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1. 发明授权

US06509073B1 Crosslinked compositions of thermoplastic fluoropolymers 有权
标题翻译：热塑性氟聚合物的交联组合物
公开(公告)号：US06509073B1
公开(公告)日：2003-01-21
申请号：US09528199
申请日：2000-03-17
申请人： Vincenzo Arcella , Julio A. Abusleme
发明人： Vincenzo Arcella , Julio A. Abusleme
IPC分类号： B32B2716
CPC分类号： C08K5/0025 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544 , Y10T428/3158 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31891 , Y10T428/31906 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , C08L27/12
摘要： Crosslinked polymer compositions obtained by subjecting to ionizing radiations compositions comprising: I) thermoprocessable copolymers of ethylene with tetrafluoroethylene (TFE) and/or chlorotrifluoroethylene (CTFE) modified with acrylic monomers of formula: CH2═CH—CO—O—R2 (a) R2 is a hydrogenated radical from 1 to 20 carbon atoms, C1-C20, alkyl, linear and/or branched radical, or cycloalkyl, or R2 is H. The radical R2 can optionally contain: heteroatoms preferably Cl, O, N; one or more functional groups preferably selected from OH, COOH, epoxide, ester and ether; and double bonds; II) one or more cross-linking agents; III) one or more optional ingredients.
摘要翻译：通过经受电离辐射组合物获得的交联聚合物组合物包括：I）乙烯与四氟乙烯（TFE）和/或氯三氟乙烯（CTFE）的热可加工共聚物，其用式R 2的丙烯酸单体改性：1-20个碳原子的氢化基团，C1 -C 20，烷基，直链和/或支链或环烷基，或R 2为H.基团R 2可任选地含有：杂原子优选Cl，O，N; 一个或多个优选选自OH，COOH，环氧化物，酯和醚的官能团; 和双键; II）一种或多种交联剂; III）一种或多种任选成分。

2. 发明授权

US5962610A Ethylene fluoro-containing copolymers 失效
标题翻译：含乙烯含氟共聚物
公开(公告)号：US5962610A
公开(公告)日：1999-10-05
申请号：US888286
申请日：1997-07-03
申请人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
发明人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
IPC分类号： C08J5/18 , C08F2/00 , C08F210/02 , C08F214/18 , C08F214/24 , C08F214/26
CPC分类号： C08F214/186 , C08F210/02
摘要： Ethylene fluoro-containing copolymers of the ECTFE and ETFE type, optionally in the presence of a third comonomer in amount comprised between 0.1 and 10% by moles, having a viscosity between 10.sup.2 and 10.sup.5 Pa.sec with shear rates of 1 sec.sup.-1 measured at the temperature of about 30.degree. C. higher than the second melting temperature, and having a rheologic curve in the diagram shear viscosity/shear-rate with a slope higher than 200, calculated as ratio between the viscosity in Pa.sec and the shear-rate in sec.sup.-1 in the shear-rate range comprised between 1 and 10 sec.sup.-1, and having a processability zone with shear-rate values higher than 10 s.sup.-1.
摘要翻译： ECTFE和ETFE型的含乙烯基氟的共聚物，任选地在第三共聚单体存在下，其量为0.1至10摩尔％，其粘度为102至105Pa·s，剪切速率为1秒-1 在比第二熔融温度高约30℃的温度下，在图中具有斜率高于200的剪切粘度/剪切速率的流变曲线，以Pa.sec中的粘度与剪切力之比计算 - 在剪切速率范围为1至10秒-1的sec-1范围内，并具有剪切速率值高于10s-1的加工性区域。

3. 发明授权

US06329481B1 Ethylene fluoro-containing copolymers 有权
标题翻译：含乙烯含氟共聚物
公开(公告)号：US06329481B1
公开(公告)日：2001-12-11
申请号：US09354158
申请日：1999-07-16
申请人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
发明人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
IPC分类号： C08F21424
CPC分类号： C08F214/186 , C08F210/02
摘要： Ethylene fluoro-containing copolymers of the ECTFE and ETFE type, optionally in the presence of a third comonomer in amount comprised between 0.1 and 10% by moles, having a viscosity between 102 and 105 Pa.sec with shear rates of 1 sec−1 measured at the temperature of about 30° C. higher than the second melting temperature, and having a rheologic curve in the diagram shear viscosity/shear-rate with a slope higher than 200, calculated as ratio between the viscosity in Pa.sec and the shear-rate in sec−1 in the shear-rate range comprised between 1 and 10 sec−1, and having a processability zone with shear-rate values higher than 10 s−1.
摘要翻译： ECTFE和ETFE型的含乙烯基氟的共聚物，任选地在第三共聚单体存在下，其量为0.1至10摩尔％，其粘度为102至105Pa·s，剪切速率为1秒-1 在比第二熔融温度高约30℃的温度下，并且在图中具有斜率高于200的剪切粘度/剪切速率的流变曲线，以Pa.sec中的粘度与剪切比之间的比计算 - 在剪切速率范围为1至10秒-1的sec-1范围内，并具有剪切速率值高于10s-1的加工性区域。

4. 发明授权

US5902860A Blends of fluorinated and acrylic elastomers 失效
标题翻译：氟化和丙烯酸弹性体的共混物
公开(公告)号：US5902860A
公开(公告)日：1999-05-11
申请号：US21532
申请日：1998-02-10
申请人： Julio A. Abusleme , Anna Staccione , Vincenzo Arcella
发明人： Julio A. Abusleme , Anna Staccione , Vincenzo Arcella
IPC分类号： C08J3/24 , C08K3/04 , C08K3/22 , C08K3/36 , C08K5/14 , C08L27/12 , C08L27/16 , C08L33/06 , C08L33/08 , C08F8/00
CPC分类号： C08K5/14 , C08L27/16 , C08L33/08 , C08L27/12
摘要： Compounds comprising a peroxide and a peroxide curable blend essentially consisting of hydrocarbon elastomers containing at least an acrylic monomer and of fluorinated VDF-based elastomers having in the polymer chain at least 5% by moles of hydrogenated groups C.sub.1 of the type ##STR1## --CH.sub.2 -- and/or --CH.sub.3, the amount of fluorinated rubber in the elastomeric blend being comprised from 5 to 75% by weight, said elastomers of the blend not containing iodine and/or bromine.
摘要翻译：包含过氧化物和过氧化物可固化共混物的化合物基本上由至少含有丙烯酸单体的烃弹性体和氟化VDF基弹性体组成，所述氟弹性体在聚合物链中具有至少5摩尔％的类型为-CH 2 - 的氢化基团C1和/ 或-CH 3，弹性体共混物中的氟化橡胶的量为5-75重量％，所述共混物的弹性体不含碘和/或溴。

5. 发明授权

US11441007B2 Fluoropolymer composition for multilayer assemblies 有权
公开(公告)号：US11441007B2
公开(公告)日：2022-09-13
申请号：US14131747
申请日：2012-07-10
申请人： Stefano Mortara , Julio A. Abusleme
发明人： Stefano Mortara , Julio A. Abusleme
IPC分类号： C08K3/22 , C08F214/22 , C08F20/06 , B29C48/21 , C09D127/16 , C08F14/22 , C08L27/16 , B32B27/30 , B32B27/36 , C08K3/30
摘要： The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.

6. 发明授权

US09382362B2 Fluoropolymer-based hybrid organic/inorganic composites 有权
公开(公告)号：US09382362B2
公开(公告)日：2016-07-05
申请号：US13638425
申请日：2011-03-31
申请人： Julio A. Abusleme , Riccardo Pieri , Ivan Pagin
发明人： Julio A. Abusleme , Riccardo Pieri , Ivan Pagin
IPC分类号： C08F20/06 , C08F214/18 , C08F8/00 , C09D127/16 , C08J5/00 , C08J5/22 , B01D67/00 , B01D69/14 , B82Y30/00 , C08F220/06 , C08F220/20 , C08F214/22 , C08F214/24 , C08K3/34 , H01M2/14 , H01M2/16 , H01M8/10 , B01D71/02 , B01D71/34 , B01D71/70
CPC分类号： C08F214/18 , B01D67/0079 , B01D69/148 , B01D71/022 , B01D71/027 , B01D71/34 , B01D71/70 , B01D2323/38 , B82Y30/00 , C08F8/00 , C08F214/182 , C08F214/186 , C08F214/225 , C08F214/245 , C08F220/06 , C08F220/20 , C08F2800/10 , C08F2810/20 , C08F2810/50 , C08J5/005 , C08J5/2281 , C08J2333/10 , C08K3/346 , C09D127/16 , H01M2/145 , H01M2/166 , H01M8/1046 , Y02P70/56 , C08F8/12 , C08F8/42 , C08F210/02 , C08K3/36
摘要： A process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) mixing at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: at least one metal compound [compound (M)] of formula: X4-mAYm, wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group comprising one or more functional groups; (ii) reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), to obtain a grafted polymer comprising pendant —Ym-1AX4-m groups, with m, Y, A and X having same meaning as above; and (iii) hydrolyzing and/or polycondensing compound (M) and/or pendant —Ym-1AX4-m groups as above. The invention also disclose the fluoropolymer hybrid organic/inorganic composites obtained therefrom and the method of the use of the same.

7. 发明授权

US08642702B2 VDF polymer composition 有权
标题翻译： VDF聚合物组成
公开(公告)号：US08642702B2
公开(公告)日：2014-02-04
申请号：US13643339
申请日：2011-04-26
申请人： Julio A. Abusleme , Stefano Mortara
发明人： Julio A. Abusleme , Stefano Mortara
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08J5/18 , C08J2327/16 , C08L27/16 , C08L27/12 , C08L23/0892
摘要： The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.
摘要翻译：本发明涉及一种热塑性VDF聚合物组合物，其包含：至少一种包含至少85％摩尔衍生自VDF的重复单元的热塑性偏二氟乙烯（VDF）聚合物; 和至少一种乙烯/氯三氟乙烯（ECTFE）聚合物，其中所述ECTFE聚合物具有小于210℃的熔点，并且其含量相对于VDF聚合物的总重量为0.1-20重量％和ECTFE聚合物。本发明还涉及制备VDF聚合物的方法及其用于制造膜，特别是透明膜的用途。

8. 发明申请

US20130192755A1 Multilayer assembly 审中-公开
标题翻译：多层装配
公开(公告)号：US20130192755A1
公开(公告)日：2013-08-01
申请号：US13877792
申请日：2011-10-12
申请人： Serena Carella , Mattia Bassi , Stefano Mortara , Paolo Toniolo , Julio A. Abusleme
发明人： Serena Carella , Mattia Bassi , Stefano Mortara , Paolo Toniolo , Julio A. Abusleme
IPC分类号： B32B27/08
CPC分类号： B32B27/08 , B32B27/20 , B32B27/304 , B32B2250/03 , B32B2250/246 , B32B2250/40 , B32B2264/102 , B32B2307/412 , B32B2307/71 , B32B2307/712 , B32B2457/12 , H01L31/0481 , Y02E10/50 , Y10T156/10 , Y10T428/257 , Y10T428/259 , Y10T428/265 , Y10T428/31544
摘要： A multilayer assembly comprising a first inner layer (L1) made from a first composition (C1), said first composition (C1) comprising at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and a second outer layer (L2) made from a second composition, said second composition (C2) being free from TiO2-containing additives, said second composition (C2) comprising at least one semi-crystalline polymer (A) comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer (A) having a heat of fusion of at least 35 J/g.
摘要翻译：一种多层组件，包括由第一组合物（C1）制成的第一内层（L1），所述第一组合物（C1）包含至少一种包含衍生自乙烯（E）和氯三氟乙烯（CTFE）的重复单元的聚合物，并且至少一钛化合物和由第二组合物制成的第二外层（L2），所述第二组合物（C2）不含TiO 2添加剂，所述第二组合物（C2）包含至少一种半结晶聚合物（A），其包含衍生自乙烯和至少一种选自三氟氯乙烯（CTFE），四氟乙烯（TFE）及其混合物的含氟单体，所述半结晶聚合物（A）具有至少35J / g的熔化热。

9. 发明授权

US07985790B2 Water-based fluoropolymer composition 有权
标题翻译：水性含氟聚合物组合物
公开(公告)号：US07985790B2
公开(公告)日：2011-07-26
申请号：US12095798
申请日：2006-12-04
申请人： Fabio Polastri , Tiziana Poggio , Julio A. Abusleme
发明人： Fabio Polastri , Tiziana Poggio , Julio A. Abusleme
IPC分类号： C08K5/05
CPC分类号： C09D127/12 , C08K5/04 , C08K5/05 , C08K5/053 , C08K5/06 , C09D127/16 , C09D127/18 , Y10T428/3154 , C08L27/12
摘要： A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond.
摘要翻译：含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物[聚合物（F）]; 水; 包含：至少一种醇溶剂[溶剂（A）];小于15重量％（基于组合物的总重量）的水溶性溶剂混合物[混合物（M）至少一种沸点为至少100℃的二醇衍生物溶剂[溶剂（GD）]，其中溶剂（GD）是包含至少两个羟基的化合物的衍生物，其中至少一个羟基已经衍生化得到醚或酯键。

10. 发明申请

US20090326154A1 Additives for Halopolymers 有权
标题翻译：卤代聚合物添加剂
公开(公告)号：US20090326154A1
公开(公告)日：2009-12-31
申请号：US12516086
申请日：2005-11-29
申请人： Julio A. Abusleme , Marco Avataneo , Giancarlo Perfetti
发明人： Julio A. Abusleme , Marco Avataneo , Giancarlo Perfetti
IPC分类号： C08F214/24
CPC分类号： C08L23/0892 , C08L23/00 , C08L27/00 , C08L51/08 , C08L53/00 , C08L71/02 , C08L2666/24 , C08L2666/22
摘要： Polymeric compositions comprising: 1) at least one thermoprocessable semicrystalline halo-polymer; 2) an additive in amounts between 0.01 and 10% by weight of 1) one or more (per)fluoropolyether polymers of formula: Q-O-[A-B]z-[A-B′]z′-A-Q′ (I) wherein: A=—(X)a—O-A′-(X′)b— wherein A′ is a perfluoropolyether chain; X, X′=—CF2—, —CF2CF2—, —CF(CF3)—; a, b=0 or 1; B derives from one or more olefins, of which at least one homopolymerizable by radical way, of formula: —[(CR1R2—CR3R4)j(CR5R6—CR7R8)j′]— (Ia) wherein j=1-30, j′=0-29, with the proviso that 2
摘要翻译：聚合物组合物包括：1）至少一种热可加工半结晶卤代聚合物; 2）0.01至10重量％的添加剂，1）一种或多种式（Q） - [AB] z- [A-B'] z'-AQ'（I）的（全）氟聚醚聚合物，其中： A = - （X）aO-A' - （X'）b-其中A'是全氟聚醚链; X，X'= -CF 2 - ， - CF 2 CF 2 - ， - CF（CF 3） - ; a，b = 0或1; B衍生自一种或多种烯烃，其中至少一种可通过自由基方式可通过以下通式共聚合： - [（CR1R2-CR3R4）j（CR5R6-CR7R8）j'] - （Ia）其中j = 1-30，j' = 0-29，条件是2 <（j + j'）<30; R 1 -R 8 =卤素，H，C 1 -C 6（全）卤代烷基，C 1 -C 6烷基或C 1 -C 6氧基（全）氟烷基; B'=（Ia），但R 1 -R 8中的至少一个具有与B不同的含义，并且2 <=（j + j'）<30; z> = 2; z'为0或整数; z，z'使得（I）的数均分子量在500和500,000之间; Q，Q'= C1-C3全氟烷基; C1-C6烷基; 或功能性端基。

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