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    • 7. 发明授权
    • Method of selectively hydrogenating ethylenically unsaturated double bonds in polymers
    • 在聚合物中选择性氢化烯属不饱和双键的方法
    • US06696518B1
    • 2004-02-24
    • US09926625
    • 2001-11-27
    • Rolf DerschHeiko MaasVolker Schädler
    • Rolf DerschHeiko MaasVolker Schädler
    • C08L3310
    • C08C19/02C08F8/04C09D1/04
    • The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.
    • 本发明涉及通过使至少一种聚合物P的水性分散体与氢在至少一种包含至少一种选自铑和/或其中的过渡金属的氢化催化剂的存在下,使聚合物P中的烯属不饱和双键氢化的方法, 钌和能够与过渡金属形成配位化合物的至少一种非离子型磷化合物,其包括在不添加溶剂的情况下将氢化催化剂并入聚合物P的水性分散体。 本发明还涉及通过该方法获得的氢化聚合物P的水分散体和包含这种分散体的涂料组合物。
    • 10. 发明授权
    • Impact modifiers prepared from (partially) hydrogenated butadiene-containing dispersions
    • 由(部分)含氢化丁二烯的分散体制备的抗冲改性剂
    • US06566457B2
    • 2003-05-20
    • US09825957
    • 2001-04-05
    • Peter BarghoornVolker SchädlerHeiko MaasNorbert Niessner
    • Peter BarghoornVolker SchädlerHeiko MaasNorbert Niessner
    • C08F804
    • C08F279/02C08F212/06
    • The invention relates to a process for preparing graft rubbers built up from at least one graft core and from at least one graft shell, comprising a) preparing an aqueous dispersion of at least one elastomeric polymer, b) then, to obtain the at least one graft core, selectively hydrogenating ethylenically unsaturated double bonds in the elastomeric polymer, using hydrogen, in the presence of at least one hydrogenation catalyst, where the aqueous dispersion of the elastomeric polymer comprises not more than 20% by volume of an organic solvent, and c) grafting onto the graft core at least one graft shell, and also to the corresponding graft rubbers. The invention further relates to blends comprising a) from 2 to 70% by weight of a graft rubber according to the invention, as component A, b) from 30 to 98% by weight of a thermoplastic polymer or of a mixture of various thermoplastic polymers, as component B, and c) from 0 to 50% by weight of other additives, as component C, where the entirety of components A to C is 100% by weight, based on the blend.
    • 本发明涉及一种用于制备由至少一个接枝芯和至少一个接枝壳构成的接枝橡胶的方法,该方法包括:a)制备至少一种弹性体聚合物的水性分散体,b)然后b)得到至少一个接枝 在至少一种氢化催化剂的存在下,使用氢气在弹性体聚合物中选择性氢化烯键式不饱和双键,其中弹性体聚合物的水分散体包含不超过20体积%的有机溶剂,和c)接枝 在接枝芯上至少一个接枝壳,以及相应的接枝橡胶。本发明还涉及包含a)2-70重量%的根据本发明的接枝橡胶作为组分A,b)从30 至98重量%的热塑性聚合物或作为组分B的各种热塑性聚合物的混合物,和c)0至50重量%的其它添加剂作为组分C,其中全部Co 基于混合物,组分A至C为100重量%。