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    • 5. 发明授权
    • Ceramic material and method of manufacture
    • 陶瓷材料及其制造方法
    • US4563433A
    • 1986-01-07
    • US466716
    • 1983-02-15
    • Russell L. YeckleyBernard North
    • Russell L. YeckleyBernard North
    • C04B35/597C04B35/58
    • C04B35/597
    • A dual phase silicon aluminum oxynitride material comprising a first phase Si-Al-O-N, commonly referred to as .beta.-Si-Al-O-N, and a second phase Si-Al-O-N referred to as .alpha.-Si-Al-O-N. In addition to the double phase Si-Al-O-Ns, there is included a glassy type material which can formulate up to ten percent by weight of the total composition. The material may be manufactured by forming a polytype material made from reacted alumina, aluminum nitride and silicon nitride. The polytype material may be mixed with further powders of silicon nitride and an oxide of yttrium, lithium or calcium and finally reacted to a double phase Si-Al-O-N material where hardness is increased as the additional .alpha.-Si-Al-O-N is increased without significantly affecting its strength.The material may be formed in situ by mixing aluminum nitride, alumina, silicon nitride, together with an oxide of yttrium, lithium or calcium. These materials can then be sintered to a final product containing a double phase Si-Al-O-N. Control of the alumina content in the polytype or in situ methods affects the percentage of .alpha.-Si-Al-O-N produced in the final product. The hardness of the material increases with the .alpha.-Si-Al-O-N content without significantly affecting its transverse rupture strength.
    • 包括通常称为β-Si-Al-O-N的第一相Si-Al-O-N和称为α-Si-Al-O-N的第二相Si-Al-O-N的双相硅铝氧氮化物材料。 除了双相Si-Al-O-N之外,还包括一种玻璃状材料,其可以配制成总组合物的10重量%。 该材料可以通过形成由反应的氧化铝,氮化铝和氮化硅制成的多型材制造。 多型材料可以与另外的氮化硅粉末和钇,锂或钙的氧化物混合,并最终与另外的α-Al-ON增加硬度的双相Si-Al-ON材料反应 没有显着影响其实力。 材料可以通过将氮化铝,氧化铝,氮化硅与钇,锂或钙的氧化物一起混合而原位形成。 然后将这些材料烧结成含有双相Si-Al-O-N的最终产品。 控制聚合物或原位方法中的氧化铝含量会影响最终产品中产生的α-Si-Al-O-N的百分比。 材料的硬度随着α-Al-O-N含量的增加而不会明显影响其横向断裂强度。
    • 9. 发明授权
    • SiAlON containing ytterbium and method of making
    • 含有镱的SiAlON及其制备方法
    • US07094717B2
    • 2006-08-22
    • US11108225
    • 2005-04-18
    • Russell L. Yeckley
    • Russell L. Yeckley
    • C04B35/599
    • C04B35/597
    • A method for making a crystallized ceramic body containing a two phase composite comprising an alpha prime SiAlON phase that contains ytterbium and a beta prime SiAlON phase, the process includes the steps of: blending together a starting powder mixture that upon densification forms the SiAlON ceramic, the starting powder includes at least about 70 weight percent silicon nitride powder wherein the silicon nitride powder contains beta silicon nitride in an amount less than or equal to about 1.6 weight percent of the silicon nitride powder, and the starting powder further including one or more powders that contribute aluminum, oxygen, and nitrogen to the beta prime SiAlON phase and aluminum, oxygen, nitrogen and ytterbium to the alpha prime SiAlON phase; and densifying the starting powder mixture to form a densified SiAlON ceramic; and heat treating the densified ceramic body so as to form the crystallized ceramic body wherein the alpha prime SiAlON phase comprises at least about 20 weight percent of the two phase composite.
    • 一种制备结晶陶瓷体的方法,该陶瓷体含有含有镱和β原子SiAlON相的α原子SiAlON相的两相复合物,该方法包括以下步骤:将致密化后形成SiAlON陶瓷的起始粉末混合物混合在一起, 起始粉末包括至少约70重量%的氮化硅粉末,其中氮化硅粉末含有小于或等于氮化硅粉末的约1.6重量%的β氮化硅,并且起始粉末还包括一种或多种粉末 对β原子SiAlON相和铝,氧,氮和镱贡献铝,氧和氮到α原子SiAlON相; 并致密化起始粉末混合物以形成致密化的SiAlON陶瓷; 并且对所述致密陶瓷体进行热处理以形成所述结晶陶瓷体,其中所述α原子SiAlON相包含所述两相复合材料的至少约20重量%。