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    • 1. 发明授权
    • Water-based polymer composition and articles made therefrom
    • 水性聚合物组合物和由其制成的制品
    • US08063135B2
    • 2011-11-22
    • US10902007
    • 2004-07-30
    • Lin Shiow-LingDavid GibalaAnthony LipplGeoffrey Scott UnderwoodTiziana Poggio
    • Lin Shiow-LingDavid GibalaAnthony LipplGeoffrey Scott UnderwoodTiziana Poggio
    • C08L79/08B32B27/28
    • C08L27/12C08L27/18C08L79/04C09D127/12C09D127/18Y10T428/3154C08L2666/20
    • The present invention relates to a water-based polymer composition, comprising: at least one polymer (P) comprising recurring units (R1), from 0 to at most 25% mol of said recurring units (R1) comprising a carboxylic acid group (in acid or salt form); at least one aromatic polyamic acid (A) comprising recurring units, more than 50% mol of said recurring units comprising at least one aromatic ring and at least one amic acid group and/or imide group [recurring units (R2)], more than 50% mol of recurring units (R2) comprising at least one amic acid group, part or all of the amic acid groups being neutralized by at least one basic compound (B); water; optionally, at least one organic solvent (S) of the aromatic polyamic acid (A), in an amount of less than 20% wt with respect to the weight of the aromatic polyamic acid. The polymer (P) is preferably a fluoropolymer; it can be either a partially fluorinated fluoropolymer, such as ECTFE, or a perfluorinated fluoropolymer such as TFE polymers.The water-based polymer compositions of this invention may be notably found useful for coating applications where organic solvents may not be desired or tolerated.
    • 本发明涉及一种水基聚合物组合物,其包含:至少一种包含重复单元(R1)的至少一种聚合物(P),0至至多25摩尔%的包含羧酸基团的重复单元(R1)(在 酸或盐形式); 至少一种包含重复单元的芳族聚酰胺酸(A),超过50%摩尔的所述重复单元包含至少一个芳族环和至少一个酰胺基和/或酰亚胺基[重复单元(R 2)],多于 50%摩尔的包含至少一种酰胺酸基团的重复单元(R2),部分或全部酰胺酸基团被至少一种碱性化合物(B)中和; 水; 任选地,芳族聚酰胺酸(A)的至少一种有机溶剂(S)的用量相对于芳族聚酰胺酸的重量小于20%wt。 聚合物(P)优选为含氟聚合物; 它可以是部分氟化的氟聚合物,例如ECTFE,或全氟化含氟聚合物如TFE聚合物。 本发明的水基聚合物组合物可以显着地用于可能不期望或耐受有机溶剂的涂布应用。
    • 3. 发明申请
    • Water-Based Fluoropolymer Composition
    • 水基含氟聚合物组合物
    • US20090018244A1
    • 2009-01-15
    • US12095798
    • 2006-12-04
    • Fabio PolastriTiziana PoggioJulio A. Abusleme
    • Fabio PolastriTiziana PoggioJulio A. Abusleme
    • C08K5/06C08K5/10C08K5/05
    • C09D127/12C08K5/04C08K5/05C08K5/053C08K5/06C09D127/16C09D127/18Y10T428/3154C08L27/12
    • A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond. Another object of the present invention is a process for manufacturing said composition. Still another object of the invention is the use of the composition of the invention for coating. Still another object of the invention is a coated article, obtained using the composition of the invention.
    • 含氟聚合物组合物,其包含:至少一种热塑性部分氟化含氟聚合物[聚合物(F)]; 水; 包含:至少一种醇溶剂[溶剂(A)];小于15重量%(基于组合物的总重量)的水溶性溶剂混合物[混合物(M) 至少一种沸点为至少100℃的二醇衍生物溶剂[溶剂(GD)],其中溶剂(GD)是包含至少两个羟基的化合物的衍生物,其中至少一个羟基 已经衍生化得到醚或酯键。 本发明的另一个目的是制备所述组合物的方法。 本发明的另一个目的是使用本发明的组合物进行涂覆。 本发明的另一个目的是使用本发明的组合物获得的涂层制品。
    • 10. 发明申请
    • Water-based polymer composition and articles made therefrom
    • 水性聚合物组合物和由其制成的制品
    • US20050070659A1
    • 2005-03-31
    • US10902007
    • 2004-07-30
    • Lin Shiow-LingDavid GibalaAnthony LipplGeoffrey UnderwoodTiziana Poggio
    • Lin Shiow-LingDavid GibalaAnthony LipplGeoffrey UnderwoodTiziana Poggio
    • C08K3/00
    • C08L27/12C08L27/18C08L79/04C09D127/12C09D127/18Y10T428/3154C08L2666/20
    • The present invention relates to a water-based polymer composition, comprising: at least one polymer (P) comprising recurring units (R1), from 0 to at most 25% mol of said recurring units (R1) comprising a carboxylic acid group (in acid or salt form); at least one aromatic polyamic acid (A) comprising recurring units, more than 50% mol of said recurring units comprising at least one aromatic ring and at least one amic acid group and/or imide group [recurring units (R2)], more than 50% mol of recurring units (R2) comprising at least one amic acid group, part or all of the amic acid groups being neutralized by at least one basic compound (B); water; optionally, at least one organic solvent (S) of the aromatic polyamic acid (A), in an amount of less than 20% wt with respect to the weight of the aromatic polyamic acid. The polymer (P) is preferably a fluoropolymer; it can be either a partially fluorinated fluoropolymer, such as ECTFE, or a perfluorinated fluoropolymer such as TFE polymers. The water-based polymer compositions of this invention may be notably found useful for coating applications where organic solvents may not be desired or tolerated.
    • 本发明涉及水基聚合物组合物,其包含:至少一种包含重复单元(R1)的至少一种聚合物(P),0至至多25摩尔%的包含羧酸基团的重复单元(R1)(在 酸或盐形式); 至少一种包含重复单元的芳族聚酰胺酸(A),超过50%摩尔的所述重复单元包含至少一个芳族环和至少一个酰胺基和/或酰亚胺基[重复单元(R 2)],多于 50%摩尔的包含至少一种酰胺酸基团的重复单元(R2),部分或全部酰胺酸基团被至少一种碱性化合物(B)中和; 水; 任选地,芳族聚酰胺酸(A)的至少一种有机溶剂(S)的用量相对于芳族聚酰胺酸的重量小于20%wt。 聚合物(P)优选为含氟聚合物; 它可以是部分氟化的氟聚合物,例如ECTFE,或全氟化含氟聚合物如TFE聚合物。 本发明的水基聚合物组合物可以显着地用于可能不期望或耐受有机溶剂的涂布应用。