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1. 发明授权

US5158928A Azo dyes for thermotransfer printing 失效
标题翻译：用于热转印打印的AZO染色
公开(公告)号：US5158928A
公开(公告)日：1992-10-27
申请号：US652771
申请日：1991-02-08
申请人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/035 , B41M5/132 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , C09B29/36 , C09B53/00 , D06P5/13
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes useful for thermotransfer printing have the formula ##STR1##
摘要翻译：用于热转印印刷的偶氮染料具有式（1）式

2. 再颁专利

USRE34877E Azo dyes for thermotransfer printing 失效
标题翻译：用于热转印的偶氮染料
公开(公告)号：USRE34877E
公开(公告)日：1995-03-14
申请号：US166103
申请日：1993-12-14
申请人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/035 , B41M5/132 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , C09B29/36 , C09B53/00 , D06P5/13 , B41M5/38
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes useful for thermotransfer printing have the formula ##STR1##
摘要翻译：用于热转印印刷的偶氮染料具有式（1）式

3. 发明授权

US5200386A Azo dyes for thermotransfer printing 失效
标题翻译：用于热转印打印的AZO染色
公开(公告)号：US5200386A
公开(公告)日：1993-04-06
申请号：US708371
申请日：1991-05-31
申请人： Ruediger Sens , Helmut Reichelt , Sabine Gruettner , Karl-Heinz Etzbach , Gunther Lamm
发明人： Ruediger Sens , Helmut Reichelt , Sabine Gruettner , Karl-Heinz Etzbach , Gunther Lamm
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , D06P5/13
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes useful for thermotransfer printing have the formula ##STR1## where the substituents have the following meanings: X is a radical of the formula IIa or IIb ##STR2## R.sup.1 is H, C.sub.1 -C.sub.6 -alkyl or phenyl which may be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -alkoxy, chlorine, bromine or cyano,R.sup.2 is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine, n is 1 or 2, K is a radical of a coupling component IIH--K III of the aniline, aminonaphthaline, pyrazole, diaminopyridine, hydroxypyridone or tetrahydroquinoline series.
摘要翻译：可用于热转印印刷的偶氮染料具有式（I）其中取代基具有以下含义：X是式IIa或IIb的基团R 1 O（CH 2）或者IIa IIb R 1是H，C 1 -C 6烷基或可被C 1 -C 4 - 烷基，C 1 -C 2 - 烷氧基，氯，溴或氰基取代的苯基，R 2为H，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，氯或溴，n为1或2 K是苯胺，氨基萘，吡唑，二氨基吡啶，羟基吡啶酮或四氢喹啉系的偶联组分II HK III的基团。

4. 发明授权

US5037798A Transfer of AZO dyes 失效
标题翻译：转移AZO染料
公开(公告)号：US5037798A
公开(公告)日：1991-08-06
申请号：US358142
申请日：1989-05-30
申请人： Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Ruediger Sens
发明人： Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Ruediger Sens
IPC分类号： B41M1/36 , B41M5/26 , B41M5/30 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , C09B29/02 , D06P5/00 , D06P5/13
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes are transferred from a substrate to a plastic-coated paper by diffusion with the aid of a thermal printing head, these azo dyes having the formula ##STR1## where R.sup.1 and R.sup.2 are each independently of the other hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted phenyl,R.sup.3 is hydrogen, alkyl, alkoxy or substituted or unsubstituted alkanoyl- or benzoyl-amino,R.sup.4 is hydrogen, chlorine, alkyl, alkoxy, alkylthio or substituted or unsubstituted phenyl andR.sup.5 is cyano, substituted or unsubstituted alkoxy- or phenoxy-carbonyl or substituted or unsubstituted mono- or di-alkyl- or -phenyl-carbamoyl.
摘要翻译：偶氮染料借助于热敏印刷头通过扩散从基底转移到塑料涂布的纸上，这些偶氮染料具有式“IMAGE”，其中R 1和R 2各自独立于另一个氢，取代或未取代的烷基或取代或未取代的苯基，R3是氢，烷基，烷氧基或取代或未取代的烷酰基或苯甲酰氨基，R4是氢，氯，烷基，烷氧基，烷硫基或取代或未取代的苯基，R5是氰基，取代或未取代的烷氧基 - 或苯氧基 - 羰基或取代或未取代的单 - 或二 - 烷基 - 或 - 苯基 - 氨基甲酰基。

5. 发明授权

US4939118A Transfer of azo dyes having a pyridine coupling component 失效
标题翻译：具有吡啶偶联成分的偶氮染料的转移
公开(公告)号：US4939118A
公开(公告)日：1990-07-03
申请号：US364153
申请日：1989-06-12
申请人： Karl-Heinz Etzbach , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Ruediger Sens
发明人： Karl-Heinz Etzbach , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C09B29/42 , D06P5/13
CPC分类号： B41M5/388 , C09B29/3639 , Y10S428/913 , Y10S428/914
摘要： Azo dyes are transferred from a substrate to a plastic-coated paper by diffusion with the aid of a thermal printing head, these azo dyes having the formula ##STR1## where D is the radical of a diazo component andR.sup.1, R.sup.2 and R.sup.3 are each independently of the others hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted phenyl or substituted or unsubstituted cyclohexyl andR.sup.4 is alkyl.
摘要翻译：偶氮染料借助于热敏印刷头通过扩散从基材转移到塑料涂布纸上，这些具有式“IMAGE”的偶氮染料其中D是重氮组分的基团，R1，R2和R3各自为独立于其它氢，取代或未取代的烷基，取代或未取代的苯基或取代或未取代的环己基，R4是烷基。

6. 发明授权

US5147845A Triazolopyridine dyes and thermal transfer of methine dyes 失效
标题翻译：三唑并吡啶染料和甲基染料的热转移
公开(公告)号：US5147845A
公开(公告)日：1992-09-15
申请号：US743191
申请日：1991-08-09
申请人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
发明人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
IPC分类号： C09B26/02 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C07D471/04 , C09B23/00 , C09B23/04 , C09B23/16 , C09B53/00 , C09B55/00 , C09B57/00 , D06P5/00 , D06P5/13
CPC分类号： B41M5/3856 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Triazolopyridine dyes useful for thermal transfer of methine dyes have the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl, which may be substituted and interrupted by one or more oxygen atoms, or is substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a 5- or 6-membered carbocyclic or heterocyclic ring which may be substituted and benzofused,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is oxygen or a radical of the formula ##STR2## where L.sup.1 is in each case C.sub.1 -C.sub.8 -alkyl which may be interrupted by 1 or 2 oxygen atoms, andX is CH or nitrogen.

7. 发明授权

US5101035A Merocyanine-like thiazole dyes and thermal transfer thereof 失效
标题翻译：类似马来酰亚胺的噻唑染料及其转印
公开(公告)号：US5101035A
公开(公告)日：1992-03-31
申请号：US571900
申请日：1990-08-24
申请人： Volker Bach , Karl-Heinz Etzbach , Gunther Lamm , Ruediger Sens , Klaus Unterforsthuber , Rosemarie Rausch-Krebs
发明人： Volker Bach , Karl-Heinz Etzbach , Gunther Lamm , Ruediger Sens , Klaus Unterforsthuber , Rosemarie Rausch-Krebs
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C07D277/42 , C09B23/16 , C09B53/00 , C09B55/00 , D06P5/13
CPC分类号： B41M5/39 , C09B55/009
摘要： Useful thermal transfer dyes are thiazole dyes having the formula ##STR1## where R.sup.1 and R.sup.2 are each, independently of the other, hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted phenyl or cyclohexyl or together with the linking nitrogen atom a heterocyclic radical,R.sup.3 is hydrogen, halogen, alkyl, substituted or unsubstituted phenyl, benzyl, cyclohexyl, hydroxyl, furyl or thienyl, andA is a cyclohexadienone radical which may be substituted and/or benzofused.
摘要翻译：有用的热转印染料是具有式“IMAGE”的噻唑染料，其中R 1和R 2各自独立地为氢，取代或未取代的烷基，取代或未取代的苯基或环己基，或与连接氮原子一起形成杂环基，R 3 是氢，卤素，烷基，取代或未取代的苯基，苄基，环己基，羟基，呋喃基或噻吩基，A是可被取代和/或苯并稠合的环己二烯酮基团。

8. 发明授权

US5093308A Oxadiazolyl-benzene azo hydroxy-pyridone dyes for thermal transfer printing a yellow print 失效
标题翻译： OXADIAZOLYL-BENZENE AZO羟基磷灰石用于热转印打印黄色印刷
公开(公告)号：US5093308A
公开(公告)日：1992-03-03
申请号：US590130
申请日：1990-09-28
申请人： Ruediger Sens , Gunther Lamm , Karl-Heinz Etzbach
发明人： Ruediger Sens , Gunther Lamm , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , D06P5/13
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914 , Y10T428/31507 , Y10T428/31786
摘要： Azo dyes useful for thermotransfer printing have the formula ##STR1## where R.sup.1 and R.sup.2 are each H; alkyl, alkoxyalkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl, alkoxycarbonylalkyl, haloalkyl, hydroxyalkyl or cyanoalkyl each of up to 20 carbon atoms and each of which may be substituted by phenyl, C.sub.1 -C.sub.4 -alkylphenyl, C.sub.1 -C.sub.4 -alkoxyphenyl, halophenyl, benzyloxy, C.sub.1 -C.sub.4 -alkylbenzyloxy, C.sub.1 -C.sub.4 -alkoxybenzyloxy, halobenzyloxy, halogen, hydroxyl or cyano; phenyl or cyclohexyl which may each be substituted by C.sub.1 -C.sub.15 -alkyl, C.sub.1 -C.sub.15 -alkoxy, halogen or benzyloxy; or a radical II[--W--O].sub.n --R.sup.4 IIwhere W is identical or different C.sub.2 -C.sub.5 -alkylene, n is 1-6, R.sup.4 is C.sub.1 -C.sub.4 -alkyl or phenyl which may be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sup.3 is H, NH.sub.2, OH or C.sub.1 -C.sub.3 -alkyl, X is H, Cl, Br, No.sub.2, methyl, phenoxy, tolyloxy, dimethylphenyloxy, chlorophenoxy or C.sub.1 -C.sub.4 -alkoxy, Y is H, Cl or Br, and Z is H, acetyl, carbamoyl or cyano.
摘要翻译：可用于热转印印刷的偶氮染料具有式（I），其中R 1和R 2各为H; 烷基，烷氧基烷基，烷酰氧基烷基，烷氧基羰基氧基烷基，烷氧基羰基烷基，卤代烷基，羟基烷基或氰基烷基，各自至多20个碳原子，并且各自可被苯基，C 1 -C 4烷基苯基，C 1 -C 4烷氧基苯基，卤代苯基，苄氧基， C 1 -C 4 - 烷氧基苄氧基，卤代苄氧基，卤素，羟基或氰基; 苯基或环己基，其各自可被C 1 -C 15 - 烷基，C 1 -C 15 - 烷氧基，卤素或苄氧基取代; 或其中W是相同或不同的C 2 -C 5亚烷基，n是1-6，R 4是C 1 -C 4 - 烷基或可被C 1 -C 4 - 烷基取代的苯基的基团II [-WO] n -R 4 II，或 C 1 -C 4 - 烷氧基，R 3是H，NH 2，OH或C 1 -C 3烷基，X是H，Cl，Br，No 2，甲基，苯氧基，甲苯氧基，二甲基苯氧基，氯苯氧基或C 1 -C 4烷氧基，Y是H， Cl或Br，Z是H，乙酰基，氨基甲酰基或氰基。

9. 发明授权

US5389596A Dye mixtures for dye transfer 失效
标题翻译：用于染料转移的染料混合物
公开(公告)号：US5389596A
公开(公告)日：1995-02-14
申请号：US59132
申请日：1993-05-10
申请人： Karl-Heinz Etzbach , Gunther Lamm , Ruediger Sens
发明人： Karl-Heinz Etzbach , Gunther Lamm , Ruediger Sens
IPC分类号： B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B67/22 , C09D11/02 , D06P5/13 , B41M5/035 , B41M5/38
CPC分类号： B41M5/3858 , C09B67/0041 , B41M5/3854 , B41M5/3856 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10S430/165
摘要： Thermal transfer dye mixtures comprise at least one azo dye with a coupling component of the diaminopyridine series and at least one triazolopyridine, pyridone and/or 1-aminopyrid-2,6-dione dye.
摘要翻译：热转印染料混合物包含至少一种偶氮染料与二氨基吡啶系列的偶联组分和至少一种三唑并吡啶，吡啶酮和/或1-氨基吡啶-2,6-二酮染料。

10. 发明授权

US5204312A Azo dyes for thermal transfer printing 失效
标题翻译： AZO染色用于热转印
公开(公告)号：US5204312A
公开(公告)日：1993-04-20
申请号：US714021
申请日：1991-06-12
申请人： Ruediger Sens , Gunther Lamm , Karl-Heinz Etzbach
发明人： Ruediger Sens , Gunther Lamm , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , D06P5/13
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes suitable for thermal transfer printing have the formula ##STR1## in which the substituents have the following meanings: R.sup.1 is H, amino, hydroxyl or C.sub.1 -C.sub.3 -alkyl, R.sup.2 is H, acetyl, carbamoyl or cyano, R.sup.3 is .omega.-phenoxy-, .omega.-tolyloxy-, .omega.-benzyloxy- or .omega.-cyclohexyloxy-C.sub.1 -C.sub.12 -alkyl whose carbon chain may be interrupted by one or two of the following nonadjacent members --O--, --CO--, --O--CO-- or --CO--O-- and which may carry one or two of the following substituents: halogen, hydroxyl, C.sub.1 -C.sub.2 -alkyl, phenyl or cyclohexyl; R.sup.4 and R.sup.5 are each H, halogen, cyano, nitro, trihalomethyl, or a radical of the formula --CO--H, --CO--R.sup.6, --O--CO--R.sup.6, --CO--OR.sup.6, --SO--OR.sup.6, --O--SO--OR.sup.6, --CO--NR.sup.7 R.sup.8, --O--CO--NR.sup.7 R.sup.8, --SO.sub.2 --NR.sup.7 R.sup.8 or --O--SO.sub.2 --NR.sup.7 R.sup.8 where R.sup.6 is C.sub.1 -C.sub.12 -alkyl or .omega.-phenoxy-, .omega.-tolyloxy-, .omega.-benzyloxy- or .omega.-cyclohexyloxy-C.sub.1 -C.sub.12 -alkyl where the carbon chain may in each case be interrupted by one or two oxygen atoms in ether function, R.sup.7 is C.sub.1 -C.sub.12 -alkyl and R.sup.8 is H or has one of the meanings of R.sup.7.
摘要翻译：适用于热转移印花的偶氮染料具有式（I）其中取代基具有以下含义：R 1为H，氨基，羟基或C 1 -C 3 - 烷基，R 2为H，乙酰基，氨基甲酰基或氰基，R 3为ω - 苯氧基 - ，ω-甲酰氧基 - ，ω-苄氧基 - 或ω-环己氧基-C1-C12-烷基，其碳链可以被一个或两个以下不相邻的基团-O - ， - CO-，-O-CO - 或-CO-O-，并且其可以携带一个或两个以下取代基：卤素，羟基，C 1 -C 2 - 烷基，苯基或环己基; R4和R5各自为H，卤素，氰基，硝基，三卤代甲基或式-CO-H，-CO-R6，-O-CO-R6，-CO-OR6，-SO-OR6，-O -SO-OR 6，-CO-NR 7 R 8，-O-CO-NR 7 R 8，-SO 2 -NR 7 R 8或-O-SO 2 -NR 7 R 8，其中R 6为C 1 -C 12 - 烷基或ω-苯氧基 - ，ω-甲酰氧基 - ，ω-苄氧基 - 或ω-环己氧基-C1-C12-烷基，其中碳链可以在每种情况下被醚功能中的一个或两个氧原子中断，R7是C1-C12-烷基，R8是H或具有R7 。

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