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    • 1. 发明授权
    • Hydrophobic nanostructured thin films
    • 疏水性纳米结构薄膜
    • US08535805B2
    • 2013-09-17
    • US12430932
    • 2009-04-28
    • Melik C. DemirelWalter J DressickAlok Singh
    • Melik C. DemirelWalter J DressickAlok Singh
    • B32B27/00
    • C09D165/04B05D1/38B05D1/60B05D5/08B05D5/10C08F283/004C08G61/025C08G81/00C08G2261/3424C08G2261/61C09D155/00C09J7/00C09J2201/626Y10T428/2835Y10T428/31504
    • Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured poly(p-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
    • 本文提供的是下面所示的聚合物。 值n为正整数。 R1是有机基团,每个R2是H或化学吸附基团,其中至少一个R2是化学吸附基团。 聚合物可以是纳米结构膜。 本文还提供了一种方法:将二对二甲苯对环磷烷二聚体转化为单体的反应蒸气; 将反应蒸气沉积在相对于蒸气通量保持一定角度的基底上以形成纳米结构的聚(对二甲苯)膜; 如果该膜不含有氢原子,则该膜与试剂反应形成与化学吸附基团的前体反应的氢原子; 并使氢原子与前体反应。 本文还提供了在可枢转的基底上具有纳米结构的聚(对二甲苯)膜的装置。 该膜具有定向的疏水性或疏油性和定向粘合性。