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    • 2. 发明授权
    • Recording liquid
    • 记录液体
    • US5478384A
    • 1995-12-26
    • US238734
    • 1994-05-05
    • Hiroshi TakimotoTomio YoneyamaHideo SanoYukichi MurataMasahiro Yamada
    • Hiroshi TakimotoTomio YoneyamaHideo SanoYukichi MurataMasahiro Yamada
    • C09B31/08C09B31/18C09D11/00C09D11/02
    • C09D11/32C09B31/08C09B31/18C09D11/328
    • A recording liquid excellent in print quality, light resistance, and water resistance which is characterized in that it contains an aqueous medium and at least one dye selected from the dyes represented by general formulae [I] to [V]: ##STR1## (wherein R.sub.1 and R.sub.2 each represents H, CH.sub.3, or OCH.sub.3 ; R.sub.3 represents H, Cl,CH.sub.3, or OCH.sub.3 ; R.sub.4 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, a tolyl group, or an anisyl group; R.sub.5 represents H, a phenyl group which may be substituted with a COOM group, or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; R.sub.6 represents H or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; X represents SO.sub.3 M or COOM; Y represents --CO-- or --SO.sub.2 --; m represents 1 or 2; n represents 0 or 1; A represents a phenylene group which may have one or more members selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, an amino group, a --COOM group, a hydroxyl group, an --SO.sub.3 M group, and a halogen atom; and M represents an alkali metal, an ammonium group, or an organic amine salt.)
    • 印刷质量,耐光性和耐水性优异的记录液,其特征在于,其含有水性介质和选自通式[I]〜[V]表示的染料中的至少一种染料: (IV)其中R 1和R 2各自表示H,CH 3或OCH 3; R 3表示H,Cl,CH 3或 OCH 3; R 4表示碳原子数1〜6的烷基,苯基,甲苯基或茴香基; R 5表示H,可以被COOM基取代的苯基或具有1〜 被COOM基团取代的3个碳原子; R6表示H或被COOM基团取代的具有1至3个碳原子的烷基; X表示SO 3 M或COOM; Y表示-CO-或-SO 2 - ; m表示 1或2; n表示0或1; A表示可以具有一个或多个选自具有1至4个碳的烷基的一个或多个的亚苯基 具有1至4个碳原子的烷氧基,氨基,-COOM基,羟基,-SO 3 M基和卤素原子; M表示碱金属,铵基或有机胺盐。
    • 3. 发明授权
    • Recording liquid
    • 记录液体
    • US5599386A
    • 1997-02-04
    • US445797
    • 1995-05-04
    • Hideo SanoYukichi MurataHiroshi Takimoto
    • Hideo SanoYukichi MurataHiroshi Takimoto
    • C09B29/30C09D11/00C09D11/02
    • C09D11/328C09B29/30
    • A recording liquid comprising an aqueous medium and at least one selected from the compounds whose free acid form is represented by the formula {1}: ##STR1## wherein, R.sup.1, R.sup.2 and R.sup.3 each independently represent a substituted or unsubstituted C.sub.1-9 alkyl group, a C.sub.1-9 alkoxy group, a halogen, hydrogen, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a C.sub.1-9 alkyl- or C.sub.6-15 aryl-sulfonyl group, a COOH group or a carboxylic ester group;m is a number of 0, 1 or 2; andR.sup.4, R.sup.5 and R.sup.6 each independently represent hydrogen, a C.sub.1-18 alkyl group, a C.sub.2-18 alkenyl group, an aryl group, an aralkyl group, an alicyclic group or a heterocyclic group, any of which groups except hydrogen may have a substituent.
    • 包含水性介质和选自游离酸形式的由式{1}表示的化合物中的至少一种的记录液体:其代表取代或未取代的C1-9烷基,C1-9烷氧基,卤素, 氢,羟基,取代或未取代的氨基甲酰基,取代或未取代的氨磺酰基,取代或未取代的氨基,硝基,磺酸酯基,C1-9烷基或C6-15芳基 - 磺酰基 ,COOH基或羧酸酯基; m是0,1或2的数字; R 4,R 5和R 6各自独立地表示氢,C 1-18烷基,C 2-18烯基,芳基,芳烷基,脂环族基或杂环基,除氢以外的基团可以具有 取代基。
    • 5. 发明申请
    • Water-soluble complex dye, recording fluid and recording method
    • 水溶性复合染料,记录液和记录方法
    • US20050081747A1
    • 2005-04-21
    • US11005021
    • 2004-12-07
    • Wataru ShimizuMio IshidaHideo SanoYukichi Murata
    • Wataru ShimizuMio IshidaHideo SanoYukichi Murata
    • C09B45/18C09B45/22C09B45/24C09B45/34C09B67/44C09D11/00C09B45/00
    • C09D11/32C09B45/18C09B45/22C09B45/24C09B45/34C09B67/0083C09D11/328C09D11/40
    • A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.
    • 能够形成具有耐光性,耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液,特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。 包含由下式(1)表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液,特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。 在式(1)中,A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团,并且可以具有任选的取代基,但它代表基团 在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环,键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。