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1. 发明授权

US4239704A Process for producing acetaldehyde 失效
标题翻译：乙醛生产方法
公开(公告)号：US4239704A
公开(公告)日：1980-12-16
申请号：US42330
申请日：1979-05-25
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/18 , B01J31/20 , C07C45/49 , C07C47/06
CPC分类号： B01J31/20 , B01J31/1895 , C07C45/49 , B01J2531/845
摘要： A process for selectively producing acetaldehyde which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) an arsenic or antimony base ligand and (6) an iodine compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to acetaldehyde.
摘要翻译：一种选择性生产乙醛的方法，其中包括将甲醇，（2）氢气，（3）一氧化碳，（4）羰基钴，羰基钴或可转化为钴的钴的材料引入反应区羰基或羰基碳氢化合物，（5）砷或锑碱配体和（6）碘化合物，然后使所述反应区的内容物在升高的温度和升高的压力下进行足以将甲醇转化为乙醛的时间。

2. 发明授权

US4339609A Process for selective formation of C.sub.4 compounds and biphosphine disulfide-containing catalyst system used therein 失效
标题翻译：用于选择性形成其中使用的C4化合物和含二硫化碳的催化剂体系的方法
公开(公告)号：US4339609A
公开(公告)日：1982-07-13
申请号：US215554
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/24 , C07C29/32 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： B01J31/0231 , B01J31/1845 , B01J31/226 , B01J31/26 , C07C29/32 , C07C45/49 , B01J2231/641 , B01J2531/845 , B01J31/20 , B01J31/2208 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a biphosphine disulfide having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, the same or different, are selected from the group consisting of saturated or unsaturated, staight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the biphosphine disulfide in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and phosphorus. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和具有下式的二膦化合物：其中R1，R2，R3和R4相同或不同，选自由具有1至24个碳原子的饱和或不饱和，直链或支链烷基，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至6个碳原子的芳烷基和烷芳基 40个碳原子及其卤素取代的衍生物。以元素钴和磷为基础，通过使用摩尔比在约2:1至约10:1范围内的钴实体和二膦二膦来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

3. 发明授权

US4151208A Process for the selective preparation of acetaldehyde from methanol and synthesis gas 失效
标题翻译：从甲醇和合成气中选择性制备乙醛的方法
公开(公告)号：US4151208A
公开(公告)日：1979-04-24
申请号：US863744
申请日：1977-12-23
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/16 , B01J31/18 , B01J31/26 , C07C45/49 , C07C47/06
CPC分类号： B01J31/183 , B01J31/26 , C07C45/49 , B01J2531/025 , B01J2531/845
摘要： A process for selectively producing acetaldehyde which comprises contacting methanol, hydrogen and carbon monoxide with cobalt (II) meso-tetraaromaticporphine and an iodine promoter.
摘要翻译：一种选择性生产乙醛的方法，包括使甲醇，氢气和一氧化碳与钴（Ⅱ）内消旋 - 四芳香卟吩和碘促进剂接触。

4. 发明授权

US4409404A Process for producing ethanol using said novel catalyst system 失效
标题翻译：使用所述新型催化剂体系生产乙醇的方法
公开(公告)号：US4409404A
公开(公告)日：1983-10-11
申请号：US352807
申请日：1982-02-26
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/20 , B01J31/26 , C07C27/00 , C07C29/32 , C07C31/08 , C07C67/00 , C07C29/00
CPC分类号： B01J31/0231 , B01J31/0234 , B01J31/0259 , B01J31/0267 , B01J31/20 , B01J31/26 , C07C29/32 , C07C31/08 , C12C11/02 , B01J2231/34 , B01J2231/641 , B01J2531/821 , B01J2531/845
摘要： A novel process for selectively producing ethanol which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) a tertiary organo Group VA compound of the Periodic Table, (6) an iodine compound and (7) a ruthenium compound; and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to ethanol.
摘要翻译：一种用于选择性生产乙醇的新方法，其包括将甲醇，（2）氢气，（3）一氧化碳，（4）羰基钴，羰基钴或含钴材料转化为反应区羰基钴或羰基钴氢化物，（5）周期表的叔有机基团VA化合物，（6）碘化合物和（7）钌化合物; 然后使所述反应区的内容物处于升高的温度和升高的压力下一段足以将甲醇转化成乙醇的时间。

5. 发明授权

US4339610A Process for selective formation of C.sub.4 compounds and thiol-containing catalyst system used therein 失效
标题翻译：用于选择性形成C4化合物和其中使用的含硫醇催化剂体系的方法
公开(公告)号：US4339610A
公开(公告)日：1982-07-13
申请号：US215555
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/32 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： C07C29/32 , C07C45/49 , C12C11/02 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和由下式定义的硫醇：其中R选自饱和或不饱和的直链或支链烷基具有1至24个碳原子，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基及其卤素取代的衍生物。基于元素钴和硫，通过使用钴实体和硫醇以约2:1至约10:1的摩尔比来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

6. 发明授权

US4239705A Process for producing acetaldehyde 失效
标题翻译：乙醛生产方法
公开(公告)号：US4239705A
公开(公告)日：1980-12-16
申请号：US42427
申请日：1979-05-25
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/20 , C07C45/49 , C07C47/06
CPC分类号： B01J31/0231 , B01J31/1895 , B01J31/20 , B01J31/26 , B01J31/34 , C07C45/49 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/845
摘要： A process for selectively producing acetaldehyde which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) an arsenic-cobalt tricarbonyl complex and (5) an iodine compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to acetaldehyde.
摘要翻译：一种选择性生产乙醛的方法，包括将甲醇，（2）氢，（3）一氧化碳，（4）砷 - 钴三羰基络合物和（5）碘化合物引入反应区（1），（5）碘化合物的反应区域升温至升高的压力达足以将甲醇转化为乙醛的时间。

7. 发明授权

US4352946A Process for producing ethanol 失效
标题翻译：生产乙醇的方法
公开(公告)号：US4352946A
公开(公告)日：1982-10-05
申请号：US153190
申请日：1980-05-27
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/32 , C07C29/00
CPC分类号： C07C29/32
摘要： A process for selectively producing ethanol which comprises introducing into a reaction zone methanol, hydrogen, carbon monoxide, a cobalt tricarbonyl complex and an iodine promoter and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time period sufficient to convert methanol to ethanol.
摘要翻译：一种选择性生产乙醇的方法，包括将甲醇，氢气，一氧化碳，三羰基钴络合物和碘促进剂引入反应区，然后将所述反应区的内容物升温至高压，持续一段时间将甲醇转化为乙醇。

8. 发明授权

US4339611A Process for selective formation of C.sub.4 compounds and organic sulfide-containing catalyst system used therein 失效
标题翻译：用于选择性形成C4化合物和其中使用的含有机硫化物的催化剂体系的方法
公开(公告)号：US4339611A
公开(公告)日：1982-07-13
申请号：US215556
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J27/043 , B01J31/20 , C07C29/32 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： B01J31/2234 , B01J27/043 , B01J31/0218 , B01J31/0231 , B01J31/20 , B01J31/26 , C07C29/32 , C07C45/49 , B01J2231/34 , B01J2231/641 , B01J2531/845 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and an organic sulfide having the formula:R.sub.1 --S--R.sub.2wherein R.sub.1 and R.sub.2 can be the same or different members selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the organic sulfide in a molar ratio in the range of about 2:1 to about 1:10, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和有机硫化物，其具有下式：R1-S-R2，其中R1和R2可以是相同或不同的选自基团由具有1至24个碳原子的饱和或不饱和的直链或支链烷基，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基原子和卤素取代的衍生物。通过使用基于元素钴和硫的摩尔比在约2:1至约1:10范围内的钴实体和有机硫化物来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

9. 发明授权

US4339608A Process for selective formation of C.sub.4 compounds and tertiary organo group VA compound-containing catalyst system used therein 失效
标题翻译：用于选择性形成其中使用的C4化合物和叔有机基团VA化合物的催化剂体系的方法
公开(公告)号：US4339608A
公开(公告)日：1982-07-13
申请号：US215354
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/18 , B01J31/20 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： B01J31/20 , B01J31/1895 , C07C45/49 , B01J2531/845
摘要： A process and catalyst system for selectively producing n-butanol and n-butanal which process comprises introducing into a reaction zone methanol, hydrogen, carbon monoxide and a catalyst system consisting essentially of (a) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (b) an iodine compound and (c) a tertiary organo Group VA compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：用于选择性生产正丁醇和正丁醛的方法和催化剂体系，该方法包括将甲醇，氢气，一氧化碳和基本上由（a）羰基钴，羰基钴或钴（b）碘化合物和（c）叔有机基团VA化合物，然后使所述反应区的内容物在升高的温度和升高的压力下进行一段时间足以将甲醇转化为正丁醇和正丁醛。

10. 发明授权

US4447557A Process for selective formation of C4 compounds and thiol-containing catalyst system used therein 失效
标题翻译：用于选择性形成C4化合物和其中使用的含硫醇催化剂体系的方法
公开(公告)号：US4447557A
公开(公告)日：1984-05-08
申请号：US353376
申请日：1982-03-01
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/32 , C07C45/49 , B01J31/20
CPC分类号： C07C29/32 , C07C45/49 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和由下式定义的硫醇：其中R选自饱和或不饱和的直链或支链烷基具有1至24个碳原子，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基及其卤素取代的衍生物。基于元素钴和硫，通过使用钴实体和硫醇以约2:1至约10:1的摩尔比来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

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