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1. 发明授权

US4167405A Fertilizers for supplying plants with iron 失效
标题翻译：供应植物铁的肥料
公开(公告)号：US4167405A
公开(公告)日：1979-09-11
申请号：US865479
申请日：1977-12-29
申请人： Volker Mues , Johannes Niggemann
发明人： Volker Mues , Johannes Niggemann
IPC分类号： C05D9/02 , C07F15/02 , C07F17/02 , C05F11/00
CPC分类号： C07F17/02 , C05D9/02 , Y10S71/02
摘要： A method of supplying plants with iron which comprises applying to the plants, or to the substrate in which they grow, at least one ferrocene derivative of the formula ##STR1## wherein R represents alkyl with 3 to 20 carbon atoms, preferably 7 to 20 carbon atoms, alone or in admixture with a diluent or carrier.
摘要翻译：给植物提供铁的方法，其包括向植物或其生长的基质施用至少一种下式的二茂铁衍生物（I），其中R表示具有3至20个碳原子的烷基，优选7 至20个碳原子，单独或与稀释剂或载体混合。

2. 发明授权

US4053296A Ferrocene derivative for supplying plants with iron 失效
标题翻译：用于供应铁矿石的FERROCENE DERIVATIVE
公开(公告)号：US4053296A
公开(公告)日：1977-10-11
申请号：US721736
申请日：1976-09-09
申请人： Volker Mues , Johannes Niggemann
发明人： Volker Mues , Johannes Niggemann
IPC分类号： C05D9/02 , C07F9/6518 , C07F15/02 , C07F17/02 , C05F11/10
CPC分类号： C07F17/02 , C05D9/02 , Y10S71/02
摘要： Ferrocene derivatives of the formula ##STR1## IN WHICH R represents the group COOR.sup.1,in whichR.sup.1 represents hydrogen, alkyl, one equivalent of an alkali metal, alkaline earth metal or heavy metal cation, or an ammonium cation in which one or moreHydrogen atoms can be replaced by alkyl,Or R represents the group COR.sup.2in whichR.sup.2 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted cycloalkenyl or optionally substituted phenyl,OrR represents the group ##STR2## in which R.sup.3 represents hydrogen or alkyl andR.sup.4 represents a ureido or thioureido radical, a radical of the formula --CH.sub.2 --CH.sub.2 --N.dbd.CH--ferrocene, a 5-membered or 6-membered heterocyclic radical or a group of the formula --OR.sup.5 or --NH-R.sup.6,in whichR.sup.5 represents hydrogen, alkyl, one equivalent of an alkali metal or alkaline earth metal cation, or an ammonium cation in which one or more hydrogen atoms canbe replaced by alkyl, andR.sup.6 represents aryl or a 5-membered or 6-membered heterocyclic radical,OrR represents the sulfonamide group or the radical --SO.sub.3 R.sup.7,in whichR.sup.7 represents hydrogen, alkyl, one equivalent of an alkali metal or alkaline earth metal cation, or an ammonium cation in which one or more hydrogen atoms can be replaced by alkyl,Or p1 R represents an alkyl, aralkyl or aryl radical which can be substituted by hydroxyl, cyano, COOR.sup.1 or ##STR3## in which R.sup.1 has the above-mentioned meansing,R', r" and R'", independently of one another, each represent hydrogen or alkyl andA.sup.- represents halide or methosulfate, are outstandingly effective for supplying plants with the micro-nutrient iron.

3. 发明授权

US4141714A Fertilizers for supplying plants with micronutrients 失效
公开(公告)号：US4141714A
公开(公告)日：1979-02-27
申请号：US869885
申请日：1978-01-16
申请人： Volker Mues , Johannes Niggemann
发明人： Volker Mues , Johannes Niggemann
IPC分类号： C05D9/02 , C07F15/02 , C05C5/00
CPC分类号： C07F15/02 , C07F15/025 , Y10S71/02
摘要： A fertilizer composition for supplying plants with nutrient iron containing as an active ingredient at least prussiate of the formula ##STR1## in which M represents an alkali metal ion, alkaline earth metal ion, heavy metal ion or ammonium ion or a proton,R.sup.1, r.sup.2, r.sup.3 and R.sup.4, independently of one another, each represent hydrogen, alkyl, hydroxyalkyl, cycloalkyl, optionally substituted aryl or aralkyl orR.sup.1, together with R.sup.2, and/or R.sup.3, together with R.sup.4, represent an alkylene group, a bis-alkylene ether group or a bis-alkylene thioether group or, together with the adjacent nitrogen atom, form an unsaturated heterocyclic ring, orR.sup.2 and R.sup.4 each represent hydrogen, alkyl or hydroxyalkyl and at the same timeR.sup.1 and R.sup.3 together represent an alkylene group,X represents an alkylene group, hydroxyalkylene group, cycloalkylene group, bis-alkylenecycloalkylene group, bis-alkylene ether group, tris-alkylene diether group, bis-alkylene thioether group or bis-alkyleneamino group,A represents 1 or 2 andB represents 1, 2, 3, or 4.Also disclosed are certain new prussiates falling within the formula given above and their method of preparation.

4. 发明授权

US4047921A Treating micro-nutrient deficiencies in plants 失效
标题翻译：处理植物微量营养缺乏症
公开(公告)号：US4047921A
公开(公告)日：1977-09-13
申请号：US668151
申请日：1976-03-18
申请人： Volker Mues , Johannes Niggemann
发明人： Volker Mues , Johannes Niggemann
IPC分类号： C05D9/02 , C05F11/00
CPC分类号： C05D9/02 , Y10S71/02 , Y10S71/903 , Y10S71/904
摘要： Plants suffering from micro-nutrient deficiences are treated with prussiates of the formulaM.sub.a [Fe(CN).sub.5 X].sub.bIn whichM is an alkali metal ion, alkaline earth metal ion, heavy metal ion, ammonium ion or hydrogen,X is a group which can occupy the sixth coordination position on the iron, or a suitable organic radical,A is 2, 3, 4 or 5, andB is 1, 2 or 3.The prussiate may be present as a hydrate and/or may be in admixture with a carrier.
摘要翻译：用微量营养缺乏的植物用马氏体[Fe（CN）5X] b的混合物处理，其中M是碱金属离子，碱土金属离子，重金属离子，铵离子或氢，X是一个基团它可以占据铁上的第六个协调位置，或者合适的有机基团，即A 2，3，4或5，和B是1,2或3。

5. 发明授权

US4589906A Inorganic depot fertilizers 失效
标题翻译：无机贮库肥料
公开(公告)号：US4589906A
公开(公告)日：1986-05-20
申请号：US479772
申请日：1983-03-28
申请人： Horst Brunn , Johannes Niggemann , Peter Kohler , Franz Hund
发明人： Horst Brunn , Johannes Niggemann , Peter Kohler , Franz Hund
IPC分类号： C05D9/02 , C05D11/00 , A01N59/00
CPC分类号： C05D9/02
摘要： A depot fertilizer composition comprising an inorganic matrix and another inorganic and/or organic component of the formulaX Me(II)O.[(1-x)/2]Me(III).sub.2 O.sub.3.YA.zI.aqin whichMe (II) is at least one divalent metal,Me(III) is at least one trivalent metal,A is at least one inorganic acid or anhydride of an inorganic acid,I is at least one organic compound,aq is 0-9,X is from 0 to 1,Y is from 0.5 to 0.7, andZ is from 0 to 20,at least one of the components containing a plant nutrient element. The compositions are suited for fertilizing the leaves or full systems of plants growing in soil or in water.
摘要翻译：一种贮存肥料组合物，其包含无机基质和式X Me（II）O。[（1-x）/ 2] Me（III）2 O 3 .YA.zI.aq的另一种无机和/或有机组分，其中Me（ II）是至少一种二价金属，Me（III）是至少一种三价金属，A是至少一种无机酸的无机酸或酸酐，I是至少一种有机化合物，aq是0-9，X是 0至1，Y为0.5至0.7，Z为0至20，至少一种组分含有植物营养元素。所述组合物适合于对在土壤或水中生长的植物的叶子或全部系统施肥。

6. 发明授权

US4334905A Agrochemical agents and their use 失效
标题翻译：农药代理及其用途
公开(公告)号：US4334905A
公开(公告)日：1982-06-15
申请号：US189261
申请日：1980-09-22
申请人： Kuno Wagner , Johannes Niggemann , Kurt Findeisen , Hans Scheinpflug
发明人： Kuno Wagner , Johannes Niggemann , Kurt Findeisen , Hans Scheinpflug
IPC分类号： C09K17/00 , C05C11/00 , C09K17/14 , C09K17/18 , C09K101/00
CPC分类号： C09K17/18 , C05C11/00 , Y10S71/02 , Y10S71/903
摘要： Azulmic acids, stabilized by condensation with carbonyl compounds, containing from 0.5 to 55 percent by weight of ionic groups of the formula ##STR1## in which R represents hydrogen, ammonium, one equivalent of a protonated or quaternized organic nitrogen base or of a sulphonium cation or one equivalent of a metal cation,and containing from 0.5 to 15 percent by weight of groups formed by decarboxylation reaction of the formula ##STR2## and acid addition salts and complex compounds of these stabilized azulmic acids, and also mixed products of these stablized azulmic acids with additives can be used as agrochemicals. The products are particularly useful as fertilizers and as soil improving agents.
摘要翻译：通过与羰基化合物缩合而稳定的唾液酸，其含有0.5至55重量％的下式的离子基团（F1），其中R表示氢，铵，1当量的质子化或季铵化的有机氮基，或锍阳离子或一当量的金属阳离子，并且含有0.5至15重量％的由式（F2）的脱羧反应形成的基团和这些稳定的薁酸的酸加成盐和络合物，以及这些稳定的唾液酸与添加剂的混合产物可用作农业化学品。该产品特别适用于肥料和土壤改良剂。

7. 发明授权

US4322237A Preserving cut flowers with N-(trifluoromethyl)-N-(dichlorofluoromethylsulphenyl)-aminobenzoic acids 失效
标题翻译：用N-（三氟甲基）-N-（二氯氟甲基亚磺酰基） - 氨基苯甲酸保存切花
公开(公告)号：US4322237A
公开(公告)日：1982-03-30
申请号：US185829
申请日：1980-09-10
申请人： Johannes Niggemann , Engelbert Kuhle , Erich Klauke
发明人： Johannes Niggemann , Engelbert Kuhle , Erich Klauke
IPC分类号： A01N3/00 , A01N3/02
CPC分类号： A01N3/00 , A01N3/02
摘要： A method of preserving cut flowers and other parts of plants which have been cut off, comprising placing the flowers or parts of plants in water containing an N-(trifluoromethyl)-N-(dichlorofluoromethylsulphenyl)-aminobenzoic acid, or salt thereof, of the formula ##STR1## in which M is hydrogen or 1 equivalent of an alkali metal atom or of an alkaline earth metal atom, andR is hydrogen, methyl, methoxy, trifluoro-methyl, chlorine or nitro.The active material can be employed in the form of a composition also containing water, a carbohydrate and a salt of magnesium, boron or aluminum. It can be held as a dry concentrate on a carrier such as kieselguhr, a natural or synthetic zeolite or alumina.
摘要翻译：一种保存切割的切花和植物的其他部分的方法，包括将植物的花或部分置于含有N-（三氟甲基）-N-（二氯氟甲基磺酰基） - 氨基苯甲酸或其盐的水中式中，M为氢或1当量碱金属原子或碱土金属原子，R为氢，甲基，甲氧基，三氟甲基，氯或硝基。活性物质可以以还含有水，碳水化合物和镁，硼或铝的盐的组合物的形式使用。它可以作为干燥浓缩物保持在诸如硅藻土，天然或合成沸石或氧化铝的载体上。

8. 发明授权

US4283219A Agrochemical agents and their use 失效
标题翻译：农药代理及其用途
公开(公告)号：US4283219A
公开(公告)日：1981-08-11
申请号：US63602
申请日：1979-08-03
申请人： Kuno Wagner , Johannes Niggemann , Kurt Findeisen , Hans Scheinpflug
发明人： Kuno Wagner , Johannes Niggemann , Kurt Findeisen , Hans Scheinpflug
IPC分类号： C05C11/00 , C09K17/18 , C05C9/00
CPC分类号： C05C11/00 , C09K17/18 , Y10S71/904
摘要： The present invention relates to agrochemical agents of products based on azulmic acids stabilized by reaction with aminoplast-forming agents and carbonyl compounds or condensation products thereof.
摘要翻译：本发明涉及基于通过与氨基塑料形成剂和羰基化合物或其缩合产物反应而稳定的薁酸的产品的农药。

9. 发明授权

US3970618A Process for the production of polyurethane foams 失效
标题翻译：生产聚氨酯泡沫的方法
公开(公告)号：US3970618A
公开(公告)日：1976-07-20
申请号：US438052
申请日：1974-01-30
申请人： Gert Jabs , Gunther Loew , Johannes Niggemann
发明人： Gert Jabs , Gunther Loew , Johannes Niggemann
IPC分类号： C08G18/00 , A01G31/00 , C08G18/32 , C08G18/48 , C08G18/50 , C08G18/72 , C08G18/78 , C08G18/79 , C08G18/14 , C08G18/77
CPC分类号： C08G18/5021 , A01G31/001 , C08G18/32 , C08G18/48 , C08G18/4804 , C08G18/482 , C08G18/72 , C08G18/78 , A01G2031/003 , C08G2101/005 , C08G2101/0083 , C08G2310/00 , Y10S521/905
摘要： Process for the production of a hydrophilic polyurethane foam having a high water retention capacity by reacting a polyhydroxyl compound having an OH number from 900-1800 and a polyisocyanate containing an aromatically bound isocyanate group and containing a urethane, urea, carbodiimide, allophanate, isocyanurate or biuret group.
摘要翻译：通过使具有900-1800的OH值的多羟基化合物与含有芳香族结合的异氰酸酯基并含有氨基甲酸酯，脲，碳二亚胺，脲基甲酸酯，异氰脲酸酯或异氰脲酸酯的多异氰酸酯反应生产具有高保水能力的亲水性聚氨酯泡沫体的方法缩二份组。

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