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1. 发明授权

US5597944A Dehydrogenation of N-paraffin to N-olefin employing manganese oxide octahedral molecular sieve as catalyst 失效
标题翻译：使用氧化锰八面体分子筛作为催化剂将N-链烷烃脱氢为N-烯烃
公开(公告)号：US5597944A
公开(公告)日：1997-01-28
申请号：US335317
申请日：1994-11-07
申请人： Chi-Lin O'Young , Robert A. Sawicki , Yuan-Gen Yin , Wen-Qing Xu , Steven L. Suib
发明人： Chi-Lin O'Young , Robert A. Sawicki , Yuan-Gen Yin , Wen-Qing Xu , Steven L. Suib
IPC分类号： C07C5/333 , C07C5/327
CPC分类号： C07C5/3332 , C07C2523/34 , C07C2529/03
摘要： The dehydrogenation of n-parrofins to n-olefins is catalyzed by novel synthetic manganese oxide octahedral molecular sieves such as OMS-1 and OMS-2.
摘要翻译：新型合成氧化锰八面体分子筛如OMS-1和OMS-2催化正烯烃脱氢为正烯烃。

2. 发明授权

US5523509A Manganese oxide octahedral molecular sieve as acid-base catalyst 失效
标题翻译：氧化锰八面体分子筛作为酸碱催化剂
公开(公告)号：US5523509A
公开(公告)日：1996-06-04
申请号：US335319
申请日：1994-11-07
申请人： Chi-Lin O'Young , Robert A. Sawicki , Yan-Fei Shen , Steven L. Suib
发明人： Chi-Lin O'Young , Robert A. Sawicki , Yan-Fei Shen , Steven L. Suib
IPC分类号： B01J23/34 , B01J23/889 , C07C1/20 , C07C45/00 , C07C1/00 , C07C49/00
CPC分类号： C07C45/002 , B01J23/34 , B01J23/8892 , C07C1/20 , C07C2529/04
摘要： Synthetic manganese oxide octahedral molecular sieves, e.g., OMS-1 and OMS-2, are employed as acid-base catalysts in a variety of acid-base organic conversion reactions.
摘要翻译：在各种酸碱有机转化反应中，使用合成的氧化锰八面体分子筛，例如OMS-1和OMS-2作为酸碱催化剂。

3. 发明授权

US5340562A Hydrothermal synthesis of octahedral molecular sieve 失效
标题翻译：八面体分子筛的水热合成
公开(公告)号：US5340562A
公开(公告)日：1994-08-23
申请号：US42171
申请日：1993-04-02
申请人： Chi-Lin O'Young , Yan-Fei Shen , Richard P. Zerger , Steven L. Suib
发明人： Chi-Lin O'Young , Yan-Fei Shen , Richard P. Zerger , Steven L. Suib
IPC分类号： B01J20/02 , C01B37/00 , C01B39/00 , C01G45/00 , C01G45/02 , C10G45/12
CPC分类号： C01G45/02 , C01B37/00 , C01G45/00 , C01P2002/02 , C01P2002/72 , C01P2002/77 , C01P2002/88
摘要： A process of synthesizing synthetic manganese oxide hydrates having various structures including hollandite and todorokite structure by hydrothermal synthesis. The products have a high degree of crystallinity, and thermal stability.
摘要翻译：通过水热合成合成具有各种结构的合成氧化锰水合物的方法，包括胡萝卜素和硬球形结构。该产品具有高度的结晶度和热稳定性。

4. 发明授权

US5635155A Hydrothermal synthesis of octahedral molecular sieve 失效
标题翻译：八面体分子筛的水热合成
公开(公告)号：US5635155A
公开(公告)日：1997-06-03
申请号：US712136
申请日：1996-09-11
申请人： Chi-Lin O'Young , Yan-Fei Shen , Richard P. Zerger , Steven L. Suib
发明人： Chi-Lin O'Young , Yan-Fei Shen , Richard P. Zerger , Steven L. Suib
IPC分类号： B01J20/02 , C01B37/00 , C01B39/00 , C01G45/00 , C01G45/02 , C01G45/12
CPC分类号： C01G45/02 , C01B37/00 , C01G45/00 , C01P2002/02 , C01P2002/72 , C01P2002/77 , C01P2002/88
摘要： A process of synthesizing synthetic manganese oxide hydrates having various structures including hollandite and todorokite structure by hydrothermal synthesis. The products have a high degree of crystallinity, and thermal stability.
摘要翻译：通过水热合成合成具有各种结构的合成氧化锰水合物的方法，包括胡萝卜素和硬球形结构。该产品具有高度的结晶度和热稳定性。

5. 发明授权

US5578282A Octahedral molecular sieve possessing (4.times.4) tunnel structure and method of its production 失效
标题翻译：具有（4x4）隧道结构的八面体分子筛及其生产方法
公开(公告)号：US5578282A
公开(公告)日：1996-11-26
申请号：US335498
申请日：1994-11-07
申请人： Chi-Lin O'Young , Steven L. Suib
发明人： Chi-Lin O'Young , Steven L. Suib
IPC分类号： C01G45/02 , C01B37/00 , C01B39/00 , C01G45/00 , C01G45/12
CPC分类号： C01G45/006 , C01B39/00 , C01G45/02 , C01G45/1221 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2006/16
摘要： A new class of manganese oxide octahedral molecular sieves possess a (4.times.4) tunnel structure. The molecular sieves possess the general compositionA.sub.a M.sub.b Mn.sub.16-b O.sub.32 n.multidot.H.sub.2 Owherein A is +1, +2, +3 or +4 tunnel cation or combination thereof, 0.ltoreq.a.ltoreq.8, M is +1, +2, +3 or +4 framework-substituting metal cation or combination thereof, 0.ltoreq.b.ltoreq.16 and n.gtoreq.0.A method of producing the molecular sieves includes the steps of dissolving a manganese salt in an organic solvent, e.g., ethanol, adding a permanganate salt to the resulting solution to provide a solid intermediate which is recovered and heated to a temperature which results in producing an octahedral molecular sieve having a (4.times.4) tunnel structure.The molecular sieves are useful in such applications as oxidation catalysis, hydrocarbon conversion, adsorption and electrochemical sensors.
摘要翻译：一类新型的氧化锰八面体分子筛具有（4×4）隧道结构。分子筛具有一般组成AaMbMn16-bO32nxH2O，其中A为+1，+2，+3或+4隧道阳离子或其组合，0≤a≤8，M为+1，+2，+ 3 或+4构架取代金属阳离子或其组合，0 / = 0。制造分子筛的方法包括以下步骤：将锰盐溶解在有机溶剂如乙醇中，向所得溶液中加入高锰酸盐，提供固体中间体，将其回收并加热至导致产生具有（4×4）隧道结构的八面体分子筛。分子筛可用于氧化催化，烃转化，吸附和电化学传感器等应用。

6. 发明授权

US5198597A Bimetallic catalysts for dehydroisomerization of N-butane to isobutene 失效
标题翻译：用于将N-丁烷脱氢异构化成异丁烯的双金属催化剂
公开(公告)号：US5198597A
公开(公告)日：1993-03-30
申请号：US738017
申请日：1991-07-30
申请人： Chi-Lin O'Young , James E. Browne , John F. Matteo , Robert A. Sawicki , John Hazen
发明人： Chi-Lin O'Young , James E. Browne , John F. Matteo , Robert A. Sawicki , John Hazen
IPC分类号： C07C5/27 , C07C5/373
CPC分类号： C07C5/2791 , C07C5/373 , Y02P20/125
摘要： Normal olefins such as n-butenes and normal alkanes such as n-butane can be coverted to branched olefin species such as isobutylene by skeletal dehydroisomerization over catalysts preferably containing metals selected from Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, VIII and the rear earth elements which are deposited upon borosilicate zeolites having pore sizes of at least about 5 Angstroms and containing boron in the framework structure thereof. The borosilicates have sufficient acidity to catalyze the skeletal isomerization of both normal alkanes and normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译：在优选含有选自IB，IIB，IIIB，IVB，VB，VIB，VIIB，VIIB族的金属的催化剂的催化剂上，可以通过骨架脱氢异构化将正丁烯和正丁烷如正丁烷等正构烯烃覆盖至支链烯烃，如异丁烯， VIII和沉积在孔径为至少约5埃的硼硅酸盐沸石上并在其骨架结构中含有硼的后土元素。硼硅酸盐具有足够的酸度来催化正构烷烃和正构烯烃的骨架异构化。催化剂可以用于制备用于与醇在一体化方法中反应的异烯烃，以产生烷基叔烷基醚如MTBE。

7. 发明授权

US5545393A Method of preparing manganese oxide octahedral molecular sieve 失效
标题翻译：制备氧化锰八面体分子筛的方法
公开(公告)号：US5545393A
公开(公告)日：1996-08-13
申请号：US335154
申请日：1994-11-07
申请人： Chi-Lin O'Young , Robert A. Sawicki
发明人： Chi-Lin O'Young , Robert A. Sawicki
IPC分类号： B01J20/06 , B01J23/34 , C01B37/00 , C01B39/00 , C01G45/02
CPC分类号： C01B39/00 , C01G45/02 , C01P2002/72 , C01P2002/77
摘要： Manganese oxide octahedral molecular sieve (OMS) is produced by the method comprising:a) forming an aqueous reaction medium containing manganese cation and permanganate anion, the reaction medium being maintained at a pH of not greater than about 4.5;b) refluxing the aqueous reaction medium under conditions which are effective to produce solid crystalline manganese oxide octahedral molecular sieve product; and,c) recovering the solid crystalline product.The method of this invention is carried out in an open system, i.e., a reflux condenser, and results in the formation of OMS which is thermally stable up to about 600.degree. C.
摘要翻译：通过以下方法制备氧化锰八面体分子筛（OMS）：a）形成含有锰阳离子和高锰酸盐阴离子的水性反应介质，反应介质保持在不大于约4.5的pH; b）在有效产生固体结晶锰氧化物八面体分子筛产物的条件下回流水性反应介质; 和c）回收固体结晶产物。本发明的方法在开放系统即回流冷凝器中进行，并导致在约600℃下热稳定的OMS的形成。

8. 发明授权

US07700796B2 Preparation of nanosized copper (I) compounds 失效
标题翻译：纳米尺寸铜（I）化合物的制备
公开(公告)号：US07700796B2
公开(公告)日：2010-04-20
申请号：US10413754
申请日：2003-04-16
申请人： Kenrick M. Lewis , Chi-Lin O'Young
发明人： Kenrick M. Lewis , Chi-Lin O'Young
IPC分类号： C01G3/05
CPC分类号： B82Y30/00 , C01C3/08 , C01C3/11 , C01G3/00 , C01G3/04 , C01G3/05 , C01P2002/72 , C01P2002/77 , C01P2002/82 , C01P2004/62 , C01P2004/64 , Y10S977/773 , Y10S977/81
摘要： A method of making nanosized copper (I) compounds, in particular, copper (I) halides, pseudohalides, and cyanocuprate complexes, in reverse micelles or microemulsions is disclosed herein. The method of the invention comprises (a) dissolving a copper (II) compound in the polar phase of a first reverse micelle or microemulsion, (b) dissolving a copper (II) to copper (I) reducing agent or a pseudohalide salt in the polar phase of a second sample of the same reverse micelle or microemulsion, (c) mixing the two reverse micelle/microemulsions samples to form nanometer sized copper (I) compounds and (d) recovering said nanometer sized copper (I) compounds. The present invention is also directed to the resultant nanosized copper (I) compounds, such as copper (I) chloride, copper (I) cyanide, and potassium cyanocuprate complexes having an average particle size of about 0.1 to 600 nanometers.
摘要翻译：本文公开了一种在反胶束或微乳液中制备纳米尺寸铜（I）化合物，特别是卤化铜（I），拟卤化物和氰基偶联物络合物的方法。本发明的方法包括（a）将铜（II）化合物溶解在第一反胶束或微乳液的极性相中，（b）将铜（II）溶解在铜（I）还原剂或拟卤化物盐中，相同反胶束或微乳液的第二样品的极性相，（c）混合两个反胶束/微乳液样品以形成纳米尺寸的铜（I）化合物和（d）回收所述纳米尺寸的铜（I）化合物。本发明还涉及所得到的纳米尺度铜（I）化合物，例如氯化铜（I），氰化铜（I）和平均粒度约为0.1至600纳米的氰基钴酸钾配合物。

9. 发明授权

US5510560A Skeletal isomerization of n-olefins to iso-olefins on binded ferrierite zeolites 失效
标题翻译：在结合的镁碱沸石沸石上正构烯烃异构化成异烯烃
公开(公告)号：US5510560A
公开(公告)日：1996-04-23
申请号：US112921
申请日：1993-08-30
申请人： Chi-Lin O'Young , Regis J. Pellet , Alison E. Hadowanetz , John Hazen , James E. Browne
发明人： Chi-Lin O'Young , Regis J. Pellet , Alison E. Hadowanetz , John Hazen , James E. Browne
IPC分类号： C07C5/27 , C07C5/22
CPC分类号： C07C5/2775 , C07C2529/06
摘要： The method of converting n-butylenes to isobutylene by a skeletal isomrization reaction wherein said reaction is carried out at a temperature of between 300.degree. C. and 650.degree. C., under a pressure of between 0.1 and 100 atmospheres and a space velocity of said n-butylenes of between 0.1 and 40 WHSV using a cagalyst comprising a zeolite binder selected frm the group consisting of alumina, silica, silica-alumina, clay and a combination thereof, said catalyst having a pore size of at least about 4.5 angstroms and the pore size structure is characteried by intersecting 10-member ring and 8-member ring channels.
摘要翻译：通过骨架均化反应将正丁烯转化为异丁烯的方法，其中所述反应在约100℃至100℃之间的压力下在300℃和650℃之间的温度下进行，所述反应在所述使用包含选自由氧化铝，二氧化硅，二氧化硅 - 氧化铝，粘土及其组合组成的组的沸石粘合剂的囊状物的0.1至40WHSV的正丁烯，所述催化剂的孔径至少为约4.5埃，孔径结构的特征是10个环和8个环通道相交。

10. 发明授权

US5227569A Skeletal isomerization of n-butylenes to isobutylene on boron-beta zeolites 失效
标题翻译：正丁烯在硼-β沸石上的异构异构化
公开(公告)号：US5227569A
公开(公告)日：1993-07-13
申请号：US747054
申请日：1991-08-19
申请人： Chi-Lin O'Young , John Hazen , Daniel G. Casey
发明人： Chi-Lin O'Young , John Hazen , Daniel G. Casey
IPC分类号： C07C5/27
CPC分类号： C07C5/2775 , Y02P20/125
摘要： Normal olefins such as n-butenes can be converted to iso olefins such as isobutylene by skeletal isomerization over catalysts of boron-beta zeolites having pore sizes of at least about 5 Angstroms and containing boron in the framework structure thereof. The boron-beta zeoliteS have sufficient acidity to catalyze the skeletal isomerization of normal olefinsto iso-olefins. The catalysts can be used to produce iso-olefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译：正丁烯如正丁烯可以通过骨架异构化在具有至少约5埃的孔径的硼-β沸石的催化剂上在其框架结构中含有硼而转化成异烯烃，例如异丁烯。硼-β沸石具有足够的酸度来催化正烯烃异构烯烃的骨架异构化。催化剂可用于生产异构烯烃，用于与醇在一体化方法中反应，生成烷基叔烷基醚如MTBE。

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