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1. 发明授权

US07025815B2 Water-soluble complex dye, recording fluid and recording method 有权
标题翻译：水溶性复合染料，记录液和记录方法
公开(公告)号：US07025815B2
公开(公告)日：2006-04-11
申请号：US11005021
申请日：2004-12-07
申请人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
发明人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
IPC分类号： C09D11/02 , C09B45/00
CPC分类号： C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
摘要： A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented.
摘要翻译：能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。

2. 发明申请

US20050081747A1 Water-soluble complex dye, recording fluid and recording method 有权
标题翻译：水溶性复合染料，记录液和记录方法
公开(公告)号：US20050081747A1
公开(公告)日：2005-04-21
申请号：US11005021
申请日：2004-12-07
申请人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
发明人： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
IPC分类号： C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/44 , C09D11/00 , C09B45/00
CPC分类号： C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
摘要： A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.
摘要翻译：能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。包含由下式（1）表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液，特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。在式（1）中，A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团，并且可以具有任选的取代基，但它代表基团在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环，键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。

3. 发明授权

US5480478A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5480478A
公开(公告)日：1996-01-02
申请号：US350077
申请日：1994-11-29
申请人： Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
发明人： Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： A recording liquid comprising an aqueous medium and at least one dye selected from dyes, a free acid form of which is represented by formula (I), (II), (III) or (VI), the symbols in the formulae being defined in the specification: ##STR1##
摘要翻译：一种包含水性介质和选自染料的至少一种染料的记录液体，其游离酸形式由式（I），（II），（III）或（VI）表示，式中的符号定义在规格：（I）（II）

4. 发明授权

US5478384A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5478384A
公开(公告)日：1995-12-26
申请号：US238734
申请日：1994-05-05
申请人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
发明人： Hiroshi Takimoto , Tomio Yoneyama , Hideo Sano , Yukichi Murata , Masahiro Yamada
IPC分类号： C09B31/08 , C09B31/18 , C09D11/00 , C09D11/02
CPC分类号： C09D11/32 , C09B31/08 , C09B31/18 , C09D11/328
摘要： A recording liquid excellent in print quality, light resistance, and water resistance which is characterized in that it contains an aqueous medium and at least one dye selected from the dyes represented by general formulae [I] to [V]: ##STR1## (wherein R.sub.1 and R.sub.2 each represents H, CH.sub.3, or OCH.sub.3 ; R.sub.3 represents H, Cl,CH.sub.3, or OCH.sub.3 ; R.sub.4 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, a tolyl group, or an anisyl group; R.sub.5 represents H, a phenyl group which may be substituted with a COOM group, or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; R.sub.6 represents H or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; X represents SO.sub.3 M or COOM; Y represents --CO-- or --SO.sub.2 --; m represents 1 or 2; n represents 0 or 1; A represents a phenylene group which may have one or more members selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, an amino group, a --COOM group, a hydroxyl group, an --SO.sub.3 M group, and a halogen atom; and M represents an alkali metal, an ammonium group, or an organic amine salt.)
摘要翻译：印刷质量，耐光性和耐水性优异的记录液，其特征在于，其含有水性介质和选自通式[I]〜[V]表示的染料中的至少一种染料：（IV）其中R 1和R 2各自表示H，CH 3或OCH 3; R 3表示H，Cl，CH 3或 OCH 3; R 4表示碳原子数1〜6的烷基，苯基，甲苯基或茴香基; R 5表示H，可以被COOM基取代的苯基或具有1〜被COOM基团取代的3个碳原子; R6表示H或被COOM基团取代的具有1至3个碳原子的烷基; X表示SO 3 M或COOM; Y表示-CO-或-SO 2 - ; m表示 1或2; n表示0或1; A表示可以具有一个或多个选自具有1至4个碳的烷基的一个或多个的亚苯基具有1至4个碳原子的烷氧基，氨基，-COOM基，羟基，-SO 3 M基和卤素原子; M表示碱金属，铵基或有机胺盐。

5. 发明授权

US5599386A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5599386A
公开(公告)日：1997-02-04
申请号：US445797
申请日：1995-05-04
申请人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
发明人： Hideo Sano , Yukichi Murata , Hiroshi Takimoto
IPC分类号： C09B29/30 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B29/30
摘要： A recording liquid comprising an aqueous medium and at least one selected from the compounds whose free acid form is represented by the formula {1}: ##STR1## wherein, R.sup.1, R.sup.2 and R.sup.3 each independently represent a substituted or unsubstituted C.sub.1-9 alkyl group, a C.sub.1-9 alkoxy group, a halogen, hydrogen, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a C.sub.1-9 alkyl- or C.sub.6-15 aryl-sulfonyl group, a COOH group or a carboxylic ester group;m is a number of 0, 1 or 2; andR.sup.4, R.sup.5 and R.sup.6 each independently represent hydrogen, a C.sub.1-18 alkyl group, a C.sub.2-18 alkenyl group, an aryl group, an aralkyl group, an alicyclic group or a heterocyclic group, any of which groups except hydrogen may have a substituent.
摘要翻译：包含水性介质和选自游离酸形式的由式{1}表示的化合物中的至少一种的记录液体：其代表取代或未取代的C1-9烷基，C1-9烷氧基，卤素，氢，羟基，取代或未取代的氨基甲酰基，取代或未取代的氨磺酰基，取代或未取代的氨基，硝基，磺酸酯基，C1-9烷基或C6-15芳基 - 磺酰基，COOH基或羧酸酯基; m是0，1或2的数字; R 4，R 5和R 6各自独立地表示氢，C 1-18烷基，C 2-18烯基，芳基，芳烷基，脂环族基或杂环基，除氢以外的基团可以具有取代基。

6. 发明授权

US5437716A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US5437716A
公开(公告)日：1995-08-01
申请号：US242627
申请日：1994-05-13
申请人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
发明人： Hideo Sano , Tomio Yoneyama , Yukichi Murata , Masahiro Yamada
IPC分类号： C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： A recording liquid comprising an aqueous medium and at least one dye selected from dyes, free acid forms of which are represented by formulae (I) and (II): ##STR1## The symbols in formulae (I) and (II) are defined in the specification.
摘要翻译：一种包含水性介质和至少一种选自染料（其游离酸形式由式（I）和（II）表示）的染料的记录液：（I）式（I） I）和（II）在本说明书中定义。

7. 发明授权

US07960521B2 Azo dyes, compositions for anisotropic dye films using them, anisotropic dye films and polarizing elements 有权
标题翻译：偶氮染料，使用它们的各向异性染料膜的组合物，各向异性染料膜和偏振元件
公开(公告)号：US07960521B2
公开(公告)日：2011-06-14
申请号：US11721986
申请日：2005-12-14
申请人： Hideo Sano , Masami Kadowaki , Ryuichi Hasegawa , Wataru Shimizu
发明人： Hideo Sano , Masami Kadowaki , Ryuichi Hasegawa , Wataru Shimizu
IPC分类号： C09B31/20 , C09B31/22 , G02B5/30
CPC分类号： C09B31/22 , G02B5/3033
摘要： To provide a dye capable of forming an anisotropic dye film showing high dichroism and having a high degree of molecular orientation, a composition containing the dye, an anisotropic dye film using the dye and a polarizing element.A trisazo dye, of which the free acid form is represented by the following formula (1), wherein at least one of B1 and D1 has at least one substituent as defined by the following Q1, a dye composition for an anisotropic dye film containing the dye, an anisotropic dye film and a polarizing element using the anisotropic dye film: Q1: an alkyl group or alkoxy group substituted by a hydrogen bond-forming group: wherein A1 is a phenyl group or a naphthyl group, each of B1 and D1 is a phenylene group or a naphthylene group, X1 is an amino group which may be substituted or a hydroxyl group, and m is 0 or 1.
摘要翻译：为了提供能够形成显示高二色性并且具有高分子取向度的各向异性染料膜的染料，含有染料的组合物，使用该染料的各向异性染料膜和偏振元件。其中游离酸形式由下式（1）表示的三偶氮染料，其中B1和D1中的至少一个具有至少一个如以下Q1所定义的取代基，用于各向异性染料膜的染料组合物含有染料，各向异性染料膜和使用各向异性染料膜的偏振元件：Q1：被氢键形成基团取代的烷基或烷氧基：其中A1是苯基或萘基，B1和D1分别为亚苯基或亚萘基，X1是可以被取代或羟基的氨基，m是0或1。

8. 发明申请

US20090267031A1 AZO DYE, COMPOSITION CONTAINING THE SAME FOR ANISOTROPIC DYE FILM, ANISOTROPIC DYE FILM, AND POLARIZING ELEMENT 有权
标题翻译： AZO DYE，含有各向异性膜的组合物，各向异性薄膜和极化元素
公开(公告)号：US20090267031A1
公开(公告)日：2009-10-29
申请号：US11721986
申请日：2005-12-14
申请人： Hideo Sano , Masami Kadowaki , Ryuichi Hasegawa , Wataru Shimizu
发明人： Hideo Sano , Masami Kadowaki , Ryuichi Hasegawa , Wataru Shimizu
IPC分类号： G02B5/30 , C09B31/16
CPC分类号： C09B31/22 , G02B5/3033
摘要： To provide a dye capable of forming an anisotropic dye film showing high dichroism and having a high degree of molecular orientation, a composition containing the dye, an anisotropic dye film using the dye and a polarizing element.A trisazo dye, of which the free acid form is represented by the following formula (1), wherein at least one of B1 and D1 has at least one substituent as defined by the following Q1, a dye composition for an anisotropic dye film containing the dye, an anisotropic dye film and a polarizing element using the anisotropic dye film: Q1: an alkyl group or alkoxy group substituted by a hydrogen bond-forming group: wherein A1 is a phenyl group or a naphthyl group, each of B1 and D1 is a phenylene group or a naphthylene group, X1 is an amino group which may be substituted or a hydroxyl group, and m is 0 or 1.
摘要翻译：为了提供能够形成显示高二色性并且具有高分子取向度的各向异性染料膜的染料，含有染料的组合物，使用该染料的各向异性染料膜和偏振元件。其中游离酸形式由下式（1）表示的三偶氮染料，其中B1和D1中的至少一个具有至少一个如以下Q1所定义的取代基，用于各向异性染料膜的染料组合物含有染料，各向异性染料膜和使用各向异性染料膜的偏振元件：Q1：被氢键形成基团取代的烷基或烷氧基：其中A1是苯基或萘基，B1和D1分别为亚苯基或亚萘基，X1是可以被取代或羟基的氨基，m是0或1。

9. 发明申请

US20050204953A1 Recording liquid 审中-公开
标题翻译：记录液体
公开(公告)号：US20050204953A1
公开(公告)日：2005-09-22
申请号：US11135300
申请日：2005-05-24
申请人： Hideo Sano , Wataru Shimizu
发明人： Hideo Sano , Wataru Shimizu
IPC分类号： B41J2/01 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328
摘要： The present invention provides a recording liquid which provides clear printed matter even when applied as an aqueous ink-jet recording liquid to recording on plain or specialized paper, and which is also excellent in the density of recorded image, the light resistance, the indoor discoloring and fading resistance, and so on. The recording liquid comprises an aqueous medium and a monoazo dye, the free acid form of which is represented by the following general formula (1): wherein R1, R2 and R3 each independently represent one of a hydrogen atom, a halogen atom, and so on, m represents a number of 0, 1 or 2, R4 represents a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, R5 represents a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, and Z represents a group represented by the following general formula (2): or a group represented by the following general formula (3):
摘要翻译：本发明提供了一种记录液体，即使在作为水性喷墨记录液体用于在普通纸或专用纸上记录时也提供清晰的印刷物，并且其记录图像的密度，耐光性，室内变色和褪色阻力等。记录液体包含水性介质和单偶氮染料，其游离酸形式由以下通式（1）表示：其中R 1，R 2和 R 3各自独立地表示氢原子，卤素原子等中的一个，m表示0,1或2的数，R 4表示氢原子或取代或未取代的碳原子数1〜9的烷基，R 5表示氢原子或取代或未取代的碳原子数1〜18的烷基，Z表示下述基团通式（2）表示的基团或由以下通式（3）表示的基团：

10. 发明授权

US06827770B2 Metal chelated dyestuff for inkjet recording, aqueous inkjet recording liquid comprising same and inkjet recording method using same 有权
标题翻译：用于喷墨记录的金属螯合染料，包含其的水性喷墨记录液和使用其的喷墨记录方法
公开(公告)号：US06827770B2
公开(公告)日：2004-12-07
申请号：US10172927
申请日：2002-06-18
申请人： Tomohiro Chino , Masahiro Yamada , Hideo Sano , Wataru Shimizu , Yuukichi Murata
发明人： Tomohiro Chino , Masahiro Yamada , Hideo Sano , Wataru Shimizu , Yuukichi Murata
IPC分类号： C09D1102
CPC分类号： C09D11/328 , C09B45/34
摘要： A metal chelated dyestuff for inkjet recording comprising a water soluble azo metal chelated compound formed by an azo-based compound represented by the following general formula (1) having one or more hydrophilic group per molecule and a metal element; an aqueous inkjet recording liquid comprising an aqueous medium and the aforementioned metal chelated dyestuff; and an inkjet recording method using the aforementioned recording liquid are described, wherein the heterocyclic ring containing X1 is a triazole ring or the like; and Ar1 represents naphthyl group having a chelated group.
摘要翻译：一种用于喷墨记录的金属螯合染料，包括由每分子具有一个或多个亲水基团和金属元素的由以下通式（1）表示的偶氮类化合物形成的水溶性偶氮金属螯合化合物; 包含水性介质和上述金属螯合染料的水性喷墨记录液; 并且描述了使用上述记录液体的喷墨记录方法，其中含有X1的杂环是三唑环等; Ar 1表示具有螯合基团的萘基。

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