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    • 8. 发明申请
    • Magnetic Tunnel Junction for MRAM applications
    • MRAM应用的磁隧道结
    • US20120181537A1
    • 2012-07-19
    • US12930877
    • 2011-01-19
    • Wei CaoCheng T. HorngWitold KulaChyu Jiuh Torng
    • Wei CaoCheng T. HorngWitold KulaChyu Jiuh Torng
    • H01L29/82H01L21/36H01L29/04
    • H01L43/10G11C11/161H01L27/222H01L43/00H01L43/02H01L43/08
    • A MTJ in an MRAM array is disclosed with a composite free layer having a lower crystalline layer contacting a tunnel barrier and an upper amorphous NiFeX layer for improved bit switching performance. The crystalline layer is Fe, Ni, or FeB with a thickness of at least 6 Angstroms which affords a high magnetoresistive ratio. The X element in the NiFeX layer is Mg, Hf, Zr, Nb, or Ta with a content of 5 to 30 atomic %. NiFeX thickness is preferably between 20 to 40 Angstroms to substantially reduce bit line switching current and number of shorted bits. In an alternative embodiment, the crystalline layer may be a Fe/NiFe bilayer. Optionally, the amorphous layer may have a NiFeM1/NiFeM2 configuration where M1 and M2 are Mg, Hf, Zr, Nb, or Ta, and M1 is unequal to M2. Annealing at 300° C. to 360° C. provides a high magnetoresistive ratio of about 150%.
    • 公开了具有接触隧道势垒的较低结晶层和上部非晶NiFeX层的复合自由层的MRAM阵列中的MTJ,用于改善位切换性能。 结晶层是厚度至少为6埃的Fe,Ni或FeB,其具有高的磁阻比。 NiFeX层中的X元素为含有5〜30原子%的Mg,Hf,Zr,Nb或Ta。 NiFeX厚度优选在20至40埃之间,以显着减少位线切换电流和短路位数。 在替代实施例中,结晶层可以是Fe / NiFe双层。 可选地,非晶层可以具有其中M1和M2是Mg,Hf,Zr,Nb或Ta的NiFeM1 / NiFeM2构型,M1不等于M2。 在300℃至360℃退火,提供约150%的高磁阻比。
    • 9. 发明授权
    • Magnetic tunnel junction for MRAM applications
    • 用于MRAM应用的磁隧道结
    • US08492169B2
    • 2013-07-23
    • US13136929
    • 2011-08-15
    • Wei CaoWitold KulaChyu-Jiuh Torng
    • Wei CaoWitold KulaChyu-Jiuh Torng
    • H01L29/82H01L29/88G11C11/02
    • H01L43/10B82Y40/00H01F10/3272H01F10/3295H01F41/307H01L43/12
    • Reading margin is improved in a MTJ designed for MRAM applications by employing a pinned layer with an AP2/Ru/AP1 configuration wherein the AP1 layer is a CoFeB/CoFe composite and by forming a MgO tunnel barrier adjacent to the CoFe AP1 layer by a sequence that involves depositing and oxidizing a first Mg layer with a radical oxidation (ROX) process, depositing and oxidizing a second Mg layer with a ROX method, and depositing a third Mg layer on the oxidized second Mg layer. The third Mg layer becomes oxidized during a subsequent anneal. MTJ performance may be further improved by selecting a composite free layer having a Fe/NiFeHf or CoFe/Fe/NiFeHf configuration where the NiFeHf layer adjoins a capping layer in a bottom spin valve configuration. As a result, read margin is optimized simultaneously with improved MR ratio, a reduction in bit line switching current, and a lower number of shorted bits.
    • 通过采用具有AP2 / Ru / AP1配置的钉扎层,其中AP1层是CoFeB / CoFe复合材料并且通过顺序形成与CoFe AP1层相邻的MgO隧道势垒,为MRAM应用设计的MTJ中的读取余量得到改善 其包括用自由基氧化(ROX)工艺沉积和氧化第一Mg层,用ROX法沉积和氧化第二Mg层,以及在氧化的第二Mg层上沉积第三Mg层。 在随后的退火中,第三Mg层变成氧化的。 通过选择具有Fe / NiFeHf或CoFe / Fe / NiFeHf构型的复合自由层,其中NiFeHf层与底部自旋阀结构中的覆盖层邻接,可以进一步改善MTJ性能。 结果,读取余量同时优化了MR比,降低了位线切换电流,并且更少的短路位数。
    • 10. 发明授权
    • Method of fabricating contact pad for magnetic random access memory
    • 制造磁性随机存取存储器接触焊盘的方法
    • US07122386B1
    • 2006-10-17
    • US11231674
    • 2005-09-21
    • Chyu-Jiuh TorngTom ZhongWei CaoPo-Kang Wang
    • Chyu-Jiuh TorngTom ZhongWei CaoPo-Kang Wang
    • H01L21/00
    • H01L43/12H01L27/222
    • A method of forming a Cu—Cu junction between a word line pad (WLP) and bit line (BL) contact is described. An opening above a WL contact is formed in a first SiNx layer on a substrate that includes a WLP and word line. After a bottom electrode (BE) layer, MTJ stack, and hard mask are sequentially deposited, an etch forms an MTJ element above the word line. Another etch forms a BE and exposes the first SiNx layer above the WLP and bond pad (BP). An MTJ ILD layer is deposited and planarized followed by deposition of a second SiNx layer and BL ILD layer. Trenches are formed in the BL ILD layer and second SiNx layer above the WLP, hard mask and BP. After vias are formed in the MTJ ILD and first SiNx layers above the WLP and BP, Cu deposition follows to form dual damascene BL contacts.
    • 描述了在字线焊盘(WLP)和位线(BL)触点之间形成Cu-Cu结的方法。 在包括WLP和字线的衬底上的第一SiN x层中形成WL触点上方的开口。 在底电极(BE)层,MTJ叠层和硬掩模之后,顺序沉积,蚀刻在字线之上形成MTJ元件。 另一蚀刻形成BE,并使WLP和接合焊盘(BP)上方的第一SiN x层暴露。 沉积MTJ ILD层并平坦化,随后沉积第二SiN x层和BL ILD层。 沟槽形成在WLP,硬掩模和BP之上的BL ILD层和第二SiN x x层中。 在WLP和BP上方的MTJ ILD和第一SiN x x层中形成通孔之后,随后进行Cu沉积以形成双镶嵌BL触点。