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1. 发明授权

US06783560B2 Process for preparing wetfast polyamide fibers 失效
标题翻译：湿快聚酰胺纤维的制备方法
公开(公告)号：US06783560B2
公开(公告)日：2004-08-31
申请号：US10270567
申请日：2002-10-16
申请人： Ulrike Breiner , Dean R. Gadoury , Harry Y. Hu , Theodore G. Karageorgiou
发明人： Ulrike Breiner , Dean R. Gadoury , Harry Y. Hu , Theodore G. Karageorgiou
IPC分类号： D06P306
CPC分类号： C08G69/28 , C08G69/02 , C08G69/04 , C08G69/16 , C08G69/26 , C08G69/48 , Y10S8/92 , Y10S8/924
摘要： A modified polyamide polymer having a high amino end group content, with more than 30 percent of the amino end groups being secondary or tertiary amine, dramatically improves the dye bleed performance. The modified polyamide may be prepared by polymerization of polyamide-forming monomers in the presence of a carboxylic acid and a hindered piperidine derivative in amounts sufficient to achieve the high amino end group content.
摘要翻译：具有高氨基端基含量的改性聚酰胺聚合物，超过30％的氨基端基是仲胺或叔胺，显着提高了染料渗色性能。改性聚酰胺可以通过聚酰胺形成单体在羧酸和受阻哌啶衍生物的存在下以足以达到高氨基端基含量的量来制备。

2. 发明授权

US06620208B2 Wetfast polyamide fiber with high amino end group content 失效
公开(公告)号：US06620208B2
公开(公告)日：2003-09-16
申请号：US09821691
申请日：2001-03-30
申请人： Ulrike Breiner , Dean R. Gadoury , Harry Y. Hu , Theodore G. Karageorgiou
发明人： Ulrike Breiner , Dean R. Gadoury , Harry Y. Hu , Theodore G. Karageorgiou
IPC分类号： D06M1100
CPC分类号： C08G69/28 , C08G69/02 , C08G69/04 , C08G69/16 , C08G69/26 , C08G69/48 , Y10S8/92 , Y10S8/924
摘要： A modified polyamide polymer having a high amino end group content, with more than 30 percent of the amino end groups being secondary or tertiary amine, dramatically improves the dye bleed performance. The modified polyamide may be prepared by polymerization of polyamide-forming monomers in the presence of a carboxylic acid and a hindered piperidine derivative in amounts sufficient to achieve the high amino end group content.

3. 发明授权

US06497731B1 Dyed polyamide-6 articles having improved wetfastness properties and methods of making same 失效
标题翻译：具有改善的耐湿性能的染色聚酰胺-6制品及其制造方法
公开(公告)号：US06497731B1
公开(公告)日：2002-12-24
申请号：US10166723
申请日：2002-06-12
申请人： Natacha Berthelon , Dean R. Gadoury , Theodore G. Karageorgiou
发明人： Natacha Berthelon , Dean R. Gadoury , Theodore G. Karageorgiou
IPC分类号： D06P502
CPC分类号： D06P5/08 , D06P1/0032 , D06P1/56 , D06P3/241 , D06P5/02 , Y10S8/924
摘要： Polyamide-6 articles exhibit dramatically improved dye bleed and perspiration performance characteristics, as well as reduced color change of fluorescent dyed polyamide-6. These improvements are achieved according to the present invention by modifying conventional dyeing and aftertreatment conditions. That is, conventional temperatures used for dyeing and the aftertreatment of polyamide-6 yarns are typically about 100° C. and 77° C., respectively. In contrast, the dyeing and aftertreatment procedures of this invention are carried out at about 80° C. or lower, and about 5° C. or lower, respectively. Bath ratios of between about 15:1 to about 20:1 are employed with the polyamide-6 article being retained in the bath sufficient to achieve about 75% dye uptake.
摘要翻译：聚酰胺-6制品表现出显着改善的染料渗出和出汗性能特征，以及荧光染色聚酰胺-6的颜色变化减少。通过改变常规染色和后处理条件，根据本发明实现了这些改进。也就是说，用于染色的常规温度和聚酰胺-6纱线的后处理通常分别为约100℃和77℃。相反，本发明的染色和后处理程序分别在约80℃或更低，约5℃或更低的温度下进行。使用约15:1至约20:1之间的浴比，聚酰胺-6制品保留在浴中足以达到约75％的染料吸收。

4. 发明授权

US5891813A Articles having a chambray appearance and process for making them 失效
标题翻译：具有种子外观的制品及其制作方法
公开(公告)号：US5891813A
公开(公告)日：1999-04-06
申请号：US031370
申请日：1998-02-26
申请人： Dean R. Gadoury
发明人： Dean R. Gadoury
IPC分类号： D06B23/00 , D06P1/00 , D06P3/00 , D06P3/24 , D06P3/82 , D06P3/85 , D06P3/854 , D06P5/00 , D06P5/20 , C09B67/00
CPC分类号： D06P3/00 , D06P1/0096 , D06P3/002 , D06P3/242 , D06P3/8204 , Y10S8/925 , Y10T442/2902 , Y10T442/3976 , Y10T442/3984 , Y10T442/40 , Y10T442/696 , Y10T442/697
摘要： Articles made from melamine fibers and aramid fibers are dyed at selected conditions and with selected dyes such that the aramid fiber is dyed but the melamine fiber is not.
摘要翻译：由三聚氰胺纤维和芳族聚酰胺纤维制成的制品在选定的条件下和选定的染料染色，使芳族聚酰胺纤维染色，但三聚氰胺纤维不染色。

5. 发明授权

US5849648A Comfort melamine fabrics and process for making them 失效
标题翻译：舒适的三聚氰胺织物和制造它们的过程
公开(公告)号：US5849648A
公开(公告)日：1998-12-15
申请号：US845555
申请日：1997-04-24
申请人： George M. Kent , Dean R. Gadoury , Dominick A. Burlone , Karen L. Johnson
发明人： George M. Kent , Dean R. Gadoury , Dominick A. Burlone , Karen L. Johnson
IPC分类号： D06P3/85 , D03D15/00 , D06M11/00 , D06M11/05 , D06M101/00 , D06M101/16 , D06M101/30 , D06P3/00 , D06P3/82 , D02G3/00
CPC分类号： D06M11/05 , D06P3/00 , D06P3/82 , D06P3/8204 , Y10T428/29 , Y10T442/696
摘要： Fabrics made of melamine fibers are made more comfortable by submerging them for at least 20 minutes in a dyebath or mock dyebath that is at least 70.degree. C.
摘要翻译：由三聚氰胺纤维制成的织物通过在至少70℃的染浴或模拟染浴中浸没至少20分钟而变得更舒适。

6. 发明授权

US06451070B1 Ultraviolet stability of aramid and aramid-blend fabrics by pigment dyeing or printing 失效
标题翻译：芳纶和芳纶混纺织物通过颜料染色或印花的紫外线稳定性
公开(公告)号：US06451070B1
公开(公告)日：2002-09-17
申请号：US09684882
申请日：2000-10-06
申请人： George M. Kent , Karen L. Johnson , Dean R. Gadoury , Randy L. Mumford
发明人： George M. Kent , Karen L. Johnson , Dean R. Gadoury , Randy L. Mumford
IPC分类号： D06P502
CPC分类号： D06P3/24 , D06P1/44 , D06P1/5221 , D06P1/5242 , D06P1/5257 , Y10S8/925
摘要： A process for improving the ultraviolet stability of aramid and aramid-blend fabrics by pigment printing or padding the fabrics. The pigment printing process comprises the steps of supplying an aramid textile fabric free of highly polar solvents and dye diffusion promoting agents; pigment printing the fabric by applying onto the fabric a print paste comprising pigment, binder, print paste thickener, and water, the print paste being substantially free of carriers; and drying, then curing the thus-treated fabric at a temperature and for a time sufficient to fix the pigment on the aramid fibers. The padding process comprises the steps of supplying an aramid textile fabric; padding the fabric by soaking in a padding liquor comprising pigment, binder, and water, the padding liquor being substantially free of carriers; and then passing the wet fabric through two rollers to remove excess padding liquor from the fabric; and drying, then curing the thus-treated fabric at a temperature and for a time sufficient to fix the pigment on the aramid fibers.
摘要翻译：一种通过颜料印花或织物填充来提高芳族聚酰胺和芳族聚酰胺混纺织物的紫外线稳定性的方法。颜料印刷方法包括提供不含高极性溶剂和染料扩散促进剂的芳族聚酰胺纺织品的步骤; 通过在织物上涂布包含颜料，粘合剂，印刷浆糊增稠剂和水的印刷浆料，印刷浆料基本上不含载体而进行颜料印刷。然后干燥，然后在足以将颜料固定在芳族聚酰胺纤维上的温度和时间下固化如此处理过的织物。填料方法包括以下步骤：提供芳族聚酰胺织物; 通过浸泡在包含颜料，粘合剂和水的填充液中来填充织物，该填充液基本上不含载体; 然后将湿织物通过两个辊子以从织物中除去多余的填充液; 然后干燥，然后在足以将颜料固定在芳族聚酰胺纤维上的温度和时间下固化如此处理过的织物。

7. 发明授权

US06214058B1 Comfort melamine fabrics and process for making them 失效
标题翻译：舒适的三聚氰胺织物和制造它们的过程
公开(公告)号：US06214058B1
公开(公告)日：2001-04-10
申请号：US09003991
申请日：1998-01-08
申请人： George M. Kent , Dean R. Gadoury , Dominick A. Burlone , Karen L. Johnson
发明人： George M. Kent , Dean R. Gadoury , Dominick A. Burlone , Karen L. Johnson
IPC分类号： D06Q102
CPC分类号： D06M11/05 , D06P3/00 , D06P3/82 , D06P3/8204 , Y10T428/29 , Y10T442/696
摘要： Fabrics made of melamine fibers are made more comfortable by submerging them for at least 20 minutes in a dyebath or mock dyebath that is at least 70° C.
摘要翻译：由三聚氰胺纤维制成的织物通过在至少70℃的染浴或模拟染浴中浸没至少20分钟而变得更舒适。

8. 发明授权

US5169405A Multi-colored disperse dyeable fabric: polyester and poly-methyl-olefin blend 失效
标题翻译：多色分散染色布：聚酯和聚甲基烯烃共混物
公开(公告)号：US5169405A
公开(公告)日：1992-12-08
申请号：US797617
申请日：1991-11-25
申请人： Matthew B. Hoyt , Bobby J. Bailey , Dean R. Gadoury
发明人： Matthew B. Hoyt , Bobby J. Bailey , Dean R. Gadoury
IPC分类号： D06P3/54 , D06P3/79 , D06P3/82
CPC分类号： D06P3/54 , D06P3/794 , D06P3/8204
摘要： A predominantly polyester fabric has a multi-colored pattern. The fabric includes at least one non-aromatic, partially crystalline polymethylolefin yarn melting above about 180.degree. as less than 50%, by weight, of the fabric, and polyester yarn. The polymethylpentene yarn and the polyester yarn are fabricated in a predetermined pattern and then piece dyed with disperse dye techniques.
摘要翻译：主要是聚酯织物具有多色图案。该织物包括至少一种在约180℃以上熔融的非芳族部分结晶聚甲基纤维纱，小于织物重量的50％和聚酯纱线。以预定图案制造聚甲基戊烯纱和聚酯纱，然后用分散染料技术染色。

9. 发明授权

US06200355B1 Methods for deep shade dyeing of textile articles containing melamine fibers 失效
标题翻译：含有三聚氰胺纤维的纺织制品的深色染色方法
公开(公告)号：US06200355B1
公开(公告)日：2001-03-13
申请号：US09467894
申请日：1999-12-21
申请人： Dean R. Gadoury
发明人： Dean R. Gadoury
IPC分类号： D06P164
CPC分类号： D06P3/021 , D06P1/65125 , D06P3/001 , D06P3/241 , D06P3/8204 , Y10S8/92 , Y10S8/924
摘要： Methods for the deep shade dyeing of melamine fiber-containing textile articles include bringing an undyed melamine fiber-containing textile article into contact with a dye bath containing a dyestuff and an acid donor at a pH of greater than about 6.0 and an elevated dyeing temperature greater than about 100° C. for a time sufficient to dye the textile article with minimal loss of melamine fibers due to acid hydrolysis. Most preferably, the textile article or articles to be dyed is placed into the dye bath at ambient temperature, and thereafter the dye bath containing the textile article or articles to be dyed is heated to the elevated dyeing temperature, for example, at a rate of between about 0.5 to about 2.0° C. per minute. Suitable dyes include non-complexed acid dyes or acid dyes complexed with a metal (e.g., iron, cobalt, copper, aluminum or any transition metal). Suitable acid donors include butyrolactones, ethylene glycol monoformates and ethylene glycol diformates. The textile article may be formed entirely of melamine fibers or may be in the form of a blend of melamine fiber with at least one other type of fiber (e.g., aramid fibers).
摘要翻译：用于含三聚氰胺纤维的纺织品的深色染色方法包括使未染色的含三聚氰胺纤维的织物制品与含有染料和酸供体的染浴接触，pH值大于约6.0，染色温度升高超过约100℃，足以染色纺织制品，由于酸水解导致三聚氰胺纤维损失最小。最优选地，待染色的纺织制品或物品在环境温度下放置在染浴中，然后将含有待染色的纺织制品或制品的染浴加热至升高的染色温度，例如以约0.5至约2.0℃/分钟。合适的染料包括与金属（例如铁，钴，铜，铝或任何过渡金属）络合的非络合酸性染料或酸性染料。合适的酸供体包括丁内酯，乙二醇单甲酸酯和乙二醇二甲酸酯。纺织制品可以完全由三聚氰胺纤维形成，或者可以是三聚氰胺纤维与至少一种其它类型的纤维（例如芳族聚酰胺纤维）的混合物的形式。

10. 发明授权

US5851238A Photochemically stabilized polyamide compositions 失效
公开(公告)号：US5851238A
公开(公告)日：1998-12-22
申请号：US690692
申请日：1996-07-31
申请人： Dean R. Gadoury , Bobby J. Bailey
发明人： Dean R. Gadoury , Bobby J. Bailey
IPC分类号： C08J5/18 , C08K5/09 , C08L77/00 , D01F1/10 , D01F6/10 , D01F6/60 , D06M13/02 , D06M13/322 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34 , D06P3/24 , D06P3/06
CPC分类号： D01F1/10 , D01F6/10 , D01F6/60 , D06P3/241 , Y10S8/924
摘要： A process for preparing photochemically stable dyed nylon compositions includes providing to a dyebath a shaped article of poly(epsilon-caprolactam) hydrolytically polymerized in the presence of water, a carboxylic acid chain regulator and a hindered piperidine derivative; and in the dyebath, dyeing the shaped article with one or more metalized or nonmetalized acid dyestuffs.

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