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    • 5. 发明申请
    • Proton-Conducting Polymer with a Two-Dimensional Backbone of Metal-Oxygen Bonding
    • 具有金属氧接合的二维骨架的质子传导聚合物
    • US20100298452A1
    • 2010-11-25
    • US12784484
    • 2010-05-20
    • Wen-Qing XuDavid Beijia Xu
    • Wen-Qing XuDavid Beijia Xu
    • C08J5/22
    • C08J5/2256C08J2383/04H01M8/0289H01M8/1037
    • The present invention relates a new proton-conducting polymer with a two dimensional backbone with metal-oxygen bonding. The metal ion in the backbone of the proton-conducting polymer of the present invention comprises elements from Group IIIA, IVA, VA, IIIB, IVB, VB, VIB, lanthanides, etc in the Chemical Periodic Table. It is more preferred for the metal ion of the proton-conducting polymer of the present invention to be silicon, aluminum, boron, gallium, indium, tin, antimony, bismuth, titanium, or zirconium. It is further preferred that the backbone of the proton-conducting polymer of the present invention comprises silicon, aluminum, boron, zirconium, or titanium. It is further preferred that the proton-conduction polymer of the present invention comprises silicon in its two dimensional backbone. The backbone of the proton-conducting polymer of the present invention is chemically stable to attacks from the hydroxyl free radicals in the fuel cells. The invented polymer with a two dimensional backbone of metal-oxygen bonding is thermally stable for high temperature usage as a proton-exchange membrane for proton-exchange membrane fuel cells. The polymer with a two dimensional backbone of metal-oxygen bonding is also flexible and ductile enough to allow successful fabrication of the invented material into membrane-electrode-assembly for fuel cells. The flexibility and conductivity of the proton-conducting polymer of the present invention also allow the proton-exchange membrane fuel cell to have a long lifespan with minimal issues in membrane delamination and denaturing during fuel cell operation at a high temperature.
    • 本发明涉及具有金属 - 氧键的二维骨架的新的质子传导性聚合物。 本发明的质子传导性聚合物的主链中的金属离子包含化学周期表中IIIA,IVA,VA,IIIB,IVB,VB,VIB,镧系元素等的元素。 本发明的质子传导性聚合物的金属离子更优选为硅,铝,硼,镓,铟,锡,锑,铋,钛或锆。 进一步优选本发明的质子传导性聚合物的骨架包含硅,铝,硼,锆或钛。 进一步优选的是,本发明的质子传导聚合物在其二维骨架中包含硅。 本发明的质子导电聚合物的主链对于燃料电池中的羟基自由基的攻击具有化学稳定性。 具有金属 - 氧键的二维骨架的本发明聚合物作为用于质子交换膜燃料电池的质子交换膜的高温使用是热稳定的。 具有金属 - 氧键合的二维骨架的聚合物也是柔性和延性足以允许成功地将本发明的材料制造成用于燃料电池的膜 - 电极组件。 本发明的质子传导性聚合物的柔韧性和导电性还允许质子交换膜燃料电池具有长的使用寿命,在高温下在燃料电池操作期间薄膜分层和变性的最小问题。
    • 7. 发明授权
    • Nickel-based reforming catalysts
    • 镍基重整催化剂
    • US08575063B2
    • 2013-11-05
    • US12606459
    • 2009-10-27
    • Wen-Qing XuDavid Beijia Xu
    • Wen-Qing XuDavid Beijia Xu
    • B01J23/00B01J21/00
    • B01J23/755B01J23/78B01J23/83B01J23/835B01J23/8435B01J23/8437B01J23/8474B01J23/883B01J23/888B01J35/1061B01J35/1066B01J35/108B01J35/109B01J37/031B01J37/04C01B3/40C01B2203/0227C01B2203/1058Y02P20/52
    • The present invention relates unique pore structures in nickel supported on alumina with the negligible formation of macropores. Incorporation of additional elements stabilizes the pore structure of the nickel supported on alumina. Additional element(s) were then further added into the nickel-supported materials. These additional element(s) further stabilize the pore structures under heating conditions. The improvements of pore structure stability under heating conditions and negligible presence of macropores limit the sintering of nickel metal to a mechanism of impeded diffusion. The negligible presence of macropores also limits the deposition of alkali metal hydroxide(s)/carbonate(s) on the outer shell of the catalyst pellet in the molten carbonate fuel cells. Both the negligible presence of macropores and improvement in pore structure stability allow for prolonging the catalyst life of these nickel supported on alumina catalysts of the present invention for reforming hydrocarbons.
    • 本发明涉及在负载在氧化铝上的镍中的独特的孔结构,可以忽略大孔的形成。 附加元素的结合稳定了负载在氧化铝上的镍的孔结构。 然后将另外的元素加入到镍负载的材料中。 这些附加元件在加热条件下进一步稳定孔结构。 加热条件下孔结构稳定性的改善和大孔存在的微不足道限制了镍金属的烧结成阻碍扩散的机理。 大孔的可忽略的存在也限制了熔融碳酸盐燃料电池中催化剂颗粒的外壳上的碱金属氢氧化物/碳酸盐的沉积。 微孔存在的微不足道和孔结构稳定性的改善使得延长本发明用于重整烃的氧化铝催化剂上的这些镍的催化剂寿命。