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    • 6. 发明申请
    • ADHESIVES
    • 粘合剂
    • US20090227724A1
    • 2009-09-10
    • US12396063
    • 2009-03-02
    • Otto GansterJorg BuchnerHeinz-Werner LucasWolfgang Henning
    • Otto GansterJorg BuchnerHeinz-Werner LucasWolfgang Henning
    • B32B37/12C08L75/04
    • C08G18/8054C08G18/1875C08G18/225C08G18/3857C08G18/5024C08G18/798C08G2170/80C09D175/04Y10T156/10
    • Preparations of surface-deactivated solid isocyanates which are dispersed in finely particulate manner, with aqueous isocyanate-reactive polymer dispersions that include a) dispersed polymers having isocyanate-reactive groups, b) dispersed surface-deactivated oligomeric solid polyisocyanates, and c) at least one catalyst, where the catalyst or the totality of catalysts accelerates the reaction of the monomeric polyisocyanates which form by the thermal cleavage of the oligomeric polyisocyanates more strongly than the thermal cleavage itself. The preparations are prepared by mixing aqueous dispersions of at least one isocyanate-reactive polymer with at least one dispersed surface-deactivated oligomeric solid polyisocyanate and at least one catalyst. The preparations can be used in binders, films and powders for bonded joints, or coatings and to make a latently cross-linking adhesive layer. Substrates can be coated with layers obtainable with the above-described preparations.
    • 具有含异氰酸酯反应性聚合物分散体的表面去活固体异氰酸酯的制备,其包括a)具有异氰酸酯反应性基团的分散的聚合物,b)分散的表面失活的低聚固体多异氰酸酯,和c)至少一种 催化剂,其中催化剂或催化剂的总量加速单体多异氰酸酯的反应,其通过热裂解本身比热裂解低聚多异氰酸酯形成。 通过将至少一种异氰酸酯反应性聚合物的水分散体与至少一种分散的表面失活的低聚固体多异氰酸酯和至少一种催化剂混合来制备制剂。 该制剂可用于粘合剂,薄膜和粘合接头粉末或涂层,并制成潜在的交联粘合剂层。 可以用可用上述制剂获得的层涂覆底物。
    • 10. 发明授权
    • Process for the production of molded articles having integral skin
    • 用于生产具有整体皮肤的模制品的方法
    • US4576970A
    • 1986-03-18
    • US703844
    • 1985-02-21
    • Otto GansterUlrich KnippBruno Luckas
    • Otto GansterUlrich KnippBruno Luckas
    • C08G18/00C08G18/08C08G18/30C08G18/42C08G18/48C08G18/66C08G18/76C08G18/14C08G18/79
    • C08G18/6603C08G18/302C08G2120/00Y10T428/249989
    • The present invention is directed to a process for the production of a molded article having a compact surface layer and a gross density above 900 kg/m.sup.3 via the reaction injection molding technique, comprising introducing a reaction mixture into a closed mold, said reaction mixture comprising:(a) a polyisocyanate component consisting of at least one polyisocyanate in which all the isocyanate groups are aromatically bound,(b) compounds having molecular weights of from 400 to 12,000 and having at least two isocyanate reactive hydrogen atoms,(c) water, in a quantity of at least 0.15 mol per mol of isocyanate groups of component (a), and(d) optionally compounds having molecular weights of from 60 to 399 and having at least two isocyanate reactive hydrogen atoms,wherein the isocyanate index, based on all the reactants taking part in the reaction is from 70 to 125, and wherein a pressure of above 40 bar is maintained in the reaction mixture during the reaction so that the carbon dioxide formed in the course of the reaction remains completely or predominantly in solution in the reaction mixture and in the molded article produced.
    • 本发明涉及通过反应注射成型技术生产具有紧密表面层和总密度高于900kg / m 3的模塑制品的方法,包括将反应混合物引入封闭模具中,所述反应混合物包含 (a)由至少一种多异氰酸酯组成的多异氰酸酯组分,其中所有异氰酸酯基团都被芳族结合,(b)分子量为400至12,000并具有至少两个异氰酸酯反应性氢原子的化合物,(c)水, 每摩尔组分(a)的异氰酸酯基团至少为0.15摩尔的量,和(d)任选分子量为60至399的具有至少两个异氰酸酯反应性氢原子的化合物,其中异氰酸酯指数基于 参与反应的所有反应物均为70〜125,在反应中反应混合物中保持40巴以上的压力,使二氧化碳 在反应过程中形成的反应完全或主要存在于反应混合物和所制备的模制品中的溶液中。