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1. 发明授权

US6048945A Graft polymers comprising polymers, containing alkylene oxide units, and ethylenically unsaturated compounds, their preparation and their use 失效
标题翻译：包含含有烯化氧单元的聚合物和烯键式不饱和化合物的接枝聚合物，其制备及其用途
公开(公告)号：US6048945A
公开(公告)日：2000-04-11
申请号：US945546
申请日：1997-11-03
申请人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
发明人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
IPC分类号： C08B31/12 , C08F8/12 , C08F283/00 , C08F283/06 , C09B67/46 , C09D17/00 , D21H17/53 , D21H19/20 , D21H21/10 , D21H21/16 , D21H21/18 , D21H17/00 , D21H17/33 , D21H17/46
CPC分类号： D21H21/18 , C08F283/00 , C08F8/44 , C09B67/0085 , C09D17/00 , D21H21/10 , D21H21/16
摘要： A graft polymer obtained by free radically polymerizing:(A) a monomer or monomer mixture comprising:(a) from 10-100% by weight of a N-vinylcarboxamide of the formula: ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0-90% by weight of at least one other monoethylenically unsaturated monomer which is copolymerizable with (a), and(c) from 0-5% by weight of at least one monomer having at least two ethylenically unsaturated nonconjugated double bonds in the molecule, in the presence of(B) a polytetrahydrofuran or a polymer which contains at least 3 units of a C.sub.2 -C.sub.4 alkylene oxide and is a hornopolymer of C.sub.2-4 -alkylene oxide having two free terminal OH groups or random or block copolymers of C.sub.2-4 -alkylene oxides having two free terminal OH groups or the reaction products of C.sub.2-4 -alkylene oxides with phenols, amines or fatty carboxylic acids, in a weight ratio (A):(B) ranging from 95:5 to 10:80, some or all of the amide groups having been eliminated by hydrolysis.
摘要翻译： PCT No.PCT / EP96 / 01663 Sec。 371日期：1997年11月3日 102（e）日期1997年11月3日PCT 1996年4月20日PCT PCT。 WO96 / 34903 PCT出版物日期：1996年11月7日通过自由基聚合获得的接枝聚合物：（A）单体或单体混合物，其包含：（a）10-100重量％的下式的N-乙烯基甲酰胺：其中R1和R2各自为H 或（c）0-90重量％的至少一种其它单烯属不饱和单体，其可以与（a）和（c）0-5重量％的至少一种单体共聚，在（B）聚四氢呋喃或含有至少3个单元的C 2 -C 4环氧烷烃的聚合物存在下，分子中至少有两个烯属不饱和非共轭双键，并且是具有两个碳原子的C2-4-氧化烯的角质聚合物游离末端OH基团或具有两个自由末端OH基团的C 2-4亚烷基氧化物或C 2-4 - 烯化氧与酚，胺或脂肪羧酸的反应产物的重量比（A）：（B）的范围为95:5至10:80，部分或全部酰胺基已被水解除去。

2. 发明授权

US6060566A Graft polymers of polymers containing vinyl ester and/or vinyl alcohol units and ethylenically unsaturated compounds, their preparation and their use 失效
标题翻译：含有乙烯基酯和/或乙烯醇单元和烯键式不饱和化合物的聚合物的接枝聚合物，其制备及其应用
公开(公告)号：US6060566A
公开(公告)日：2000-05-09
申请号：US983141
申请日：1998-01-21
申请人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
发明人： Walter Denzinger , Martin Rubenacker , Claudia Nilz , Primoz Lorencak , Dietmar Monch , Rudolf Schuhmacher , Andreas Stange
IPC分类号： C08B37/00 , C08F8/12 , C08F261/04 , C08F263/02 , C08F283/06 , C08F291/00 , C09D7/45 , D21H17/34 , D21H17/37 , D21H21/10 , D21H21/14 , D21H21/16 , D21H21/18 , C08F263/04 , C08L51/04
CPC分类号： D21H17/37 , C08F261/04 , C08F263/02 , C08F8/12 , C08F8/44 , D21H21/10 , D21H21/146 , D21H21/16 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures comprising(a) from 1 to 100% by weight of N-vinylcarboxamides of the formula ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule,in the presence of(B) polymers which contain units of vinyl esters of saturated C.sub.1 -C.sub.4 -carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran,in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group ##STR2## from the polymerized monomers (I) of the graft polymer with formation of units of the formula ##STR3## and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.
摘要翻译： PCT No.PCT / EP96 / 02991 Sec。 371日期1998年1月21日 102（e）1998年1月21日PCT PCT 1996年7月9日PCT公布。第WO97 / 04014号公报日期1997年2月6日通过（A）单体或单体混合物的自由基聚合获得接枝聚合物，所述单体或单体混合物包含（a）1至100重量％的下式的N-乙烯基甲酰胺其中R 1和R 2各自为H或C 1 -C 6 - 烷基，（b）0至99重量％的可与单体（a）和（c）共聚的其它单烯属不饱和单体，0至5重量％的具有至少两个烯属不饱和的非共轭双键的单体分子，在（B）包含饱和C 1 -C 4羧酸和/或乙烯醇单元的乙烯基酯单元的聚合物存在下，或包含这些聚合物和具有至少3个烯化氧单元或聚四氢呋喃的聚合物的混合物的存在下，在95:5至10:90的重量比（A）：（B））中，如果需要，随后从形成下式的单元的接枝聚合物的聚合单体（I）中除去该基团，上述接枝聚合物用于制备纸，纸板和纸板作为干和湿强度剂，作为保留和引流助剂以及作为二烯酮上浆和淀粉阳离子化剂的促进剂，作为颜料的分散剂和用于生产薄纸的起皱助剂。

3. 发明授权

US5851300A Cationic modification of starch and use of the cationically modified starch 失效
标题翻译：淀粉的阳离子改性和阳离子改性淀粉的使用
公开(公告)号：US5851300A
公开(公告)日：1998-12-22
申请号：US817644
申请日：1997-04-29
申请人： Friedrich Linhart , Andreas Stange , Rudolf Schuhmacher , Heinrich Hartmann , Walter Denzinger , Manfred Niessner , Claudia Nilz , Wolfgang Reuther , Hubert Meixner
发明人： Friedrich Linhart , Andreas Stange , Rudolf Schuhmacher , Heinrich Hartmann , Walter Denzinger , Manfred Niessner , Claudia Nilz , Wolfgang Reuther , Hubert Meixner
IPC分类号： C08B31/12 , C08B31/00 , C08G73/02 , C08G81/00 , D21H17/29 , D21H21/18 , C08B30/12 , C08B30/00 , D21H11/00
CPC分类号： C08G73/0213 , C08B31/00 , C08G81/00 , D21H17/29 , D21H21/18
摘要： In a cationic modification process for starch, starch is reacted with polymers that contain amino and/or ammonium groups in an aqueous medium at temperatures from 115.degree. C. to 180.degree. C. under an increased pressure and in the absence of oxidizers, polymerization initiators and alkali. The reaction is conducted so that maximum 10% by weight starch has its molar weight reduced. Also disclosed is the use of the thus obtained reaction products as dry strength agents for paper.
摘要翻译： PCT No.PCT / EP95 / 04075第 371日期1997年04月29日 102（e）1997年4月29日PCT PCT 1995年10月17日PCT公布。第WO96 / 13525号公报日期1996年5月9日在淀粉的阳离子改性方法中，淀粉与含水氨基和/或铵基团的聚合物在115℃至180℃的温度下在升高的压力下和在不存在氧化剂，聚合引发剂和碱。进行反应使得最大10重量％的淀粉具有降低的摩尔重量。还公开了由此获得的反应产物作为纸的干强度剂的用途。

4. 发明授权

US5630907A Use of hydrolyzed copolymers of N-vinylcarboxamides and monoethylenically unsaturated carboxylic acids in papermaking 失效
标题翻译：在造纸中使用N-乙烯基甲酰胺和单烯属不饱和羧酸的水解共聚物
公开(公告)号：US5630907A
公开(公告)日：1997-05-20
申请号：US651655
申请日：1996-05-21
申请人： Claudia Nilz , Walter Denzinger , Heinrich Hartmann , Michael Kroener , Friedrich Linhart , Rudolf Schuhmacher , Dietmar Moench , Andreas Stange
发明人： Claudia Nilz , Walter Denzinger , Heinrich Hartmann , Michael Kroener , Friedrich Linhart , Rudolf Schuhmacher , Dietmar Moench , Andreas Stange
IPC分类号： C08F8/12 , D21H21/10
CPC分类号： C08F8/12 , C08J5/18 , C08F2810/50
摘要： Copolymers which are obtained by copolymerization ofa) from 5 to 99 mol % of N-vinylcarboxamides,b) from 95 to 1 mol % of monoethylenically unsaturated carboxylic acids and/or the alkali metal, alkaline earth metal, ammonium or amine salts thereof, and if required,c) up to 30 mol % of other monoethylenically unsaturated compounds, and if required,d) up to 2 mol % of crosslinking agents,and subsequent partial or complete elimination of the acyl groups from the N-vinylcarboxamides polymerized in the copolymer, with formation of amino or ammonium groups, are used as additives to paper stock for increasing the drainage rate and the retention in papermaking, and the dry and wet strength of the paper.
摘要翻译：通过a）5〜99摩尔％的N-乙烯基酰胺共聚得到的共聚物，b）95〜1摩尔％的单烯属不饱和羧酸和/或其碱金属，碱土金属，铵或胺盐，并且如果需要，c）至多30mol％的其它单烯键式不饱和化合物，如果需要，d）最多达2mol％的交联剂，随后部分或完全消除由乙烯基酰胺聚合的N-乙烯基酰胺共聚物，形成氨基或铵基，被用作纸浆的添加剂，以增加造纸中的排水速率和保留性，以及纸的干和湿强度。

5. 发明授权

US6114435A Preparation of aqueous solutions of polymers containing vinylamine units, which solutions have a long shelf life, and their use 失效
标题翻译：含有乙烯胺单元的聚合物的水溶液的制备，该溶液具有长的保质期及其用途
公开(公告)号：US6114435A
公开(公告)日：2000-09-05
申请号：US716280
申请日：1996-09-30
申请人： Claudia Nilz , Manfred Winter , Michael Kroner , Andreas Stange , Rudolf Schuhmacher
发明人： Claudia Nilz , Manfred Winter , Michael Kroner , Andreas Stange , Rudolf Schuhmacher
IPC分类号： C08F8/12 , D21H17/34 , D21H21/18 , D21H21/20 , C08L39/02
CPC分类号： D21H21/20 , C08F8/12 , D21H17/34 , D21H21/18 , C08F2800/20
摘要： Solutions of polymers containing vinylamine units, which solutions have a long shelf life, are prepared by hydrolyzing polymers containing N-vinylcarboxamide units with acids in an aqueous medium and removing the carboxylic acids eliminated from the polymers as esters from the aqueous polymer solution after the hydrolysis by adding at least stoichiometric amounts of at least one C.sub.1 -C.sub.6 -alcohol and distilling off the esters from the reaction mixture, and said aqueous solutions are used as dry and wet strength agents in papermaking.
摘要翻译： PCT No.PCT / EP95 / 01030 Sec。 371日期1996年9月30日 102（e）1996年9月30日PCT PCT 1995年3月20日PCT公布。公开号WO95 / 26989 日期1995年10月12日含有乙烯基胺单元的聚合物的溶液具有长的保存期限，其通过在水性介质中水解含有N-乙烯基甲酰胺单元的聚合物和酸从聚合物中除去作为酯的羧酸从水溶液通过加入至少一种化学计量的至少一种C 1 -C 6醇并从反应混合物中蒸馏出酯，水解后的聚合物溶液，并将所述水溶液用作造纸中的干和湿强度剂。

6. 发明授权

US5334287A Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturated compounds and their use 失效
标题翻译：含有糖结构或其衍生物和烯属不饱和化合物的天然物质的接枝聚合物及其用途
公开(公告)号：US5334287A
公开(公告)日：1994-08-02
申请号：US914926
申请日：1992-07-17
申请人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
发明人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
IPC分类号： C08F251/02 , C08F251/00 , D21H17/34 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/06 , D21H21/10
CPC分类号： C08F251/00 , D21H17/35 , D21H17/375 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
摘要翻译：接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的单烯属不饱和单体0-5重量％的分子中含有两个或更多个烯属不饱和的非共轭双键的单体含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

7. 发明授权

US5578678A Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturated compounds and their use 失效
标题翻译：含有糖结构或其衍生物和烯属不饱和化合物的天然物质的接枝聚合物及其用途
公开(公告)号：US5578678A
公开(公告)日：1996-11-26
申请号：US229636
申请日：1994-04-19
申请人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
发明人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
IPC分类号： C08F251/02 , C08F251/00 , D21H17/34 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/06 , D21H21/10
CPC分类号： C08F251/00 , D21H17/35 , D21H17/375 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
摘要翻译：接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的单烯属不饱和单体0-5重量％的分子中含有两个或更多个烯属不饱和的非共轭双键的单体含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

8. 发明授权

US5543459A Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturated compounds and their use 失效
标题翻译：含有糖结构或其衍生物和烯属不饱和化合物的天然物质的接枝聚合物及其用途
公开(公告)号：US5543459A
公开(公告)日：1996-08-06
申请号：US401617
申请日：1995-03-09
申请人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
发明人： Heinrich Hartmann , Walter Denzinger , Michael Kroener , Claudia Nilz , Friedrich Linhart , Andreas Stange
IPC分类号： C08F251/02 , C08F251/00 , D21H17/34 , D21H17/35 , D21H17/37 , D21H21/18 , D21H21/06 , D21H21/10
CPC分类号： C08F251/00 , D21H17/35 , D21H17/375 , D21H21/18
摘要： Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
摘要翻译：接枝聚合物可以通过（A）单体或单体混合物（a）的自由基聚合获得，所述单体或单体混合物为（a）10至100重量％的开链N-乙烯基酰胺（b），0至90重量％的其它无羧基在（B）天然物质的存在下，可以与单体（a）和（c）共聚合的0〜5重量％的分子中含有2个以上烯属不饱和的非共轭双键的单体的单体不饱和单体含有糖结构，例如单糖，寡糖和多糖，重量比（A）：（B）为95:5至20:80，如果需要，随后水解聚合单体的酰胺基 a）形成氨基的接枝聚合物，并且所述聚合物用作纸，纸板和纸板的干和湿强度剂。

9. 发明授权

US06746542B1 Modifying starch with cationic polymers and use of the modified starches as dry-strength agent 失效
标题翻译：用阳离子聚合物改性淀粉，使用改性淀粉作为干强剂
公开(公告)号：US06746542B1
公开(公告)日：2004-06-08
申请号：US09926230
申请日：2001-09-27
申请人： Primoz Lorencak , Andreas Stange , Kurt Diehl , Norbert Mahr
发明人： Primoz Lorencak , Andreas Stange , Kurt Diehl , Norbert Mahr
IPC分类号： C08B3012
CPC分类号： D21H21/20 , C08B31/00 , C08B31/185 , C08L3/00 , C08L3/02 , C08L3/10 , D21H17/29 , C08L2666/02
摘要： A process for modifying starch by heating starch in an aqueous medium to temperatures above the gelatinization temperature of said starch comprises effecting said modifying of said starch in the presence of (a) a polymeric cationizer selected from the group consisting of the polymers containing vinylamine units and having molar masses of up to 1 million, the polyethyleneimines, the polydiallyldimethylammonium chlorides, the condensates of dimethylamine with epichlorohydrin or dichloroalkanes, the condensates of dichloroethane and ammonia, and the mixtures thereof, and (b) polymeric papermaking drainage aids selected from the group consisting of the water-soluble crosslinked polyamidoamines with or without an ethyleneimine graft, the polymers containing acrylamide and/or methacrylamide units and having molar masses of more than 1 million, the polymers containing vinylamine units and having molar masses of more then 1 million, and the mixtures thereof.
摘要翻译：通过将水性介质中的淀粉加热至高于所述淀粉糊化温度的温度来改性淀粉的方法包括在（a）聚合阳离子化剂存在下进行所述淀粉的所述改性，所述聚合阳离子化剂选自含有乙烯胺单元的聚合物和摩尔质量高达100万，聚二烯丙基二甲基氯化铵，二甲基胺与表氯醇或二氯烷烃的缩合物，二氯乙烷和氨的缩合物及其混合物，和（b）聚合物造纸引流助剂，选自具有或不具有乙烯亚胺接枝的水溶性交联聚酰胺胺的聚合物，含有丙烯酰胺和/或甲基丙烯酰胺单元并且摩尔质量大于100万的聚合物，所述聚合物含有乙烯胺单元并且具有大于100万的摩尔质量，其混合物。

10. 发明授权

US06616807B1 Method for producing high dry-strength paper, pulpboard and cardboard 有权
标题翻译：生产高强度干纸，纸板和纸板的方法
公开(公告)号：US06616807B1
公开(公告)日：2003-09-09
申请号：US09381970
申请日：1999-10-01
申请人： Rainer Dyllick-Brenzinger , Primoz Lorencak , Hubert Meixner , Peter Baumann , Ellen Krüger , Andreas Stange , Martin Rübenacker
发明人： Rainer Dyllick-Brenzinger , Primoz Lorencak , Hubert Meixner , Peter Baumann , Ellen Krüger , Andreas Stange , Martin Rübenacker
IPC分类号： D21H2110
CPC分类号： D21H21/10 , D21H17/29 , D21H17/45 , D21H17/455 , D21H17/55 , D21H17/56 , D21H21/18 , D21H23/765
摘要： Paper, board and cardboard having high dry strength are produced by the addition of cationic, anionic and/or amphoteric starch as dry strength agents to the paper stock and drainage of the paper stock with sheet formation in the presence of cationic polymers as retention aids for starch, and cationic polymeric retention aids are used for increasing the retention of dry strength agents comprising cationic, anionic and/or amphoteric starch in the production of paper, board and cardboard.
摘要翻译：具有高干燥强度的纸，纸板和纸板通过在阳离子聚合物作为助留剂的存在下，将作为干强度剂的阳离子，阴离子和/或两性淀粉作为干燥强度剂加入到纸料中，淀粉和阳离子聚合物助留剂用于在纸，纸板和纸板的生产中增加包含阳离子，阴离子和/或两性淀粉的干强度剂的保留性。

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