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    • 4. 发明授权
    • Magnetic discs having a multi-component binder
    • 具有多组分粘合剂的磁盘
    • US3955037A
    • 1976-05-04
    • US521459
    • 1974-11-06
    • Matthias MarxJob-Werner HartmannWerner Ostertag
    • Matthias MarxJob-Werner HartmannWerner Ostertag
    • C09D5/23G11B5/702H01F10/02
    • G11B5/7022G11B5/7023Y10S428/90Y10T428/31529Y10T428/31688
    • A process for the manufacture of improved magnetic discs by applying a thin layer of a fluid dispersion of magnetic pigments and optional non-magnetic pigments in a binder mixture to a non-magnetic rigid base and curing the magnetic layer which has been applied. The binder consists essentially of from 60 to 90 percent by weight of a solid curable polycondensate of 2,2-bis-(4-hydroxyphenyl)-propane and epichlorohydrin having an epoxide equivalent weight of approximately 400 to 5,000, from 5 to 25 percent by weight of a curable allyloxybenzene-formaldehyde condensate of the resol type with free or alcohol-etherified methylol groups and a molecular weight of less thah 1,000, and from 5 to 30 percent by weight of a curable melamine-formaldehyde condensate with more than two alcohol-etherified methylol groups and a molecular weight of less than 3,000, from 10 to 35 percent by weight of the above epoxy resin being replaced by a reaction product of an epoxy group-containing polycondensate of 2,2-bis-(4-hydroxyphenyl)-propane and epichlorohydrin with the N-methylolamide of a copolymerizable olefinically unsaturated carboxylic acid of 3 to 5 carbon atoms. The magnetic layers thus produced adhere firmly to the base, can be readily ground and polished and are particularly resistant to wear when the magnetic discs are in use.
    • 通过将粘合剂混合物中的磁性颜料和任选的非磁性颜料的流体分散体的薄层施加到非磁性刚性基底并固化已经施加的磁性层来制造改进的磁盘的方法。 粘合剂基本上由60至90重量%的2,2-双 - (4-羟基苯基) - 丙烷和表氯醇的固体可固化缩聚物,其环氧当量为约400至5,000,按重量计为5至25% 具有游离或醇醚化的羟甲基的分解型甲醛型可固化的烯丙氧基苯 - 甲醛缩合物的重量和分子量小于1,000的可固化的烯丙氧基苯 - 甲醛缩合物和5至30重量%的可固化的三聚氰胺 - 甲醛缩合物与多于两个的醇 - 醚化的羟甲基和小于3,000的分子量,10至35重量%的上述环氧树脂被2,2-双(4-羟基苯基) - (4-羟基苯基) - 环氧基的环氧基缩聚物的反应产物代替, 丙烷和表氯醇与3-羟甲基酰胺的可共聚的烯属不饱和羧酸的3至5个碳原子。 由此产生的磁性层牢固地粘附到基底上,可容易地研磨和抛光,并且当使用磁盘时特别耐磨损。