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    • 2. 发明授权
    • Organosiloxanes useful in molding compositions based on unsaturated
polyesters and unsaturated monomers
    • 有机硅氧烷可用于基于不饱和聚酯和不饱和单体的模塑组合物
    • US4120837A
    • 1978-10-17
    • US794996
    • 1977-05-09
    • Werner SchaferHans-Albrecht ScholzSiegfried Wilhelm
    • Werner SchaferHans-Albrecht ScholzSiegfried Wilhelm
    • C08L67/00C08K3/26C08K3/34C08K5/09C08K5/54C08K5/5419C08L67/06
    • C08K5/54C08K3/18C08K9/12
    • Molding compositions, based on unsaturated polyester resins, unsaturated monomers, catalysts, inorganic and/or organic fillers and/or reinforcing agents, dyestuffs and/or pigments, lubricants and optionally inhibitors, containing a siloxane of the formula ##STR1## wherein A IS 0 OR 1b is a number from 1 to 500, provided that when a is 0, b must be equal to or greater than 3 and the compound is a cyclosiloxane,R.sup.1 is hydrogen, alkyl or trimethylsilyl,R.sup.2 is alkyl of 8 to 32 carbon atoms, --R.sup.4 OCOR.sup.5, or --R.sup.4 OR.sup.6, where R.sup.4 is a bivalent radical, R.sup.5 is alkyl of 12 to 22 carbon atoms and R.sup.6 is alkyl of 8 to 22 carbon atoms, provided that up to 80 mole % of the above-mentioned radicals defining R.sup.2 may be methyl and provided further that at least one R.sup.2 per molecule is other than methyl, andR.sup.3 is methyl or alkoxy of 1 to 4 carbon atoms, and/or a carboxysiloxane as an eternal and/or internal lubricant, optionally together with an additional external and/or internal lubricant.
    • 含有下式的硅氧烷(I)的基于不饱和聚酯树脂,不饱和单体,催化剂,无机和/或有机填料和/或增强剂,染料和/或颜料,润滑剂和任选的抑制剂的成型组合物,其中 A 0或1 B为1至500的数字,当A为0时,B必须等于或大于3,化合物为环硅氧烷,R1为氢,烷基或三甲基甲硅烷基,R2为烷基8 至32个碳原子,-R4OCOR5或-R4OR6,其中R4是二价基团,R5是12-22个碳原子的烷基,R6是8-22个碳原子的烷基,条件是高达80% 上述定义R 2的基团可以是甲基,并进一步提供每个分子至少一个R 2不是甲基,R 3是甲基或1至4个碳原子的烷氧基,和/或作为永久和/或内部润滑剂的羧基硅氧烷,任选地 以及额外的外部和/或内部润滑剂。
    • 10. 发明授权
    • Backing sheet for the weathering-proof coating of thin, plane backing in
continuous presses without recooling
    • 背衬板用于连续压机中的薄平面背衬的耐候性涂层,无需再冷却
    • US4579776A
    • 1986-04-01
    • US638865
    • 1984-08-07
    • Jurgen FockWerner SchaferDietmar Schedlitzki
    • Jurgen FockWerner SchaferDietmar Schedlitzki
    • D06N3/04D06N7/00D06N7/02D06N7/06D21H19/20D21H27/26B32B27/10B32B27/08B32B27/30
    • D06N7/00D06N3/042D21H27/26D21H19/20Y10T428/26Y10T428/27Y10T428/31866Y10T428/31906
    • A backing sheet for the weathering-resistant coating of thin, plane backings in continuous presses without recooling comprising(A) a paper impregnated with curable melamine resin in an amount of 40 to 60 weight percent of aminoplast resin, based on the weight of the paper, in the dried state, and(B) a coating of curable acrylic resin on the impregnated paper in an amount of 60 to 150 g/m.sup.2, the curable acrylic resin being a copolymer obtained by polymerizing:(a) 60 to 80 weight percent of one or more alkyl methacrylate esters with 1 to 20 carbon atoms in the alkyl radical;(b) 1 to 30 weight percent of one or more alkyl acrylate esters with 1 to 8 carbon atoms in the alkyl radical;(c) 1 to 20 weight percent of an N-methoxymethylamide of acrylic acid, methacrylic acid, or mixtures thereof;(d) 1 to 20 weight percent of a hydroxyalkyl ester of acrylic or methacrylic acid, with 2 to 4 carbon atoms in the alkyl radical;(e) 1 to 20 weight percent of acrylamide or methacrylamide, the molar ratio of component (c) to the sum of (d) and (e) being about 1:1 and the ratio of (d) to (c) being 4:1 to 1:4;(f) 0 to 35 weight percent of acrylonitrile,the sum of components (a) to (f) being 100 weight percent. The so-called endless laminates, fabricated by using the inventive backing sheet containing the selected acrylic resin, have a defect-free surface, even though the laminates were not recooled.
    • 一种用于不连续冲压的连续压机中的薄的平面背衬的耐候性涂层的背衬片,包括(A)基于纸的重量(A)以40至60重量%的氨基塑料树脂的量浸渍可固化三聚氰胺树脂的纸 (B)在浸渍纸上涂布可固化丙烯酸树脂的量为60〜150g / m 2,可固化丙烯酸树脂是通过以下方法获得的共聚物:(a)60-80重量% 的一个或多个在烷基中具有1至20个碳原子的甲基丙烯酸烷基酯酯; (b)1至30重量%的烷基中具有1至8个碳原子的一种或多种丙烯酸烷基酯酯; (c)1至20重量%的丙烯酸,甲基丙烯酸或其混合物的N-甲氧基甲基酰胺; (d)1至20重量%的烷基中具有2至4个碳原子的丙烯酸或甲基丙烯酸的羟烷基酯; (e)1至20重量%的丙烯酰胺或甲基丙烯酰胺,组分(c)与(d)和(e)之和的摩尔比为约1:1,(d)与(c)的比例为4 1:1:4; (f)0-35重量%的丙烯腈,组分(a)至(f)的总和为100重量%。 通过使用含有所选择的丙烯酸树脂的本发明背衬片制成的所谓的无端层压板即使没有重新冷却,也具有无缺陷的表面。