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    • 5. 发明授权
    • Silicon nitride with improved high temperature strength
    • 具有改善的高温强度的氮化硅
    • US4904624A
    • 1990-02-27
    • US144458
    • 1988-01-15
    • Russell L. Yeckley
    • Russell L. Yeckley
    • C04B35/593
    • C04B35/593
    • The flexural strength and stress rupture life of isostatically hot pressed silicon nitride containing between 1 and 12 weight percent of rare earth oxide and not more than 0.5 weight percent alumina is substantially increased by treating green bodies in flowing nitrogen at a temperature between 1000.degree. and 1500.degree. C. before degassing for the isostatic hot pressing. The iron content of the bodies is also reduced by this heat treatment, and this is believed to eliminate sources of fracture failure. Silicon nitride bodies with a flexural strength in excess of 525 MPa at 1370.degree. C. and with stress rupture lives reliably in excess of 200 hours at 300 MPa stress at 1370.degree. C. can be prepared in this way. The strain rates of silicon nitride under high temperature stress can also be reduced.
    • 含有1〜12重量%稀土氧化物和不超过0.5重量%氧化铝的等静压热压氮化硅的弯曲强度和应力断裂寿命通过在1000〜1500℃的温度下处理生态体 在等离子体热压脱气前。 通过这种热处理也减少了这些物体的铁含量,这被认为是消除了断裂破坏的原因。 在1370℃下,弯曲强度超过525MPa,在1370℃下的应力断裂的应力断裂的可靠性超过200小时的氮化硅体可以以这种方式制备。 氮化硅在高温应力下的应变速率也可以降低。
    • 10. 发明授权
    • Ceramic material and method of manufacture
    • 陶瓷材料及其制造方法
    • US4563433A
    • 1986-01-07
    • US466716
    • 1983-02-15
    • Russell L. YeckleyBernard North
    • Russell L. YeckleyBernard North
    • C04B35/597C04B35/58
    • C04B35/597
    • A dual phase silicon aluminum oxynitride material comprising a first phase Si-Al-O-N, commonly referred to as .beta.-Si-Al-O-N, and a second phase Si-Al-O-N referred to as .alpha.-Si-Al-O-N. In addition to the double phase Si-Al-O-Ns, there is included a glassy type material which can formulate up to ten percent by weight of the total composition. The material may be manufactured by forming a polytype material made from reacted alumina, aluminum nitride and silicon nitride. The polytype material may be mixed with further powders of silicon nitride and an oxide of yttrium, lithium or calcium and finally reacted to a double phase Si-Al-O-N material where hardness is increased as the additional .alpha.-Si-Al-O-N is increased without significantly affecting its strength.The material may be formed in situ by mixing aluminum nitride, alumina, silicon nitride, together with an oxide of yttrium, lithium or calcium. These materials can then be sintered to a final product containing a double phase Si-Al-O-N. Control of the alumina content in the polytype or in situ methods affects the percentage of .alpha.-Si-Al-O-N produced in the final product. The hardness of the material increases with the .alpha.-Si-Al-O-N content without significantly affecting its transverse rupture strength.
    • 包括通常称为β-Si-Al-O-N的第一相Si-Al-O-N和称为α-Si-Al-O-N的第二相Si-Al-O-N的双相硅铝氧氮化物材料。 除了双相Si-Al-O-N之外,还包括一种玻璃状材料,其可以配制成总组合物的10重量%。 该材料可以通过形成由反应的氧化铝,氮化铝和氮化硅制成的多型材制造。 多型材料可以与另外的氮化硅粉末和钇,锂或钙的氧化物混合,并最终与另外的α-Al-ON增加硬度的双相Si-Al-ON材料反应 没有显着影响其实力。 材料可以通过将氮化铝,氧化铝,氮化硅与钇,锂或钙的氧化物一起混合而原位形成。 然后将这些材料烧结成含有双相Si-Al-O-N的最终产品。 控制聚合物或原位方法中的氧化铝含量会影响最终产品中产生的α-Si-Al-O-N的百分比。 材料的硬度随着α-Al-O-N含量的增加而不会明显影响其横向断裂强度。