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    • 8. 发明授权
    • CMP of copper/ruthenium substrates
    • 铜/钌基板的CMP
    • US07265055B2
    • 2007-09-04
    • US11259645
    • 2005-10-26
    • Christopher C. ThompsonVlasta BrusicRenjie Zhou
    • Christopher C. ThompsonVlasta BrusicRenjie Zhou
    • H01L21/302
    • H01L21/3212C09G1/02C23F3/04
    • The invention provides a method of chemically-mechanically polishing a substrate. A substrate comprising ruthenium and copper is contacted with a chemical-mechanical polishing system comprising a polishing component, hydrogen peroxide, an organic acid, at least one heterocyclic compound comprising at least one nitrogen atom, and water. The polishing component is moved relative to the substrate, and at least a portion of the substrate is abraded to polish the substrate. The pH of the polishing system is about 6 to about 12, the ruthenium and copper are in electrical contact, and the difference between the open circuit potential of copper and the open circuit potential of ruthenium in the polishing system is about 50 mV or less.
    • 本发明提供了一种化学机械抛光衬底的方法。 包含钌和铜的基材与包括抛光组分,过氧化氢,有机酸,至少一种包含至少一个氮原子的杂环化合物和水的化学机械抛光系统接触。 抛光组分相对于基底移动,并且研磨衬底的至少一部分以抛光衬底。 抛光系统的pH为约6至约12,钌和铜电接触,并且抛光系统中铜的开路电位与钌的开路电位之间的差为约50mV或更小。
    • 9. 发明授权
    • CMP method for noble metals
    • 贵金属的CMP方法
    • US06527622B1
    • 2003-03-04
    • US10054059
    • 2002-01-22
    • Vlasta BrusicFrancesco M. De RegeKevin J. MoeggenborgIsaac K. CherianRenjie Zhou
    • Vlasta BrusicFrancesco M. De RegeKevin J. MoeggenborgIsaac K. CherianRenjie Zhou
    • B24B100
    • H01L21/3212B24B37/044C09G1/02C09K3/1463C23F3/04C23F3/06H01L28/65
    • The invention provides a method of polishing a substrate comprising a noble metal comprising (i) contacting the substrate with a CMP system and (ii) abrading at least a portion of the substrate to polish the substrate. The CMP systems each comprise an abrasive and/or polishing pad, a liquid carrier, and optionally one or more polishing additives. In a first embodiment, the polishing additives are selected from the group consisting of diketones, diketonates, heterocyclic nitrogen-containing compounds, heterocyclic oxygen-containing compounds, heterocyclic phosphorus-containing compounds, urea compounds, nitrogen-containing compounds that can be zwitterionic compounds, salts thereof, and combinations thereof. In a second embodiment, the polishing additive is a metal compound with two or more oxidation states and is used in conjunction with a peroxy-type oxidizer. In a third embodiment, the CMP system comprises &agr;-alumina and fumed alumina, wherein the weight ratio of &agr;-alumina to fumed alumina is about 0.6:1 to about 9:1.
    • 本发明提供一种抛光包括贵金属的基材的方法,包括(i)使基板与CMP系统接触,以及(ii)研磨基材的至少一部分以抛光基材。 CMP系统各自包括磨料和/或抛光垫,液体载体和任选的一种或多种抛光添加剂。 在第一实施方案中,抛光添加剂选自二酮,二酮,杂环含氮化合物,含杂环氧的化合物,含杂环的化合物,尿素化合物,可以是两性离子化合物的含氮化合物, 其盐,及其组合。 在第二实施方案中,抛光添加剂是具有两种或更多种氧化态的金属化合物,并与过氧型氧化剂结合使用。 在第三个实施方案中,CMP系统包括α-氧化铝和热解氧化铝,其中α-氧化铝与热解氧化铝的重量比为约0.6:1至约9:1。
    • 10. 发明授权
    • Method of polishing a multi-layer substrate
    • 抛光多层基材的方法
    • US06852632B2
    • 2005-02-08
    • US10353542
    • 2003-01-29
    • Shumin WangVlasta Brusic KaufmanSteven K. GrumbineIsaac K. CherianRenjie Zhou
    • Shumin WangVlasta Brusic KaufmanSteven K. GrumbineIsaac K. CherianRenjie Zhou
    • B24B57/02B24D11/00C09G1/02C09K3/14H01L21/304H01L21/302C09K13/00
    • C09G1/02
    • The invention provides a method for polishing one or more layers of a multi-layer substrate that includes a first metal layer and a second layer comprising (i) contacting the first metal layer with a polishing system comprising a liquid carrier, at least one oxidizing agent, at least one polishing additive that increases the rate at which the system polishes at least one layer of the substrate, wherein the polishing additive is selected from the group consisting of pyrophosphates, condensed phosphates, phosphonic acids and salts thereof, amines, amino alcohols, amides, imines, imino acids, nitriles, nitros, thiols thioesters, thioethers, carbothiolic acids, carbothionic acids, thiocarboxylic acids, thiosalicylic acids, and mixtures thereof, and a polishing pad and/or an abrasive, and (ii) polishing the first metal layer with the system until at least a portion of the first metal layer is removed from the substrate.
    • 本发明提供了一种用于抛光一层或多层多层基材的方法,所述多层基材包括第一金属层和第二层,其包括(i)使第一金属层与包括液体载体,至少一种氧化剂 至少一种抛光添加剂,其增加系统抛光至少一层基材的速率,其中所述抛光添加剂选自焦磷酸盐,缩合磷酸盐,膦酸及其盐,胺,氨基醇, 酰胺,亚胺,亚氨基酸,腈,亚硝基,硫醇硫酯,硫醚,硫代硫酸,碳硫酸,硫代羧酸,硫代水杨酸及其混合物,以及抛光垫和/或磨料,和(ii) 层,直到第一金属层的至少一部分从衬底去除。