounds, a method of producing these compounds and the usage of these compounds, pesticide compositions whose active ingredient is chosen from these compounds, each in free form or in agrochemically employable salt form, and a method of producing and using these compositions. The active ingredients, in free form or in agrochemically employable salt form, have advantageous pesticidal properties. The are especially suitable for the control of pests in agriculture and in storage, as well as in the care of domestic animals.
    • 本发明涉及通式为化学式R 1的化合物是未取代的或一至五取代的芳基,其中取代基选自例如OH,卤素,CN,C 1 -C 6 - 烷基,任选取代的C 3 -C 8 - 环烷基和任选取代的C 3 -C 8 - 环烯基; A为例如单键,C 1 -C 12 - 亚烷基或O; X 1和X 2彼此独立地为R 10; X3为H或R10; R10为卤素,CN,NO2,C1-C6-烷基,C3-C8-环烷基或C1-C6-卤代烷基; R21和R22彼此独立地为例如H,卤素,CN ,NO 2,OH,SH,C 1 -C 6烷基,C 3 -C 8 - 环烷基,C 1 -C 6烷基-C 3 -C 8 - 环烷基或C 3 -C 8环烷基-C 1 -C 6烷基; R 23和R 24独立地为 另一个例子是H,C 1 -C 6烷基,C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基或C 3 -C 8卤代环烷基; m是1,2,3 或4; 和n为0,1或2;以及生理上可接受的加成化合物,这些化合物的制备方法和这些化合物的用途,其活性成分选自这些化合物的农药组合物,各自为游离形式或农业化学可使用的盐 形式,以及生产和使用这些组合物的方法。 活性成分,游离形式或具有农业化学应用的盐形式,具有有利的杀虫特性。 特别适用于农业,仓储以及家畜照顾中的害虫控制。